Extraction of Palladium(II) with a Magnetic Sorbent Based on Polyvinyl Alcohol Gel, Metallic Iron, and an Environmentally Friendly Polydentate Phosphazene-Containing Extractant
Abstract
:1. Introduction
2. Results and Discussion
3. Conclusions
4. Materials and Methods
4.1. Materials
4.2. Methods
4.3. Synthesis of Hexakis-[4-{(N-allylimino)methyl}-phenoxy]-cyclotriphosphazene
4.4. Synthesis of Hexakis-[4-{α,α-(N-allylamino)(O,O-diethylphosphoryl)methylidine}phenoxy]cyclotriphosphazene (Extractant)
4.5. Extraction of Palladium with the Developed Extractant
4.6. Synthesis of Sorbents
4.7. Sorption of Palladium by the Developed Sorbent
4.8. Stripping of Palladium
4.9. Sorption of Palladium by the Developed Gel in the Presence of Copper
4.10. Synthesis of a Magnetic Sorbent Containing Acid-Resistant Iron
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Chemical Element | Actual Content | Theoretical Content | ||
---|---|---|---|---|
Weight | Atomic | Weight | Atomic | |
C | 41.01 | 32.24 | 41.05 | 32.17 |
N | 5.15 | 3.47 | 5.13 | 3.45 |
O | 15.7 | 9.25 | 15.63 | 9.20 |
P | 11.23 | 3.42 | 11.34 | 3.45 |
Cl | 8.65 | 2.30 | 8.67 | 2.30 |
Pd | 13.1 | 1.17 | 13.00 | 1.15 |
H | 5.16 | 48.15 | 5.18 | 48.28 |
Optical Density, Units | Number of Microorganisms, CFU mL−1 | ||
---|---|---|---|
Bacteria | Yeast and Fungi | ||
Control | 9.03 | 8.0 × 109 | 6.0 × 105 |
Sample | 9.29 | 1.29 × 1010 | 2.6 × 106 |
No. | Gelation Time | Displaced Liquid, wt % | Water Uptake, wt % |
---|---|---|---|
1. | 1 day | 0 | 54.7 |
2. | 1 day | 23.4 | 53.4 |
3. | 12 h | 43.1 | 45.1 |
4. | 7 h | 71.6 | 39.4 |
5. | 5 h | 75.1 | 22.1 |
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Yudaev, P.; Butorova, I.; Stepanov, G.; Chistyakov, E. Extraction of Palladium(II) with a Magnetic Sorbent Based on Polyvinyl Alcohol Gel, Metallic Iron, and an Environmentally Friendly Polydentate Phosphazene-Containing Extractant. Gels 2022, 8, 492. https://doi.org/10.3390/gels8080492
Yudaev P, Butorova I, Stepanov G, Chistyakov E. Extraction of Palladium(II) with a Magnetic Sorbent Based on Polyvinyl Alcohol Gel, Metallic Iron, and an Environmentally Friendly Polydentate Phosphazene-Containing Extractant. Gels. 2022; 8(8):492. https://doi.org/10.3390/gels8080492
Chicago/Turabian StyleYudaev, Pavel, Irina Butorova, Gennady Stepanov, and Evgeniy Chistyakov. 2022. "Extraction of Palladium(II) with a Magnetic Sorbent Based on Polyvinyl Alcohol Gel, Metallic Iron, and an Environmentally Friendly Polydentate Phosphazene-Containing Extractant" Gels 8, no. 8: 492. https://doi.org/10.3390/gels8080492