Kinetic Modeling for the “One-Pot” Hydrogenolysis of Cellulose to Glycols over Ru@Fe3O4/Polymer Catalyst
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Catalyst Synthesis
2.3. Characterization
2.4. Catalyst TESTING Procedure and Product Analysis
3. Results
3.1. Catalyst Characterization
3.2. Cellulose Hydrogenolysis
4. Discussion
5. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | SBET, m2/g | SL, m2/g | St, m2/g | V, cm3/g |
---|---|---|---|---|
HPS | 1075 | 1191 | 265 (1); 807 (2); 1072 | 0.37 |
Fe3O4/HPS | 450 | 480 | 160 (1); 289 (2); 449 | 0.13 |
Ru@Fe3O4/HPS | 364 | 392 | 175 (1); 189 (2); 364 | 0.08 |
Element | C 1s | O 1s | N 1s | Cl 2p | Ru 3p3/2 | Fe 2p3/2 |
---|---|---|---|---|---|---|
%at/%wt. | 66.8/45.5 | 25.8/23.5 | 0.2/0.2 | 0.4/0.8 | 3.3/18.9 | 3.5/11.1 |
Catalyst | Selectivity, % | Specific Catalytic Activity Calculated as a Gram of EG or PG per Gram of Ru per Hour, h−1 | ||
---|---|---|---|---|
EG | PG | EG | PG | |
Ru@Fe3O4/HPS | 22.6 | 20.0 | 39.12 | 34.62 |
5% Ru-Fe3O4/SiO2 | 19.1 | 20.9 | 25.29 | 27.72 |
3% Ru/HPS | 7.4 | 12.5 | 7.51 | 12.71 |
Parameter, (mol/mol)n·s−1 | Value | Parameter, (mol/mol)n·s−1 | Value |
---|---|---|---|
k1 | 1.47 ± 0.07 × 10−3 | k6 | 3.41 ± 0.17 × 10−4 |
k2 | 1.14 ± 0.06 × 10−4 | k7 | 4.55 ± 0.23 × 10−5 |
k3 | 9.72 ± 0.49 × 10−5 | k8 | 4.35 ± 0.22 × 10−4 |
k4 | 1.45 ± 0.07 × 10−4 | k9 | 2.81 ± 0.14 × 10−4 |
k5 | 2.90 ± 0.14 × 10−4 | k10 | 1.61 ± 0.08 × 10−4 |
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Manaenkov, O.; Kosivtsov, Y.; Sapunov, V.; Kislitsa, O.; Sulman, M.; Bykov, A.; Sidorov, A.; Matveeva, V. Kinetic Modeling for the “One-Pot” Hydrogenolysis of Cellulose to Glycols over Ru@Fe3O4/Polymer Catalyst. Reactions 2022, 3, 1-11. https://doi.org/10.3390/reactions3010001
Manaenkov O, Kosivtsov Y, Sapunov V, Kislitsa O, Sulman M, Bykov A, Sidorov A, Matveeva V. Kinetic Modeling for the “One-Pot” Hydrogenolysis of Cellulose to Glycols over Ru@Fe3O4/Polymer Catalyst. Reactions. 2022; 3(1):1-11. https://doi.org/10.3390/reactions3010001
Chicago/Turabian StyleManaenkov, Oleg, Yuriy Kosivtsov, Valentin Sapunov, Olga Kislitsa, Mikhail Sulman, Alexey Bykov, Alexander Sidorov, and Valentina Matveeva. 2022. "Kinetic Modeling for the “One-Pot” Hydrogenolysis of Cellulose to Glycols over Ru@Fe3O4/Polymer Catalyst" Reactions 3, no. 1: 1-11. https://doi.org/10.3390/reactions3010001