Preliminary Study of Australian Pinot Noir Wines by Colour and Volatile Analyses, and the Pivot© Profile Method Using Wine Professionals
Abstract
:1. Introduction
2. Materials and Methods
2.1. Selected Wines
2.1.1. Basic Oenological Attributes
2.1.2. Vineyard Sites
2.2. Pivot© Profile
2.3. Headspace Solid-Phase Microextraction-Gas Chromatography-Mass Spectrometry
2.3.1. Esters, Alcohols and Fatty Acids
2.3.2. C13-Norisoprenoids
2.4. Chromatic Components and Colour Structure Analysis
2.5. Data Analysis
3. Results and Discussion
3.1. Volatile Analysis
3.2. Chromatic and Colour Structure Analysis
3.3. Principal Component Analysis
3.4. Sensory Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Region | State | Vintage | Alc. % (v/v) | pH | Titratable Acidity (g L−1) |
---|---|---|---|---|---|
Adelaide Hills | SA | 2018 | 13.8 ± 0.6 | 3.9 ± 0.2 | 5.14 ± 0.35 |
Yarra Valley | VIC | 2018 | 13.4 ± 0.3 | 3.7 ± 0.1 | 5.43 ± 0.36 |
Mornington Peninsula | VIC | 2018 | 13.8 ± 0.3 | 3.7 ± 0.1 | 5.88 ± 0.18 |
Northern Tasmania | TAS | 2018 | 13.3 ± 0.3 | 3.6 ± 0.2 | 5.83 ± 0.51 |
Southern Tasmania | TAS | 2018 | 13.6 ± 0.2 | 3.8 ± 0.1 | 5.56 ± 0.28 |
Region | State | Altitude (m a.s.l.) | GDD (days) 1 | GST (°C) 2 | January (°C) 3 | February (°C) 4 | Rainfall (mm) 5 |
---|---|---|---|---|---|---|---|
Adelaide Hills | SA | 340–540 | 1923 ± 117 | 19.1 ± 0.6 | 22.3 ± 0.6 | 21.5 ± 0.6 | 236 ± 33 |
Yarra Valley | VIC | 150–210 | 1766 ± 27 | 18.3 ± 0.2 | 21.4 ± 0.2 | 20.8 ± 0.2 | 453 ± 17 |
Mornington Peninsula | VIC | 90–240 | 1697 ± 70 | 18.0 ± 0.3 | 20.7 ± 0.4 | 20.2 ± 0.4 | 348 ± 11 |
Northern Tasmania | TAS | 25–150 | 1303 ± 29 | 16.1 ± 0.1 | 19.0 ± 0.2 | 17.9 ± 0.2 | 318 ± 24 |
Southern Tasmania | TAS | <50 | 1210 ± 133 | 15.7 ± 0.6 | 18.4 ± 0.6 | 16.4 ± 0.5 | 317 ± 56 |
Analyte | Odour Threshold (µg L−1) and Descriptor/s | Adelaide Hills | Yarra Valley | Mornington Peninsula | Northern Tasmania | Southern Tasmania | Odour Activity Value (min–max) | p |
---|---|---|---|---|---|---|---|---|
Higher Alcohols | ||||||||
2-Methylpropanol (mg L−1) | 40 1 (mg L−1) (solvent) | 69 ± 20 | 66 ± 3 | 75 ± 8 | 100 ± 38 | 78 ± 15 | 1.6–2.5 | ns |
3-Methylbutanol (mg L−1) | 30 1 (mg L−1) (solvent) | 168 ± 20 | 183 ± 34 | 176 ± 33 | 254 ± 68 | 197 ± 29 | 5.6–8.5 | ns |
2-Methylbutanol (mg L−1) | 1.2 2 (mg L−1) (solvent) | 80 ± 7 | 94 ± 17 | 97 ± 12 | 130 ± 40 | 105 ± 16 | 67–108 | ns |
2-Phenylethanol (mg L−1) | 10 1 (mg L−1); 14 3 (mg L−1) (floral) | 21 ± 8 | 22 ± 7 | 24 ± 7 | 29 ± 4 | 19 ± 5 | 1.9–2.9; 1.3–2.1 | ns |
1-Hexanol | 8000 1 (cut grass) | 1829 ± 595 | 1629 ± 297 | 1622 ± 770 | 1968 ± 779 | 2350 ± 924 | 0.20–0.29 | ns |
Butanol | 150,000 2 (fusel) | 1789 ± 894 | 1648 ± 259 | 1282 ± 123 | 1302 ± 127 | 2122 ± 1016 | 0.01 | ns |
Total (mg L−1) | - | 342 ± 56 | 368 ± 61 | 375 ± 61 | 516 ± 151 | 403 ± 67 | - | ns |
Ethyl Esters | ||||||||
Ethyl propanoate | 9000 2 (fruity) | 205 ± 40 | 189 ± 56 | 170 ± 18 | 183 ± 18 | 177 ± 35 | 0.02 | ns |
Ethyl butanoate | 20 1 (acid fruit, apple) | 238 ± 90 | 272 ± 4 | 166 ± 43 | 196 ± 41 | 258 ± 88 | 8.3–12.9 | ns |
Ethyl hexanoate | 5 1; 14 3 (green apple) | 346 ± 121 | 415 ± 46 | 257 ± 75 | 326 ± 26 | 431 ± 74 | 51–86; 18.3–30.8 | ns |
Ethyl octanoate | 2 1, 5 3 (sweet, fruity) | 384 ± 114 | 495 ± 27 | 300 ± 117 | 350 ± 16 | 453 ± 83 | 150–247; 60–99 | ns |
Ethyl decanoate | 200 3 (grape) | 140 ± 61 abc | 218 ± 52 a | 100 ± 38 bc | 89 ± 12 c | 182 ± 35 ab | 0.44–1.09 | <0.05 |
Ethyl 2-methylpropanoate | 15 1 (sweet, fruity) | 121 ± 18 c | 178 ± 54 bc | 198 ± 28 ab | 255 ± 40 a | 149 ± 30 bc | 8.1–17.0 | <0.01 |
Ethyl 2-methylbutanoate | 1 1; 18 3 (apple) | 8.4 ± 1.1 b | 14.1 ± 6.3 ab | 14.1 ± 4.4 ab | 18.6 ± 1.0 a | 11.2 ± 0.1 b | 8.4–18.6; 0.47–1.03 | <0.05 |
Ethyl 3-methylbutanoate | 3 3 (fruity) | 11.8 ± 1.9 | 21.2 ± 9.3 | 20.6 ± 8.3 | 27.7 ± 4.0 | 15.0 ± 0.8 | 3.9–9.2 | ns |
Total (µg L−1) | - | 1454 ± 447 | 1802 ± 255 | 1226 ± 332 | 1445 ± 158 | 1676 ± 346 | - | ns |
Acetate Esters | ||||||||
Ethyl acetate (mg L−1) | 12.2 4 (mg L−1) (fruity) | 98 ± 13 | 102 ± 27 | 102 ± 14 | 88 ± 6 | 91 ± 18 | 7.2–8.3 | ns |
2-Methylpropyl acetate | 1600 2 (fruity) | 61 ± 6 | 62 ± 19 | 68 ± 12 | 79 ± 39 | 64 ± 17 | 0.04–0.05 | ns |
2-Methylbutyl acetate | 313 5a; 1083 5b (fruity) | 39.5 ± 5.3 | 50 ± 3 | 41.1 ± 5.6 | 58 ± 18 | 47.0 ± 10.8 | 0.13–0.18; 0.04–0.05 | ns |
3-Methylbutyl acetate | 300 1 (banana) | 170 ± 27 | 277 ± 67 | 176 ± 42 | 288 ± 127 | 232 ± 92 | 0.57–0.96 | ns |
Total (mg L−1) | - | 98 ± 13 | 102 ± 27 | 102 ± 14 | 88 ± 6 | 91 ± 18 | - | ns |
Acids | ||||||||
2-Methylbutanoic acid | 2200 2 (cheesy) | 286 ± 11 | 317 ± 120 | 317 ± 58 | 443 ± 104 | 311 ± 45 | 0.13–0.20 | ns |
3-Methylbutanoic acid | 33.4 3 (blue cheese) | 386 ± 17 | 448 ± 150 | 433 ± 115 | 643 ± 180 | 436 ± 81 | 11.5–19.2 | ns |
2-Methylpropanoic acid | 2300 3 (cheese, rancid) | 1324 ± 184 | 1292 ± 177 | 1439 ± 212 | 2000 ± 573 | 1470 ± 214 | 0.56–0.87 | ns |
Acetic acid (mg L−1) | 2 1 (mg L−1) (vinegar) | 688 ± 152 | 669 ± 102 | 617 ± 156 | 659 ± 146 | 659 ± 36 | 0.31–0.34 | ns |
Octanoic acid | 500 3 (cheese) | 1442 ± 517 | 1878 ± 251 | 1085 ± 483 | 1335 ± 58 | 1800 ± 405 | 2.2–3.8 | ns |
Decanoic acid | 1000 3 (rancid, fat) | 417 ± 147 b | 661 ± 130 a | 355 ± 145 b | 336 ± 22 b | 536 ± 19 ab | 0.34–0.66 | <0.05 |
Total (mg L−1) | - | 692 ± 153 | 673 ± 103 | 621 ± 157 | 664 ± 147 | 663 ± 37 | - | ns |
C13-Norisoprenoids | ||||||||
α-Ionone | NA | 1.30 ± 0.03 | 1.26 ± 0.05 | 1.35 ± 0.03 | 1.30 ± 0.04 | 1.21 ± 0.04 | - | ns |
β-Ionone | 0.09 3 (violet, floral) | 1.23 ± 0.07 | 1.12 ± 0.06 | 1.27 ± 0.09 | 1.19 ± 0.06 | 0.04 ± 0.16 | 0.45–14 | ns |
β-Damascenone | 0.05 1 (rose, honey) | 1.40 ± 0.35 | 0.96 ± 0.32 | 0.80 ± 0.21 | 1.41 ± 0.45 | 1.17 ± 0.46 | 16–28 | ns |
Total (µg L−1) | - | 3.93 ± 0.45 | 3.34 ± 0.43 | 3.42 ± 0.33 | 3.90 ± 0.55 | 2.42 ± 1.08 | ns |
Attribute | Adelaide Hills | Yarra Valley | Mornington Peninsula | Northern Tasmania | Southern Tasmania | p |
---|---|---|---|---|---|---|
Colour density (AU) | 4.57 ± 0.68 | 4.02 ± 0.68 | 3.70 ± 1.06 | 4.66 ± 1.26 | 4.20 ± 0.20 | ns |
Hue | 0.86 ± 0.07 a | 0.75 ± 0.02 bc | 0.81 ± 0.02 ab | 0.72 ± 0.06 c | 0.72 ± 0.03 c | <0.01 |
Chemical age 1 | 0.45 ± 0.02 a | 0.34 ± 0.04 c | 0.41 ± 0.02 ab | 0.36 ± 0.02 bc | 0.33 ± 0.04 c | <0.01 |
Chemical age 2 | 0.16 ± 0.02 a | 0.11 ± 0.03 b | 0.16 ± 0.02 a | 0.14 ± 0.01 ab | 0.11 ± 0.03 b | <0.05 |
Total anthocyanin (mg L−1) | 98 ± 13 ab | 114 ± 16 a | 76 ± 16 b | 109 ± 23 ab | 131 ± 23 a | <0.05 |
Non-bleachable pigment (AU) | 1.12 ± 0.22 | 0.80 ± 0.21 | 0.84 ± 0.29 | 0.99 ± 0.32 | 0.81 ± 0.12 | ns |
Total pigment (AU) | 6.78 ± 0.95 | 7.1± 0.9 | 5.23 ± 1.26 | 7.11 ± 1.70 | 7.89 ± 0.96 | ns |
(%) Non-bleachable pigment | 16.4 ± 1.6 a | 11.3 ± 2.8 b | 15.9 ± 2.4 a | 13.8 ± 1.3 ab | 10.6 ± 2.9 b | <0.05 |
Total phenolics (AU) | 34.1 ± 5.3 | 33.1 ± 3.2 | 39.3 ± 11.2 | 32.9 ± 10.4 | 28.0 ± 4.9 | ns |
Total tannins (g L−1) | 0.78 ± 0.41 | 0.72 ± 0.17 | 1.22 ± 0.63 | 0.87 ± 0.64 | 0.44 ± 0.30 | ns |
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Longo, R.; Pearson, W.; Merry, A.; Solomon, M.; Nicolotti, L.; Westmore, H.; Dambergs, R.; Kerslake, F. Preliminary Study of Australian Pinot Noir Wines by Colour and Volatile Analyses, and the Pivot© Profile Method Using Wine Professionals. Foods 2020, 9, 1142. https://doi.org/10.3390/foods9091142
Longo R, Pearson W, Merry A, Solomon M, Nicolotti L, Westmore H, Dambergs R, Kerslake F. Preliminary Study of Australian Pinot Noir Wines by Colour and Volatile Analyses, and the Pivot© Profile Method Using Wine Professionals. Foods. 2020; 9(9):1142. https://doi.org/10.3390/foods9091142
Chicago/Turabian StyleLongo, Rocco, Wes Pearson, Angela Merry, Mark Solomon, Luca Nicolotti, Hanna Westmore, Robert Dambergs, and Fiona Kerslake. 2020. "Preliminary Study of Australian Pinot Noir Wines by Colour and Volatile Analyses, and the Pivot© Profile Method Using Wine Professionals" Foods 9, no. 9: 1142. https://doi.org/10.3390/foods9091142