A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes

Arif Idris Ismiev; Gunay Zakhid Mamedova; Victor V. Dotsenko; Nikolai A. Aksenov; Inna V. Aksenova; Abel Mamedali Magerramov

doi:10.3390/ecsoc-22-05794

,

and

¹

Department of Chemistry, Baku State University, Akademik Zahid Xəlilov küçəsi-23, Baku 1148, Azerbaijan

²

Department of Chemistry and High Technologies, Kuban State University, 149 Stavropolskaya Str., 350040 Krasnodar, Russia

³

Department of Chemistry, North Caucasus Federal University, 1a Pushkina Str., 355009 Stavropol, Russia

⁴

ChemEx Lab, Vladimir Dal’ Lugansk National University, 20A Molodezhny, 91034 Lugansk, Russia

Proceedings2019, 9(1), 1;https://doi.org/10.3390/ecsoc-22-05794

This article belongs to the Proceedings 22nd International Electronic Conference on Synthetic Organic Chemistry

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Abstract

The reaction of furfural with secondary amines and isopropyl cyanoacetate leads to the formation of the previously unknown diisopropyl 8-(dialkylamino)-2,4-dicyano-3-(2-furyl)-6- oxobicyclo[3.2.1]octane-2,4-dicarboxylates. The structures of the products were confirmed by NMR and X-ray analysis.

Keywords:

furfural; isopropyl cyanoacetate; Stenhouse salt; Nazarov reaction; carbocyclization; bicyclo[3.2.1]octane

A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes^†

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A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes †

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A New Approach to the Synthesis of Functionalized Bicyclo[3.2.1]octanes^†