1. Introduction
Quantum thermodynamics [
1,
2] has emerged as a promising research field both from a experimental [
3,
4,
5,
6] and from a theoretical perspective [
7,
8,
9,
10,
11,
12,
13,
14]. Statistical fluctuations in single quantum systems satisfy new laws known as quantum fluctuation theorems. Some of the fundamental questions have been addressed by Jarzynski and co-workers [
7,
8,
9,
10]. In [
7], an expression for the equilibrium free energy difference between two configurations of a system, in terms of the work performed in parametrically switching from one configuration to the other, is given. The work reported in [
8] settles the statements of the second law of thermodynamics through a generalization of the ones of Kelvin–Planck, Clausius, and Carnot. The authors of [
9] discuss the statistics of heat exchange between two classical or quantum finite systems initially prepared at different temperatures. Many questions, such as the role of entanglement and coherence, still remain open [
15,
16,
17,
18,
19]. The answer to these questions may lead to the development of quantum heat engines and refrigerators, as well as simple descriptions of quantum many-body systems. Recently, the authors of [
11] present the First and Second Laws of Quantum Thermodynamics from a Microscopic Definition of Entropy. In the same direction, the work presented in [
12] addresses the emergence of thermodynamic laws from quantum mechanics, from a viewpoint based on the connection of quantum thermodynamics with the theory of open quantum systems. In [
13], the analysis of thermodynamic uncertainty principles has been conducted. The authors of [
17] have shown that the energetic contribution of the dynamics of coherence is an essential topic to address for the consistency of the theory of quantum thermodynamics. An increasing number of works are devoted to the design of quantum heat engines and refrigerators. Among others, we can mention the heat machines whose working substance performs an Otto cycle. Some examples have been presented in [
16,
17,
20,
21,
22,
23]. In [
20], a quantum Otto engine using two-interacting spins as its working medium is analyzed within the framework of stochastic thermodynamics. The authors of [
21] analyze the efficiency of the quantum Otto cycle applied to a superconducting cavity. In [
22], the statistic work of a Fermi gas when a localized scattering potential is suddenly introduced in a Fermi sea is analyzed. The authors of [
23] investigate the particle–number dependence of some features of the out-of-equilibrium dynamics of d-dimensional Fermi gases in the dilute regime. In [
16], heat engines whose working substance are made of two coupled qubits performing a generalized Otto cycle have been studied in connection with the properties of coherence and entanglement.
Since the pioneering work of Bender [
24,
25] on Hamiltonians which obey Parity-Time Reversal (PT)-symmetry, many works have been written, setting the basis of the dynamics of non-Hermitian systems. The Hamiltonians which are invariant under PT-symmetry belong to the class of pseudo-Hermitian Hamiltonians [
26,
27]. A Pseudo-Hermitian operator is an operator which is similar to its adjoint. The spectrum of pseudo-Hermitian Hamiltonians may contain complex conjugate pairs. In terms of the space of parameters of the model, two dynamical phases can be distinguished. In one of the regions, the spectrum is real (symmetry phase), and, in the other complex conjugate, pairs appear (phase with broken symmetry). The border between both regions consists of Exceptional Points (EPs). At these points, two or more eigenvalues and their corresponding eigenstates are coalescent. Concerning the thermodynamics of this class of Hamiltonians, it has been proved that the quantum Jarzynski equality [
7] can be generalized to PT-symmetric quantum mechanics with an unbroken phase [
28]. The concept was extended to pseudo-Hermitian in the symmetry phase in [
29]. In a recent paper [
30], some aspects of quantum thermodynamics under the background of non-Hermitian quantum mechanics have been analyzed in connection to a quantum harmonic oscillator.
In this work, we proposed to study the amount of work we can extract from an Otto cycle when the working substance is a hybrid system composed of bosons and spins. The system interacts through a Hamiltonian based on a generalization of Da Providencia–Schütte Hamiltonian [
31]. We have included an asymmetry parameter in the interaction to account for the impurities that can be present in the system [
32,
33,
34]. Thus, the interaction is constructed as pseudo Hermitian. The study is focused on the influence of the asymmetry parameter on the extracted work.
The work is organized as follows: In
Section 2, we describe the model and the methods we have employed. We review the fundamentals of pseudo-Hermicity and its application to our model. In
Section 3, we analyze the statistical properties of the system and the efficiency of the Otto cycle, both as a heat machine and as a refrigerator. Conclusions are drawn in
Section 4.
2. Materials and Methods
The model of Da Providencia and Shütte [
31] has been intensively studied in different physical contexts. In particular, it is adequate to describe systems that exhibit condensate phases [
35,
36,
37,
38]. In a recent experiment, [
39], the generation of pairs of photons in a cavity and electrons has been reported. The Hamiltonian model [
31] can be written as
where
b and
are the annihilation and the creation boson operators associated with a harmonic oscillator of energy
, respectively. The operators
obey a
algebra, and they are used to model a two-level system of
spins,
being the separation in the energy of the levels. The coupling constant is denoted by
g.
The Hamiltonian
is invariant with respect to the operator
. The model exhibits two different phases. In the normal phase, the minimum value of energy is an eigenstate of
with eigenvalue zero, while, in the deformed phase, the ground state corresponds to an eigenstate of
with eigenvalue non-zero that is a condensate. When the ground state corresponds to an eigenstate of
with positive eigenvalue
L, the ground state is a boson condensate, while, with
, we have a condensate of spins [
31].
The boson–fermion representation of the model and its behavior at finite temperature have been discussed in [
40,
41]. In this work, we shall analyze the properties of a modified pseudo-Hermitian Hamiltonian
where
is a real parameter which we have introduced as an asymmetry in the interaction between the spins and the bosons. It accounts for the impurities of the system. Similar proposals can be found in [
32,
33,
34]. The proposed Hamiltonian preserves the invariance under
.
As a consequence of the pseudo-Hermicity of the Hamiltonian H, it exists an operator positive defined such that . The operator serves as a metric operator, and we can define a vector space with a new inner product .
Let us denote by
the set of eigenstates of
H,
, and
those of
,
. It can be shown that
forms a complete bi-orthogonal set
The operator
can be constructed as
so that
, and
, being
The new inner product is given by
Another characteristic of the pseudo-Hermicity of the Hamiltonian
H of Equation (
2) is that the corresponding spectrum is formed either by real or by complex conjugate pairs of eigenvalues. In the model parameter space, the real spectrum corresponds to the symmetry phase while the complex pair conjugate spectrum corresponds to the phase of broken symmetry. The limiting points of these two dynamical phases are called Exceptional Points (EPs). At these points, two or more eigenvalues and their corresponding eigenstates are coalescent. For the Hamiltonian of Equation (
2), the EP takes place for
. From the mathematical point of view, for
, the spectrum of
H is real and, for some value of
, complex pair conjugate eigenvalues are present.
The grand partition function at a temperature
T can be obtained from the density matrix
, with
and
being the chemical potential as
It has been proved in [
29] that, when the eigenvalues of the Hamiltonian appear as complex conjugate pairs,
takes real values.
From
, we can derive the thermodynamics of the system, i.e., we can compute the entropy,
S, the free energy,
F, the internal energy,
U, and the specific heat,
C, as usual:
We fix
by imposing that
be equal to the number of spins,
, of the system.
Let us briefly review the derivation of the exact grand partition function for the Hamiltonian of Equation (
2). For further details, the reader is kindly referred to [
41].
We assume that the model space for the spins consists of two levels, each with degeneration . Thus, in the grand canonical ensemble, the number of spins, , varies from 0 to . The normalized state of l-bosons shall be denoted by .
We shall give the basis of the physical space in terms of the set the vectors
is the index corresponding to levels,
k represents substates, and
i reads for the partition with
i particles and
n is the particle number of the configuration. Thus,
,
and
. The dimension of the spin subspace
, while the bosonic subspace has an infinite dimension.
We aimed to decompose the spin subspace into invariant and irreducible subspaces. The distribution of a given number of particles on two degenerate levels can be represented by numbers
and
, i.e.,
is the number of sublevels which are occupied by particles in both the lower and the upper levels,
is the number of sublevels which are unoccupied in the lower and upper levels. The distribution of the particles on the
sublevels determines the quasispin
S of the state, with
. The number of particles in this configuration is
. We shall call
the subspace of states with
occupied- and
unoccupied-sublevels. The dimension is
. They are
different subspaces
. Each of these subspaces can be decomposed into irreducible ones with multiplicities
The exact grand partition function can be written
In writing
, we have used the fact that the Hamiltonian of Equation (
2) commutes with the operator
. Thus, its eigenvalues can be given in terms of the eigenvalue
L of
.
3. Results and Discussion
In this section, we shall present results for a system modeled by the Hamiltonian of Equation (
2).
As reported in [
31], for
, the spectrum depends on the values of the dimensionless constant
. For values of
, the ground state is an eigenstate of
with eigenvalue
, while for values of
the minimum value of the energy of the spectrum of
corresponds to a state with
. The corresponding dimensionless constant for the pseudo-Hermitian Hamiltonian
H of Equation (
2) can be set as
. The same trend is true for the pseudo Hermitian Hamiltonian
H of Equation (
2) in terms of
x. That is, the minimum value of the energy in the normal phase (
) is achieved at the value
, while in the deformed phase
. For
, complex pair conjugate eigenvalues are present in the spectrum, and EPs occur for values
.
For simplicity, we shall take the Boltzmann constant as , and we shall measure the energy in units of . We shall fix the number of spins to , , and .
As pointed out before, for values of
, EPs are present. As an example, in
Figure 1, we plot the eigenvalues of
H of Equation (
2) as a function of
for
for two different values of
L.
In
Figure 2 and
Figure 3, we show the behavior of the entropy and the internal energy, respectively. The curves correspond to different values of the dimensionless coupling constant
x. In
Figure 2, from left to right, the values of
x take the values
, respectively. The same for
Figure 3, but from the up to the down curve. Panels (a), (b), (c), and (d), stand for values of the asymmetry parameter
and
, respectively. The curves of both entropy and internal energy are continuous as a function of the temperature but displayed a pronounced change in the slope at low temperatures, this is the signature of a second-order phase transition as a function of the temperature. This transition occurs to greater values of
T as
increases.
In
Figure 4 and
Figure 5, we have displayed the behavior of the temperature and the internal energy, as a function of the dimensionless parameter
x, at constant values of the entropy. The entropy
S takes the values 2 to 8, in steps of one, in increasing order from the down curve to the up curve. As in the previous figures, panels (a), (b), (c), and (d), stand for values of the asymmetry parameter
, and
, respectively. As can be inferred from
Figure 4, the temperature remains almost constant along the adiabatic up to values of
. The same is true for the internal energy displayed in
Figure 5. As
tends to zero, both temperature and entropy remain constant along the adiabatic.
In
Figure 6 and
Figure 7, we show the behavior of the entropy and the internal energy, respectively. The curves correspond to different values of the dimensionless coupling constant
x. In
Figure 6 and
Figure 7, from the up to the down curve, the values of
x take the values
, and 2, respectively. Panels (a), (b), (c), and (d) stand for values of the asymmetry parameter
, and
, respectively. As seen in
Figure 1, at the value
, the system shows a
for
. Though the partition function is real [
8,
29], the behavior of entropy and the internal energy, for large values of
x, may show anomalies at low temperatures. This is because we are working with an effective interaction that takes into account the effect of the environment, and not with the whole system [
42,
43,
44].
In
Figure 8 and
Figure 9, we have displayed the behavior of the temperature and the internal energy, as a function of the dimensionless parameter
x, at constant values of the entropy. The entropy
S takes the values 2 to 8, in steps of one, in increasing order from the down curve to the up curve. As in the previous figures, panels (a), (b), (c), and (d), stand for values of the asymmetry parameter
, and
, respectively. The curves of the temperature and the internal energy show a softer variation with the coupling constants as compared with the corresponding results (
Figure 4 and
Figure 5) for
.
The mean value of
as a function of the temperature is depicted in
Figure 10. The curves correspond to different values of the dimensionless coupling constant
x. From the up to the down curve,
x takes the values
, respectively. Panels (a), (b), (c), and (d) stand for values of the asymmetry parameter
, and
, respectively. As can be observed from the figure, for the larger values of
at low temperatures,
L takes negative values (condensate of spins). The mean value of
increases with
T.
From the previous results, it can be inferred that, in the computation of the partition function and of the thermodynamical properties derived from it, the effect of the presence of EPs is not significant. At a given
, the partition function is the trace of the density matrix over all the possible configurations of the system. For the present model, for large values of
L, the EPs concentrate near values of
tending to zero. However, as seen from
Figure 10, the mean values of
are not larger than 10, even at high temperatures. The presence of the EPs should be relevant to other physical quantities, i.e., the survival probability in the study of the thermal evolution of an adequate initial state.
To complete the analysis of the system, we shall study the work that can be extracted from the hybrid system after an Otto cycle is performed. In
Figure 11, we have drawn an Otto cycle. We performed work on the system from
along the adiabatic
, heat is released from
, the system performs work from
along the adiabatic
, and heat is absorbed from
to return to the initial state. The coefficient of efficiency is defined as usual as the ratio of the absolute value of the net work conducted by the system to the heat absorbed (in our convention, the work conducted on the system is positive, and the one the system performs is negative, the same for the heat absorbed and the heat released), which is
where we have taken into account the fact that the internal energy is conserved after performing a cycle,
.
If the cycle is completed in the reverse direction, the system behaves as a refrigerator, with the efficiency given by
In
Figure 12, it is shown that the maximum value of the efficiency of the Otto cycle that works among two adiabatic curves,
for
and
. The maximum values for the coefficient of efficiency are obtained by increasing the asymmetry parameter
.
The efficiency as a refrigerator of the inverse Otto cycle is presented in
Figure 13, for values of
, and
, respectively. The maximum values for the coefficient of efficiency are obtained by decreasing the asymmetry parameter
.
The parameter regulates the asymmetry between the pair creation and the pair destruction of a boson and a spin. For values of , the interaction favors the destruction of pairs, and the system is efficient in working as a heat machine. On the other hand, for values of , the interaction favors the production of pairs, and the system is efficient in working as a refrigerator.
For the sake of completeness, in
Figure 14, we present results for the maximum efficiency of the Otto cycle that works among two adiabatic curves,
, for negative asymmetry parameter
and
.
As
, the net work conducted on the system approaches zero,
, the same is true for the balance between the heat extracted and absorbed,
. Thus, as
, the efficiency as a heat machine is zero, but the efficiency as refrigerators becomes considerably large. This mechanism may serve as a way for cooling a hybrid system as the one of [
39].
4. Conclusions
In this work, we have modified the model of Da Providencia and Schüte [
31] by introducing an asymmetry factor in the interaction among the bosons and the spins. This asymmetry serves to take into account the imperfections of the environment, similar approaches have been used [
32,
33,
34]. We have computed the exact partition function and from it the general thermodynamical properties of the hybrid system. The system undergoes a second-order phase transition as a function of the temperature, for different values of
. We have studied both the symmetry,
, and the broken symmetry dynamical phase,
.
We have presented results concerning the thermodynamical properties of the system in its broken symmetry phase. We observed that the presence of EPs does not have a significant effect on the partition function because, at a fixed
, all the possible configurations contribute to the trace of the temperature-dependent density matrix. Nevertheless, the presence of EPs may be relevant in analyzing other physical aspects of the problem, i.e., the temperature evolution of a particular initial state. At large values of the coupling constant and
, though the partition function takes real values, anomalies in the thermodynamical quantities can appear since we are working with an effective interaction which takes into account the effects of the environment, we are not working with the whole system [
42,
43,
44].
For positive values of , as the asymmetry parameter is increased, the critical temperature, for different values of the dimensionless coupling constant x, takes higher values. At constant entropy, both the internal energy and the temperature remain almost unchanged for values of . We performed an Otto cycle with this hybrid system as the working substance. The maximum values of the coefficient of efficiency are achieved by increasing ; on the contrary, the maximum values for the efficiency of the system working as a refrigerator are obtained by decreasing the values of . As pointed out before, the parameter regulates the asymmetry between the pair creation and the pair destruction of a boson and a spin of the proposed interaction. For values of , the interaction favors the destruction of pairs, and the system is efficient in working as a heat machine. On the other hand, for values of , the interaction favors the production of pairs, and the system is efficient in working as a refrigerator. The introduction of an asymmetry factor, in the case , allows for obtaining a very large efficiency of the system as a refrigerator. As , the net work completed on the system approaches zero, and the same is true for the balance between the heat extracted and absorbed. Thus, as , the efficiency as a heat machine is zero, but the efficiency as refrigerators becomes considerably large. This mechanism may serve as a way for cooling a hybrid system.
Work is in progress concerning the temperature-dependent evolution of a given initial state in the vicinity of EPs.