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Open AccessArticle

A Co(II)-Hydrazone Schiff Base Single Ion Magnet Exhibiting Field Induced Slow Relaxation Dynamics

1
Centre de Recherche Paul Pascal, Université de Bordeaux, UMR 5031, 115 Avenue du Dr. A. Schweitzer, 33600 Pessac, France
2
Institute of Biological Chemistry, Washington State University, Pullman, WA 99164, USA
3
Instituto de Ciencia Molecular (ICMol), Dpto. Química Inorgánica, Universidad de Valencia, 46980 Paterna, Spain
*
Author to whom correspondence should be addressed.
Dedicated to the memory of Professor Samiran Mitra: an inspiring mentor and researcher.
Magnetochemistry 2018, 4(4), 56; https://doi.org/10.3390/magnetochemistry4040056
Received: 30 October 2018 / Revised: 27 November 2018 / Accepted: 1 December 2018 / Published: 7 December 2018
(This article belongs to the Special Issue A Themed Issue in Honor of Late Professor Samiran Mitra)
An octahedral Co(II) complex with N′-(2-hydroxybenzylidene)acetohydrazide Schiff base ligand [HL] forms a 3D supramolecular assembly supported by non-coordinating ClO4 ions and H2O molecules. Individual spin centres are non-interacting and give rise to significant spin-orbit coupling, resulting in field induced slow magnetisation relaxation; which is characteristic of Single Ion Magnet (SIM) behaviour. View Full-Text
Keywords: Co(II)-Hydrazone complex; Single ion magnet; slow magnetic relaxation; magnetic anisotropy; Supramolecular interaction Co(II)-Hydrazone complex; Single ion magnet; slow magnetic relaxation; magnetic anisotropy; Supramolecular interaction
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MDPI and ACS Style

Sadhukhan, D.; Ghosh, P.; Gómez-García, C.J.; Rouzieres, M. A Co(II)-Hydrazone Schiff Base Single Ion Magnet Exhibiting Field Induced Slow Relaxation Dynamics. Magnetochemistry 2018, 4, 56. https://doi.org/10.3390/magnetochemistry4040056

AMA Style

Sadhukhan D, Ghosh P, Gómez-García CJ, Rouzieres M. A Co(II)-Hydrazone Schiff Base Single Ion Magnet Exhibiting Field Induced Slow Relaxation Dynamics. Magnetochemistry. 2018; 4(4):56. https://doi.org/10.3390/magnetochemistry4040056

Chicago/Turabian Style

Sadhukhan, Dipali; Ghosh, Prithwi; Gómez-García, Carlos J.; Rouzieres, Mathieu. 2018. "A Co(II)-Hydrazone Schiff Base Single Ion Magnet Exhibiting Field Induced Slow Relaxation Dynamics" Magnetochemistry 4, no. 4: 56. https://doi.org/10.3390/magnetochemistry4040056

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