1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization
Abstract
:1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
Supplementary Materials
Author Contributions
Conflicts of Interest
References
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Complex | 1 | 2 | 3 |
---|---|---|---|
Formula | C35H22F12O10S4Tb | C35H22F12O10S4Dy | C35H22F12O10S4Yb |
Mr/g mol−1 | 1117.70 | 1121.27 | 1131.80 |
Crystal system | Monoclinic | Monoclinic | Monoclinic |
Space group | C2/c | C2/c | C2/c |
a/Å | 35.9505(106) | 35.8577(39) | 36.0071(168) |
b/Å | 10.3997(30) | 10.3531(8) | 10.3359(46) |
c/Å | 10.4496(30) | 10.4158(11) | 10.3599(48) |
β/° | 95.9205(35) | 96.0006(50) | 95.5797(64) |
V/Å3 | 3886.0(2) | 3845.6(5) | 3837.3(3) |
Z | 4 | 4 | 4 |
T/K | 93.15 | 93.15 | 96.15 |
Diffraction reflection | 4.118 ≤ 2θ ≤ 27.576 | 4.099 ≤ 2θ ≤ 27.523 | 4.005 ≤ 2θ ≤ 27.431 |
ρcalcd/g cm−3 | 1.910 | 1.937 | 1.959 |
μ/mm−1 | 2.150 | 2.277 | 2.771 |
Number of reflections | 7573 | 15193 | 7322 |
Independent reflections | 4395 | 4439 | 4243 |
F02 ˃ 2σ(F0)2 | 3847 | 3941 | 2506 |
Number of variables | 322 | 322 | 285 |
Rint, R1, wR2 | 0.0226, 0.0271, 0.0599 | 0.0321, 0.0252, 0.0544 | 0.0850, 0.0827, 0.2130 |
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Yatoo, M.A.; Cosquer, G.; Morimoto, M.; Irie, M.; Breedlove, B.K.; Yamashita, M. 1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization. Magnetochemistry 2016, 2, 21. https://doi.org/10.3390/magnetochemistry2020021
Yatoo MA, Cosquer G, Morimoto M, Irie M, Breedlove BK, Yamashita M. 1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization. Magnetochemistry. 2016; 2(2):21. https://doi.org/10.3390/magnetochemistry2020021
Chicago/Turabian StyleYatoo, Mudasir Ahmad, Goulven Cosquer, Masakazu Morimoto, Masahiro Irie, Brian K. Breedlove, and Masahiro Yamashita. 2016. "1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization" Magnetochemistry 2, no. 2: 21. https://doi.org/10.3390/magnetochemistry2020021
APA StyleYatoo, M. A., Cosquer, G., Morimoto, M., Irie, M., Breedlove, B. K., & Yamashita, M. (2016). 1D Chains of Lanthanoid Ions and a Dithienylethene Ligand Showing Slow Relaxation of the Magnetization. Magnetochemistry, 2(2), 21. https://doi.org/10.3390/magnetochemistry2020021