Raman Spectroscopic Analysis of a Mid-19th Century Reredos by Sir George Gilbert Scott
Abstract
:1. Introduction
2. Background, Method, and Materials
‘The last ornament added to the edifice is the beautiful reredos presented to it by his Grace the late Duke of Newcastle, with his usual generosity. This gives great richness to the east end of the church, and looking from its opposite end, terminates the vista very pleasingly; but when the eye has become accustomed to its varied hues, and can critically trace out all its details, again it becomes a question whether its features accord well with the old fabric it has been placed in; and also whether its really best materials, such as the marble shafts forming a part of the composition, should have been so entirely subdued by the tints emanating simply from the painter’s brush aided by gilding. As a work of art, however, it will command admiration; and the difficulty of treating this end of the church must be borne in mind, consisting as it does, simply of a veil of masonry, filling up the original central tower-arch. There can be no doubt as to the genius of the designer, Mr G. G. Scott, nor of the munificence of the noble donor of this reredos.’[20]
3. Results
- Three pigments are adopted for the red colour, namely vermilion (mercury sulfide), haematite (iron III) oxide) and more rarely, red lead; the latter pigment is found in only one specimen (WPNA 3). WPNA 1 curiously comprises two different red pigments, namely vermilion alone and haematite in admixture with carbon—the darker red colour incorporated carbon black and was used with vermilion only in WPNA 3. Generally, the carbon spectral signatures were indicative of a vegetative source of carbon black but WPNA2 and WPNA3 showed the phosphate stretching band at 960 cm−1 indicative of a bone black or ivory black pigment: this was preferred for instances where artists desired a glossier tonal black quality [23]. The green pigment is a mixture of chrome yellow and blue ultramarine, and the single mineral alternatives of malachite, green earth, viridian, and verdigris were not used. A visually dark red pigment hue in WPNA4 is also a mixture of red vermilion and blue ultramarine.
- Lighter and darker shades of blue were achieved using ultramarine and lead white or carbon, respectively.
- Calcite and dolomite signals are assigned to the substrate.
- WPNA6 is predominantly chrome yellow but contains some ultramarine, possibly a contaminant.
- A brown colour is seen in WPNA 7 and is a mixture of carbon black, haematite, quartz, lead white, and barytes. The presence of barytes is attributed to a filler and lightening agent.
4. Discussion and Conclusions
In the designing or directing of all these [decorative features] the architect should have a primary influence, and even in works of the highest kind the painter should work hand in hand with the architect.[25]
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
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Sample Number | Colour | Pigments Identified | Characteristic Raman Bands/cm−1 |
---|---|---|---|
WPNA 1 | Red | vermilion | 257, 353 |
Red | haematite | 223, 292, 410 | |
Black | carbon black | 1320, 1598 | |
WPNA 2 | Blue | ultramarine | 548 |
White | lead white | 1050 | |
Black | bone black | 960, 1320, 1598 | |
WPNA 3 | Red | vermilion | 257, 353 |
Black | bone black | 960, 1320, 1598 | |
Red | red lead | 224, 316, 390, 550 | |
Black | carbon black | 1320, 1598 | |
WPNA 4 | Blue | ultramarine | 548 |
White | lead white | 1050 | |
Black | carbon black | 1320, 1598 | |
Red | vermilion | 257, 353 | |
WPNA 5 | Yellow | chrome yellow | 320, 852 |
White | lead white | 1050 | |
WPNA 6 | Yellow | chrome yellow | 320, 852 |
Blue | ultramarine | 548 | |
Yellow | chrome yellow/ ultramarine | 320, 548, 852 | |
Red | vermilion | 257, 353 | |
WPNA 7 | Red | haematite | 223, 292, 410 |
Black | carbon black | 1320, 1598 | |
White | barytes | 981 |
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Brooke, C.; Edwards, H.; Vandenabeele, P.; Lycke, S.; Pepper, M. Raman Spectroscopic Analysis of a Mid-19th Century Reredos by Sir George Gilbert Scott. Heritage 2023, 6, 5082-5092. https://doi.org/10.3390/heritage6070269
Brooke C, Edwards H, Vandenabeele P, Lycke S, Pepper M. Raman Spectroscopic Analysis of a Mid-19th Century Reredos by Sir George Gilbert Scott. Heritage. 2023; 6(7):5082-5092. https://doi.org/10.3390/heritage6070269
Chicago/Turabian StyleBrooke, Christopher, Howell Edwards, Peter Vandenabeele, Sylvia Lycke, and Michelle Pepper. 2023. "Raman Spectroscopic Analysis of a Mid-19th Century Reredos by Sir George Gilbert Scott" Heritage 6, no. 7: 5082-5092. https://doi.org/10.3390/heritage6070269
APA StyleBrooke, C., Edwards, H., Vandenabeele, P., Lycke, S., & Pepper, M. (2023). Raman Spectroscopic Analysis of a Mid-19th Century Reredos by Sir George Gilbert Scott. Heritage, 6(7), 5082-5092. https://doi.org/10.3390/heritage6070269