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Stepwise Synthesis, Hydrogen-Bonded Supramolecular Structure, and Magnetic Property of a Co–Mn Heterodinuclear Complex

Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
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Magnetochemistry 2019, 5(1), 5; https://doi.org/10.3390/magnetochemistry5010005
Received: 31 December 2018 / Revised: 13 January 2019 / Accepted: 14 January 2019 / Published: 20 January 2019
(This article belongs to the Special Issue Coordination Compounds for Coordination Molecule-Based Devices)
A cobalt(III)–manganese(II) heterometallic dinuclear complex, [MnII{CoIII(µ-Himn)3}Cl2(CH3OH)], was prepared by a metalloligand approach. X-ray crystallographic analysis indicated that the metalloligand [CoIII(Himn)3] underwent mer/fac geometrical isomerization upon coordination to a Mn ion. Owing to the non-coordinating N–H bonds in the [CoIII(Himn)3] moiety, the heterodinuclear complex exhibited hydrogen bond interactions with the Cl ligand of the neighboring complex to construct two-dimensional hydrogen-bond networks. The bond distances around the Mn center and the χMT value at 300 K indicate that the Mn center is in a divalent state. The temperature dependence of the χMT product and field dependence of the magnetization showed the isotropic nature of the MnII center. View Full-Text
Keywords: cobalt(III)–manganese(II) heterometallic complex; Crystal structure; magnetism; hydrogen-bonded supramolecular structure cobalt(III)–manganese(II) heterometallic complex; Crystal structure; magnetism; hydrogen-bonded supramolecular structure
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Mitsuhashi, R.; Ueda, T.; Mikuriya, M. Stepwise Synthesis, Hydrogen-Bonded Supramolecular Structure, and Magnetic Property of a Co–Mn Heterodinuclear Complex. Magnetochemistry 2019, 5, 5.

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