The Plaka Bridge in Epirus: An Evaluation of New Building Materials for Its Restoration
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
3.1. Characterization of Historical and Quarry Stones—Evaluation of Their Compatibility
3.1.1. Stone Samples’ Description
3.1.2. Mineralogical and Compositional Analysis
3.1.3. Microstructural Analysis of Compact Historical Stone and Quarry Stone
3.1.4. Hygric Behavior of Historical and Restoration Stones Through Capillary Rise Tests
3.1.5. Mechanical Behavior of Compact Historical and Quarry Stones through Ultrasound Velocity Measurements
3.1.6. Aesthetic Compatibility of Historic Stone and Quarry Stone in Relation to Color and Surface Morphology Characteristics
3.2. Evaluation of Restoration Mortars
3.2.1. Design of Restoration Mortars—Compatibility and Performance Criteria
3.2.2. Fresh Mortar Characteristics
3.2.3. Study of Chemical Evolution with Time
3.2.4. Analysis of Microstructural Characteristics
3.2.5. Analysis of Mechanical Characteristics
3.2.6. Adherence of the Different Mortars to the Quarry Stone as a Substrate—Pull-Off Resistance
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | Sample Description |
---|---|
SH1 | Compact stone, most dominant type of the bridge’s building stones |
SH2 | Compact stone, most dominant type of the bridge’s building stones |
PH1 | Porous stone, used as filling material at interior of bridge’s main body |
R_S | Freshly cut stone from nearby quarry “Dafnoula stone” |
Sample | Mineralogical Composition |
---|---|
SH1 | Quartz, calcite, albite, anorthite, chlorite, montmorillonite–chlorite, muscovite, biotite, illite, chrysotile, lizardite, chlorite–serpentine |
PH1 | Calcite, quartz |
R_S | Quartz, albite, calcite, anorthite, montmorillonite–chlorite, illite, lizardite |
Sample | Mass Loss (%) in Different Temperature Ranges | |||
---|---|---|---|---|
<120 °C | 120–200 °C | 200–600 °C | >600 °C | |
SH1 | 0.35 | 0.10 | 0.72 | 11.46 |
R_S | 0.45 | 0.11 | 1.01 | 7.67 |
Sample | Total Cumulative Volume (mm3/g) | Specific Surface Area (m2/g) | Average Pore Radius (μm) | Total Porosity (%) | Bulk Density (g/cm3) |
---|---|---|---|---|---|
SH1 | 4.08 | 0.71 | 0.023 | 1.07 | 2.61 |
R_S | 11.74 | 1.03 | 0.108 | 3.03 | 2.58 |
Sample | Average Specific Weight (g/cm3) | Standard Deviation |
---|---|---|
SH_1 | 2.61 | 0.02 |
SH_2 | 2.60 | 0.01 |
PH_1 | 2.02 | 0.96 |
PH_2 | 1.26 | 0.13 |
R_S | 2.59 | 0.01 |
Sample | CRC (g/(cm2sec1/2)) | St.dev. | Average WACcap (%) | St.dev. |
---|---|---|---|---|
SH | 2.00·10−4 | 0 | 0.643 | 0.068 |
R_S | 2.33·10−4 | 5.8·10−5 | 0.864 | 0.090 |
Sample | Average Ultrasound Velocity (m/s) | Standard Deviation |
---|---|---|
SH_1 | 4265.21 | 260.41 |
SH_2 | 4535.05 | 177.81 |
R_S | 4397.47 | 250.75 |
Sample | L | Standard Deviation | a | Standard Deviation | b | Standard Deviation |
---|---|---|---|---|---|---|
SH1 | 63.20 | 1.63 | −1.21 | 0.37 | 1.07 | 0.58 |
SH2 | 63.09 | 1.60 | −0.98 | 0.50 | 2.36 | 1.80 |
R_S | 57.49 | 1.65 | −1.77 | 0.17 | 0.98 | 0.42 |
Sample Comparison | ΔΕ | ΔΕ*94 | ΔC*2,1 | ΔH*2,1 |
---|---|---|---|---|
Comparison of R_S with SH1 | 5.74 | 2.91 | 0.41 | 0.39 |
Comparison of R_S with SH2 | 5.82 | 3.19 | −0.53 | 1.50 |
Restoration Mortar | Lime Powder | Natural Hydraulic Lime NHL3.5 | Metakaolin | Natural Pozzolan | Siliceous Sand (0–2 mm) | Mix Sand | Superplasticizer (%w/w of dry mortar) | Addition of Additives |
---|---|---|---|---|---|---|---|---|
L_M8.5 | 16.5 | - | 8.50 | - | 75 | - | - | NO |
L_M8.5_s | 16.5 | - | 8.50 | - | 75 | - | 0.05 | NO |
NHL_M1 | 24.00 | 1.00 | - | 75 | - | - | NO | |
Pl.Br.1 | 18.75 | 4.17 | 12.5 | - | 64.58 | 0.05 | YES | |
Pl.Br.2 | 18.75 | 4.17 | 12.5 | - | 64.58 | 0.05 | NO |
Restoration Mortar | W/B | Flow Table (cm) | Bulk Density (g/cm3 ) | Retained Water (%) |
---|---|---|---|---|
L_M8,5 | 1.10 | 15.50 | 1.88 | 93.77 |
L_M8,5s | 1.01 | 15.10 | 1.92 | 94.56 |
NHL_M1 | 0.74 | 15.00 | 2.04 | 92.41 |
Pl.Br.1 | 0.69 | 16.50 | 1.82 | 99.02 |
Pl.Br.2 | 0.65 | 16.80 | 1.97 | 89.88 |
Restoration Mortar | Mass loss (%) in Different Temperature Ranges (°C) | Inverse Hydraulicity Ration | |||||
---|---|---|---|---|---|---|---|
Days | <120 °C | 120–200 °C | 200–600 °C | 600–1000 °C | 370–470 °C | ||
L_M8,5 | 14 | 0.97 | 0.96 | 2.28 | 8.19 | 0.45 | 2.94 |
L_M8,5 | 28 | 0.99 | 1.05 | 2.32 | 8.28 | 0.51 | 2.90 |
L_M8,5 | 90 | 0.90 | 0.99 | 2.31 | 8.06 | 0.27 | 2.66 |
L_M8,5_s | 14 | 1.02 | 1.26 | 2.92 | 7.16 | 0.89 | 2.18 |
L_M8,5_s | 28 | 0.94 | 0.98 | 2.72 | 8.75 | 0.62 | 2.84 |
L_M8,5_s | 90 | 1.01 | 0.81 | 2.21 | 9.29 | 0.00 | 3.08 |
NHL_M1 | 14 | 1.13 | 0.84 | 2.04 | 7.56 | 0.62 | 3.35 |
NHL_M1 | 28 | 0.83 | 0.52 | 1.86 | 7.62 | 0.62 | 4.33 |
NHL_M1 | 90 | 0.70 | 0.47 | 2.03 | 8.40 | 0.00 | 3.36 |
Pl.Br.1 | 14 | 0.53 | 0.59 | 4.23 | 16.66 | 1.33 | 4.77 |
Pl.Br.1 | 28 | 0.69 | 0.67 | 3.93 | 17.83 | 1.11 | 5.11 |
Pl.Br.1_ons | 28 | 0.45 | 0.49 | 4.07 | 18.29 | 1.10 | 5.29 |
Pl.Br.1 | 90 | 0.79 | 0.89 | 4.06 | 16.40 | 0.63 | 3.80 |
Pl.Br.2 | 14 | 0.63 | 0.58 | 2.65 | 17.91 | 0.71 | 7.11 |
Pl.Br.2 | 28 | 0.55 | 0.50 | 2.10 | 18.08 | 0.42 | 8.29 |
Pl.Br.2 | 90 | 0.72 | 0.73 | 2.68 | 17.87 | 0.00 | 5.24 |
Sample | Total Cumulative Volume (mm3/g) | Specific Surface Area (m2/g) | Average Pore Radius (μm) | Total Porosity (%) | Bulk Density (g/cm3) |
---|---|---|---|---|---|
L_M8,5 | 228.16 | 9.79 | 0.62 | 36.40 | 1.60 |
L_M8,5s | 214.58 | 9.06 | 0.48 | 34.87 | 1.62 |
NHL_M1 | 153.97 | 4.66 | 0.37 | 28.58 | 1.86 |
Pl.Br.1 | 239.44 | 4.34 | 0.66 | 37.16 | 1.55 |
Pl.Br.2 | 192.16 | 4.85 | 0.63 | 32.91 | 1.71 |
Historical mortars | 194–418 | 19.5–49.5 | 0.013–0.047 | 31.6–48.1 | 1.11–1.63 |
Restoration Mortar | Age (days) | Flexural Strength (Mpa) | StDev | Compressive Strength (Mpa) | StDev |
---|---|---|---|---|---|
L_M8,5 | 14 | 0.92 | 0.08 | 5.25 | 0.47 |
28 | 1.58 | 0.07 | 6.65 | 0.45 | |
90 | 1.37 | 0.21 | 5.90 | 0.14 | |
L_M8,5_s | 14 | 1.31 | 0.48 | 6.33 | 0.73 |
28 | 1.75 | 0.16 | 9.27 | 0.53 | |
90 | 1.12 | 0.66 | 7.47 | 0.39 | |
NHL_M1 | 14 | 1.24 | 0.04 | 2.87 | 0.10 |
28 | 1.31 | 0.06 | 4.48 | 0.10 | |
90 | 1.62 | 0.13 | 5.52 | 0.17 | |
Pl.Br.1 | 14 | 0.46 | 0.02 | 0.00 | 0.00 |
28 | 1.41 | 0.15 | 2.83 | 0.21 | |
90 | 2.83 | 0.12 | 7.08 | 0.26 | |
Pl.Br.2 | 14 | 0.84 | 0.12 | 2.80 | 0.06 |
28 | 0.85 | 0.04 | 4.83 | 0.18 | |
90 | 0.83 | 0.14 | 7.67 | 0.36 |
Mortar | Pull-off Force (kN) | Mortar Adhesive Strength (MPa) | Area of Detachement |
---|---|---|---|
NHL_M1 | 0.229 | 0.09 | Mortar and stone detached from upper surface of pavement stone, mortar presents adhesion to stone tile after detachment (Figure 9d) |
Pl.Br.1 | 0 | 0 | Mortar completely detached from pavement stone – then easily detached manually from stone tile (Figure 9b) |
Pl.Br.2 | 0.371 | 0.15 | Stone tile and upper part of mortar were detached from lower part of mortar and pavement stone (as in Figure 9d) |
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Apostolopoulou, M.; Nikolaidis, I.; Grillakis, I.; Kalofonou, M.; Keramidas, V.; Delegou, E.T.; Karoglou, M.; Bakolas, A.; Lampropoulos, K.C.; Mouzakis, C.; et al. The Plaka Bridge in Epirus: An Evaluation of New Building Materials for Its Restoration. Heritage 2019, 2, 1136-1159. https://doi.org/10.3390/heritage2020074
Apostolopoulou M, Nikolaidis I, Grillakis I, Kalofonou M, Keramidas V, Delegou ET, Karoglou M, Bakolas A, Lampropoulos KC, Mouzakis C, et al. The Plaka Bridge in Epirus: An Evaluation of New Building Materials for Its Restoration. Heritage. 2019; 2(2):1136-1159. https://doi.org/10.3390/heritage2020074
Chicago/Turabian StyleApostolopoulou, Maria, Ioannis Nikolaidis, Iakovos Grillakis, Myrto Kalofonou, Vasileios Keramidas, Ekaterini T. Delegou, Maria Karoglou, Asterios Bakolas, Kyriakos C. Lampropoulos, Charalampos Mouzakis, and et al. 2019. "The Plaka Bridge in Epirus: An Evaluation of New Building Materials for Its Restoration" Heritage 2, no. 2: 1136-1159. https://doi.org/10.3390/heritage2020074