1. Introduction
In quantum theory, a classical observable, which is modeled by a real scalar variable, is replaced by a quantum operator, which is analogous to an infinite-dimensional matrix operator. A quantum operator that represents an observable endows the observable with probabilistic properties such as a mean and a variance (or fluctuation from its mean as it is measured by the standard deviation from its mean).
In order to associate an operator with a mean, a quantum system is described by a quantum state or a state vector . For instance, given an operator and a quantum state described by the state vector , the mean of the operator is its expectation value given by in Dirac’s notation. This is entirely analogous to the linear algebra notation . This associates a real scalar number with a Hermitian operator in the given quantum state . The fluctuation from its mean or its standard deviation is given by .
For example, classically, a particle is described with a position variable
q and a momentum variable
p. In quantum theory, the position variable is replaced by a position operator
, and the momentum variable is replaced by a momentum operator
. In the quantum world, the position operator
and the momentum operator
do not commute or
. The fundamental postulate of quantum mechanics is the canonical commutator that [
1,
2,
3,
4]:
where the square bracket represents the definition of a commutator. Sometimes, this is called Dirac’s fundamental postulate [
1]. Many properties of quantum physics, such as the uncertainty principle, can be derived from this postulate. Moreover, one can derive the representation of the momentum operator
in terms of the coordinate operator
. Hence, the fundamental postulate is important for quantum theory as well as the quantization of electromagnetic fields where the quantum fluctuation of electromagnetic fields is important.
In this note, we shall show that the fundamental commutator can be derived from the Heisenberg equations of motion, and the quantum Hamilton equations. Heisenberg equations can be derived from the quantum state equation, and quantum Hamilton equations can be derived from energy conservation argument. The fundamental postulate of quantum theory is the quantum state equation, which was first proposed by Schrödinger, based on the energy conservation argument.
Furthermore, it can be shown that quantum Hamilton equations can be derived from the Heisenberg equations of motion after invoking the fundamental commutator [
3]. The quantum Hamilton equations are very similar in form to the classical Hamilton equations. As such, there is usually a clear analogy and a mathematical homomorphism between the classical and quantum theories of many systems, such as electromagnetic fields. This streamlines the derivation of many quantum equations of motion. It also explains why the equations of motion for quantum electromagnetics resemble those of classical electromagnetics [
5].
Using this mathematical homomorphism, one can derive the quantum Maxwell equations without using mode decomposition (or Fourier decomposition), a procedure followed in most textbooks [
6,
7,
8]. Maxwell’s equations can be quantized directly in the coordinate space. Moreover, it is easy to add impressed sources to Maxwell’s equations and quantize them, as has been shown in [
5].
For a set of discrete oscillators coupled to each other, the canonical commutator of (
1) (see [
6]) is:
In the continuum limit, when the variables
and
become fields
and
, respectively, then the commutator becomes [
5]:
or the Kronecker delta function becomes a Dirac delta function in the continuum limit. It can be shown that these commutators induce derivatives with respect to operators and give rise to the quantum Hamilton equations. Using the above, the quantum Maxwell equations can be derived [
5].
2. Classical Hamiltonian of an Oscillator
A general classical oscillator, including the anharmonic oscillator, has a Hamiltonian given by:
where
p and
q are functions of time
t. Its multi-variable differential can be written as:
In order for the above to be zero for energy conservation, then:
The above are the infinitely many possible energy conserving equations of motion for this problem. They are similar to the Hamilton equations determined up to a factor
C. The reason is that the clock is not defined in a kinematic system, and all of these systems moving with different clocks will satisfy energy conservation. However, we can fix the clock by invoking the definition of velocity in terms of momentum, namely that:
i.e., the connection between velocity and momentum, which can be derived from the first equation of (
7) with (
4). For this, we need to pick
.
The above can be generalized to the case when
, viz., it is time dependent. This is physically equivalent to a time varying clock. Again, we can use (
8) to calibrate our clock. When
, (
7) is mathematically equivalent to the case when the general energy conserving solution is such that:
which is another way to express an energy conserving solution.
Furthermore, (
7) can be rewritten as:
Then, the time stretching technique, similar to the coordinate stretching technique [
9,
10,
11,
12,
13], can be used to rewrite the above as:
where
. To agree with laboratory experiments, the time stretching variable
.
3. Quantum Hamiltonian
In the quantum world,
p and
q, the canonical conjugate variables, are elevated to be quantum operators. Hence, (
4) becomes:
Since functions of an operator argument are operators themselves,
and
are now quantum operators. This Hamiltonian operator acts on a state vector
in the manner of the Schrödinger equation, viz.,
where
is a vector that indicates the state of the quantum system with the normalization condition, i.e.,
. Equation (
13) is a fundamental postulate of quantum theory. It cannot be derived, but it is based on the postulate of Schrödinger (Later, this equation for the quantum state was used for quantum Hamiltonians for different quantum systems, e.g., the Dirac equation for relativistic electrons. It has also been used for the quantum Maxwell equations [
5]. In order not to confuse this with the Schrödinger equation for wave functions in an atom, for instance, we will call this Schrödinger’s quantum state equation.). In addition, for energy conservation,
, which represents the total energy of the system, is time independent, and
solves: (
13) is of the form
where
.
The requirement of a quantum system is that the expectation value of the quantum operators, which are the quantum representation of an observable or canonical dynamic variable, be equal to their classical analog. For instance, the expectation value of the Hamiltonian operator
is:
With (
14) substituted into (
15), it indeed can be shown that
H is independent of time. In other words,
In the above, commutes with a function of , namely , and hence, the above time dependence cancels, yielding a constant of time implying energy conservation. So far, nothing has been said of the commutators in quantum theory. Therefore, the assumption that is time independent is consistent with energy conservation.
One can show further that given an operator
in the Schrödinger picture, it has the expectation value given by:
where the operator in the Heisenberg picture emerges [
4],
and
in the Schrödinger picture is time independent. In the following, we will eliminate the subscript
h. When an operator is a function of time, it is understood to be in the Heisenberg picture. Moreover, it can be shown that the equation of motion for
in the Heisenberg picture takes the form of:
where
is the commutator. The above is the Heisenberg equation of motion.
Given the fundamental commutator relation,
, it can be shown that [
3,
4,
5]:
The above introduces the concept of a derivative with respect to to an operator, namely that . We will digress to discuss this in more detail.
It is to be noted that the above is derived by induction, or recursion: Given that:
and the commutator
, it can be shown that:
The reverse of the above procedure is also true.
3.1. A Word on the Derivative with Respect to the Operator
In the above, the derivative of an operator with respect to to an operator has meaning only when the operator is acting on its eigenstate (eigenvector). Then, the operator can be treated as a scalar number, which is the eigenvalue associated with the particular eigenvector. Assume that a quantum state is expanded in terms of a set of eigenvectors, which is given by:
where
are the eigenvectors of
, then it follows that:
where
is an alternative way of denoting the derivative with respect to an operator, and here,
. The above implies that in evaluating
, we will let this operator
act on the state vector expanded in terms of
, the eigenvectors of
, and then take the derivative with respect to the eigenvalue
in the preceding equation. Hence,
only produces another operator
.
The above is in agreement with a perturbation expansion or the first variation of
, so that:
It expands to only first order to:
only if
or they commute and share the same set of eigenvectors. In other words, the same set of eigenvectors diagonalizes
and
simultaneously. That
and
share the same set of eigenvectors is in fact implied in the derivation of (
25). The commutator in (
28) is important in allowing a simple definition of the derivative with respect to an operator.
6. Fundamental Commutator from Energy Conservation
The Heisenberg equations of motion are also energy conserving as they are derived from the quantum state Equation (
13). Hence, both the Hamilton equations and Heisenberg equations of motion can be derived without invoking the fundamental commutator, but merely from energy conservation alone. Next, we shall show that the fundamental commutator can actually be derived from the quantum Hamilton equations and Heisenberg equations of motion.
We can start with one of the quantum Hamilton equations that follows from energy conservation argument after calibrating the clock. This is:
Next, we look at the Heisenberg equations of motion, one of which is:
where we define
. From (
46) and (
47), it follows that
By writing the Hamiltonian as a polynomial, then from the above, taking the
m-th term of the polynomial, it is quite easy to show that
By setting
in the above, then
which is the fundamental commutator. Therefore preceding argument shows that the fundamental commutator can be derived from, or is consistent with, quantum Hamilton equations and Heisenberg equations of motion, which are energy conserving equations.
One of the fundamental postulates of quantum theory is (
13), which cannot be derived. It is the equation of motion for the quantum state. It was first proposed by Schrodinger, and later used to describe all quantum systems, include Dirac’s equation for relativistic electrons.
The fundamental commutator is important for energy conservation, and it can be generalized to the quantization of electromagnetic fields [
5]. However, it is intimately related to energy conservation.