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Proceeding Paper

Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols †

by
Mireia Toledano-Pinedo
1,*,
Hristo Anatóliev
1,
Teresa Martínez del Campo
1 and
Pedro Almendros
2
1
Grupo de Lactamas y Heterociclos Bioactivos, Unidad Asociada al CSIC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain
2
Instituto de Química Orgánica General, IQOG-CSIC, Juan de la Cierva 3, 28006-Madrid, Spain
*
Author to whom correspondence should be addressed.
†
Presented at the 23rd International Electronic Conference on Synthetic Organic Chemistry, 15 November–15 December 2019; Available online: https://ecsoc-23.sciforum.net/.
Proceedings 2019, 41(1), 58; https://doi.org/10.3390/ecsoc-23-06467
Published: 14 November 2019
(This article belongs to the Proceedings of The 23rd International Electronic Conference on Synthetic Organic Chemistry)
Versions Notes

Abstract

We report herein a study on the Ag/Cu-catalyzed reactivity of α-allenols. The focus was the development of new methodologies for cyclization and/or transposition of this moiety. By simple solvent switch, the divergent preparation of dihydrofurans and 3-halo-3-alkenals in a controlled manner has been reached.
Keywords: allene; dihydrofurans and 3-halo-3-alkenals allene; dihydrofurans and 3-halo-3-alkenals

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MDPI and ACS Style

Toledano-Pinedo, M.; Anatóliev, H.; Campo, T.M.d.; Almendros, P. Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols. Proceedings 2019, 41, 58. https://doi.org/10.3390/ecsoc-23-06467

AMA Style

Toledano-Pinedo M, Anatóliev H, Campo TMd, Almendros P. Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols. Proceedings. 2019; 41(1):58. https://doi.org/10.3390/ecsoc-23-06467

Chicago/Turabian Style

Toledano-Pinedo, Mireia, Hristo Anatóliev, Teresa Martínez del Campo, and Pedro Almendros. 2019. "Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols" Proceedings 41, no. 1: 58. https://doi.org/10.3390/ecsoc-23-06467

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