A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis Methode of the PAANa
2.3. Characterization of PAANa
2.4. Lithium Battery Manufacturing and Performance
3. Results
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
- Kang, J.; Kwon, J.Y.; Han, D.Y.; Park, S.; Ryu, J. Customizing polymeric binders for advanced lithium batteries: Design principles and beyond. Appl. Phys. Rev. 2024, 11. [Google Scholar] [CrossRef]
- Deng, L.; Liu, J.-K.; Wang, Z.; Lin, J.-X.; Liu, Y.-X.; Bai, G.-Y.; Zheng, K.-G.; Zhou, Y.; Sun, S.-G.; Li, J.-T. A Formula to Customize Cathode Binder for Lithium Ion Battery. Adv. Energy Mater. 2024, 14, 2401514. [Google Scholar] [CrossRef]
- Hong, S.-B.; Jang, Y.-R.; Kim, H.; Jung, Y.-C.; Shin, G.; Hah, H.J.; Cho, W.; Sun, Y.-K.; Kim, D.-W. Wet-Processable Binder in Composite Cathode for High Energy Density All-Solid-State Lithium Batteries. Adv. Energy Mater. 2024, 14, 2400802. [Google Scholar] [CrossRef]
- Chen, B.; Zhang, Z.; Xiao, M.; Wang, S.; Huang, S.; Han, D.; Meng, Y. Polymeric Binders Used in Lithium Ion Batteries: Actualities, Strategies and Trends. ChemElectroChem 2024, 11, e202300651. [Google Scholar] [CrossRef]
- Jiang, X.; Li, T.; Dong, A.; Yang, D. Synthesis and Evaluation of Poly (Trifluoroethyl Methacrylate) Binders as a Polyvinylidene Fluoride Alternative for Lithium-Ion Batteries. Energy Technol. 2024, 12, 2400511. [Google Scholar] [CrossRef]
- Zhong, S.; Huang, Y.; Zhang, F.; Wang, H.; Liu, P.; Liu, J.; Li, Z.; Li, Y.; Lu, Z. Dextran Sulfate Sodium as Multifunctional Aqueous Binder Stabilizes Spinel LiMn2O4 for Lithium Ion Batteries. Adv. Funct. Mater. 2025, 35, 2414602. [Google Scholar] [CrossRef]
- Si, M.; Jian, X.; Xie, Y.; Zhou, J.; Jian, W.; Lin, J.; Luo, Y.; Hu, J.; Wang, Y.-J.; Zhang, T.D.; et al. A Highly Damping, Crack-Insensitive and Self-Healable Binder for Lithium-Sulfur Battery by Tailoring the Viscoelastic Behavior. Adv. Energy Mater. 2024, 14, 2303991. [Google Scholar] [CrossRef]
- Wang, W.; Hua, L.; Zhang, Y.; Wang, G.; Li, C. A Conductive Binder Based on Mesoscopic Interpenetration with Polysulfides Capturing Skeleton and Redox Intermediates Network for Lithium Sulfur Batteries. Angew. Chem. Int. Ed. 2024, 63, e202405920. [Google Scholar] [CrossRef] [PubMed]
- Patra, A.; Matsumi, N. Densely Imidazolium Functionalized Water Soluble Poly(Ionic Liquid) Binder for Enhanced Performance of Carbon Anode in Lithium/Sodium-Ion Batteries. Adv. Energy Mater. 2025, 15, 2403071. [Google Scholar] [CrossRef]
- Su, Z.; Li, G.; Zhang, J. Coaxial Nanofiber Binders Integrating Thin and Robust Sulfide Solid Electrolytes for High-Performance All-Solid-State Lithium Battery. Adv. Funct. Mater. 2025, 35, 2415409. [Google Scholar] [CrossRef]
- Trivedi, S.; Pamidi, V.; Bautista, S.P.; Shamsudin, F.N.A.; Weil, M.; Barpanda, P.; Bresser, D.; Fichtner, M. Water-Soluble Inorganic Binders for Lithium-Ion and Sodium-Ion Batteries (Adv. Energy Mater. 9/2024). Adv. Energy Mater. 2024, 14, 2470041. [Google Scholar] [CrossRef]
- Gupta, A.; Badam, R.; Mantripragada, B.S.; Mishra, S.N.; Matsumi, N. Ultra-Durability and Reversible Capacity of Silicon Anodes with Crosslinked Poly-BIAN Binder in Lithium-Ion Secondary Batteries for Sturdy Performance. Adv. Sustain. Syst. 2025, 9, 2400263. [Google Scholar] [CrossRef]
- Yang, K.; Chen, K.; Zhang, X.; Gao, S.; Sun, J.; Gong, J.; Chai, J.; Zheng, Y.; Liu, Z.; Wang, H. Exploring Phenolphthalein Polyarylethers as High-Performance Alternative Binders for High-Voltage Cathodes in Lithium-Ion Batteries. Small 2024, 20, 2403993. [Google Scholar] [CrossRef] [PubMed]
- Dou, W.; Zheng, M.; Zhang, W.; Liu, T.; Wang, F.; Wan, G.; Liu, Y.; Tao, X. Review on the Binders for Sustainable High-Energy-Density Lithium Ion Batteries: Status, Solutions, and Prospects. Adv. Funct. Mater. 2023, 33, 2305161. [Google Scholar] [CrossRef]
- Zhang, S.S. Impact of Binder Content and Type on the Electrochemical Performance of Silicon Anode Materials. ChemPhysChem 2024, 25, e202400570. [Google Scholar] [CrossRef] [PubMed]
- Wang, W.; Yue, X.; Meng, J.; Wang, X.; Zhou, Y.; Wang, Q.; Fu, Z. Comparative Study of Water-Based LA133 and CMC/SBR Binders for Sulfur Cathode in Advanced Lithium–Sulfur Batteries. J. Phys. Chem. C 2019, 123, 250–257. [Google Scholar] [CrossRef]
- Tatara, R.; Umezawa, T.; Kubota, K.; Horiba, T.; Takaishi, R.; Hida, K.; Matsuyama, T.; Yasuno, S.; Komaba, S. Effect of Substituted Styrene-Butadiene Rubber Binders on the Stability of 4.5 V-Charged LiCoO2 Electrode. ChemElectroChem 2021, 8, 4345–4352. [Google Scholar] [CrossRef]
- Müllner, S.; Michlik, T.; Reichel, M.; Held, T.; Moos, R.; Roth, C. Effect of Water-Soluble CMC/SBR Binder Ratios on Si-rGO Composites Using µm- and nm-Sized Silicon as Anode Materials for Lithium-Ion Batteries. Batteries 2023, 9, 248. [Google Scholar] [CrossRef]
- Jin, B.; Li, Y.; Qian, J.; Zhan, X.; Zhang, Q. Environmentally Friendly Binders for Lithium-Sulfur Batteries. ChemElectroChem 2020, 7, 4158–4176. [Google Scholar] [CrossRef]
- Oli, N.; Choudhary, S.; Weiner, B.R.; Morell, G.; Katiyar, R.S. Comparative Investigation of Water-Based CMC and LA133 Binders for CuO Anodes in High-Performance Lithium-Ion Batteries. Molecules 2024, 29, 4114. [Google Scholar] [CrossRef] [PubMed]
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Feng, L.; Chen, W.; Hai, F.; Gao, X.; Ban, Y.; Xue, W.; Yan, W.; Yang, Y.; Li, M. A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries 2025, 11, 190. https://doi.org/10.3390/batteries11050190
Feng L, Chen W, Hai F, Gao X, Ban Y, Xue W, Yan W, Yang Y, Li M. A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries. 2025; 11(5):190. https://doi.org/10.3390/batteries11050190
Chicago/Turabian StyleFeng, Lianxiang, Wenting Chen, Feng Hai, Xin Gao, Yuyu Ban, Weicheng Xue, Wentao Yan, Yunxiao Yang, and Mingtao Li. 2025. "A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries" Batteries 11, no. 5: 190. https://doi.org/10.3390/batteries11050190
APA StyleFeng, L., Chen, W., Hai, F., Gao, X., Ban, Y., Xue, W., Yan, W., Yang, Y., & Li, M. (2025). A Modified Acrylic Binder Used for the Graphite Negative Electrode in LithiumIon Batteries. Batteries, 11(5), 190. https://doi.org/10.3390/batteries11050190