The Impact of the Fermentation Strategy on the Flavour Formation of Ilzer Rose (Malus domestica Borkh.) Apple Wine
Abstract
:1. Introduction
2. Materials and Methods
2.1. Fruit Material
2.2. Preparation of Juice Samples
2.3. Preparation of the Apple Wines
2.4. Analysis of Basic Fruit Wine Parameters
2.4.1. Sugar Concentration
2.4.2. Acidity
2.4.3. Sample Preparation and GC-MS Analysis
2.4.4. Sensory Evaluation
2.4.5. Statistical Analysis
3. Results and Discussion
3.1. Volatile Compounds Obtained from Apple Juice and Dependence on the Maceration Time
3.2. Investigation of the Apple Wines
3.2.1. Fermentation and Basic Apple Wine Parameters
3.2.2. Volatile Compounds from Apple Wines
3.2.3. Sensory Analysis
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Compound | RI [DB5] exp § | RI [DB5] lit. $ | Juice 0 h Maceration Mean ± SD [µg L−1] | Juice 2 h Maceration Mean ± SD [µg L−1] | Juice 5 h Maceration Mean ± SD [µg L−1] | Juice 8 h Maceration Mean ± SD [µg L−1] | Significance |
---|---|---|---|---|---|---|---|
acids | |||||||
acetic acid | 612 | 625 | 1.53 ± 0.3 | 0.72 ± 0.6 | 2.56 ± 0.2 | 1.37 ± 1.2 | No |
2-methyl butanoic acid | 842 | 856 | 25.3 ± 1.3 a | 15.9 ± 1.3 b | 17.7 ± 1.5 b | 20.4 ± 0.2 a,b | * |
hexanoic acid | 967 | 980 | 3.0 ± 0.0 c | 7.1 ± 0.1 b | 7.0 ± 0.2 b | 10.3 ± 0.3 a | ** |
alcohols | |||||||
1-propanol t | <600 | 548 | 1.94 ± 0.1 | 2.00 ± 0.7 | 2.96 ± 0.0 | 2.36 ± 0.6 | No |
2-butanol | 601 | 605 | 0.91 ± 0.0 | 0.81 ± 0.3 | 1.25 ± 0.0 | 1.17 ± 0.3 | No |
2-methyl Propanol | 628 | 654 | 2.92 ± 0.1 | 0.71 ± 0.8 | 1.20 ± 0.3 | 1.03 ± 1.1 | No |
1-butanol | 665 | 660 | 40.3 ± 3.1 b | 51.4 ± 2.7 a,b | 60.9 ± 1.6 a | 61.9 ± 2.7 a | * |
1-penten-3-ol | 684 | 686 | 0.34 ± 0.0 b | 0.92 ± 0.1 a | 0.95 ± 0.0 a | 1.14 ± 0.1 a | ** |
2-methyl-1-butanol | 739 | 743 | 67.5 ± 3.8 a | 84.1 ± 4.5 a,b | 78.0 ± 0.6 a,b | 93.6 ± 3.3 b | * |
1-pentanol | 767 | 766 | 0.36 ± 1.9 | 3.35 ± 0.5 | 3.68 ± 0.1 | 5.07 ± 0.2 | No |
2,3-butanediol | 780 | 773 | 1.38 ± 0.4 | 3.37 ± 1.7 | 4.31 ± 1.1 | 4.02 ± 1.1 | No |
3-hexen-1-ol (Z)- | 851 | 858 | 0.89 ± 0.5 c | 20.5 ± 0.5 b | 21.0 ± 0.1 b | 34.1 ± 2.5 a | ** |
2-hexen-1-ol (E)- | 866 | 887 | 12.6 ± 2.1 c | 356 ± 13.9 a,b | 317 ± 11.3 b | 394 ± 19.6 c | ** |
1-hexanol | 868 | 867 | 106.9 ± 0.2 b | 623 ± 43.4 a | 617 ± 23.1 a | 821 ± 60.6 a | ** |
1-heptanol | 967 | 970 | 8.02 ± 1.0 b | 24.0 ± 4.7 a | 27.3 ± 0.4 a | 29.6 ± 0.7 a | * |
1-octen-3-ol | 979 | 979 | 0.55 ± 0.0 b | 1.93 ± 0.1 a | 1.72 ± 0.0 a | 2.07 ± 0.1 a | ** |
methionol | 982 | 980 | 5.46 ± 0.2 a | 3.91 ± 0.2 b | 3.97 ± 0.3 a,b | 5.12 ± 0.3 a,b | * |
6-methyl-5-hepten-2-ol | 993 | 994 | 15.6 ± 1.0 c | 29.2 ± 1.5 b | 33.9 ± 0.9 a,b | 40.0 ± 2.2 a | ** |
2-ethyl hexanol | 1029 | 1028 | 2.01 ± 0.1 c | 3.58 ± 0.1 a | 3.00 ± 0.0 b | 3.74 ± 0.0 a | ** |
benzyl alcohol | 1042 | 1032 | 3.04 ± 0.3 d | 8.06 ± 0.2 c | 10.4 ± 0.3 b | 21.5 ± 0.2 a | ** |
1-octanol | 1069 | 1069 | 1.14 ± 0.1 d | 5.14 ± 0.1 c | 7.70 ± 0.1 b | 13.06 ± 0.3 a | ** |
3-octen-1-ol (Z)- | 1071 | 1047 | 1.85 ± 0.2 b | 5.96 ± 0.1 a | 6.30 ± 0.2 a | 8.03 ± 0.9 a | * |
phenylethyl alcohol | 1127 | 1113 | 2.29 ± 0.3 c | 3.12 ± 0.1 b,c | 3.69 ± 0.2 b | 6.04 ± 0.1 a | ** |
1,3-octanediol | 1264 | 1275 | 451 ± 24.3 b | 544 ± 20.3 a,b | 688 ± 24.4 a | 703 ± 71.1 a | * |
1-dodecanol | 1477 | 1475 | 6.60 ± 2.8 | 7.69 ± 1.6 | 6.18 ± 1.4 | 5.82 ± 1.0 | No |
carbonyls | |||||||
2,3-butanedione | 615 | 623 | 0.15 ± 0.0 c | 0.25 ± 0.0 b | 0.37 ± 0.0 a | 0.39 ± 0.0 a | ** |
butanal | 602 | 601 | 51.2 ± 0.0 | 1.45 ± 0.1 | 1.13 ± 0.0 | 1.33 ± 0.1 | No |
2-butanone | 600 | 600 | 2.79 ± 0.4 | 3.47 ± 0.4 | 3.54 ± 0.1 | 4.41 ± 0.7 | No |
1-penten-3-one | 687 | 687 | 0.55 ± 0.1 | 0.74 ± 0.1 | 0.65 ± 0.0 | 0.50 ± 0.0 | No |
2-pentanone | 688 | 695 | 2.76 ± 0.1 | 2.52 ± 0.3 | 2.69 ± 0.1 | 2.70 ± 0.3 | No |
2-pentenal (E)- | 756 | 748 | 0.62 ± 0.0 b | 1.10 ± 0.1 a | 0.61 ± 0.0 b | 0.51 ± 0.1 b | * |
3-hexenal (Z) | 797 | 795 | 10.3 ± 0.5 a | 6.44 ± 0.5 b | 2.78 ± 0.1 c | 2.67 ± 0.3 c | ** |
hexanal | 799 | 801 | 51.4 ± 2.2 a | 49.2 ± 3.0 a | 18.6 ± 0.1 b | 18.3 ± 1.2 b | ** |
2,4-hexadienal (E,E)- | 911 | 916 | 12.03 ± 0.8 a | 11.3 ± 1.1 a | 5.28 ± 0.3 b | 5.24 ± 0.3 b | ** |
2-heptenal (E)- | 960 | 964 | 1.47 ± 0.2 b | 3.40 ± 0.1 a | 3.16 ± 0.0 a | 2.83 ± 0.1 a | ** |
benzaldehyde | 972 | 961 | 5.03 ± 0.2 d | 25.5 ± 0.4 a | 13.7 ± 0.6 d | 22.0 ± 0.3 c | ** |
6-methyl-5-hepten-2-one | 988 | 988 | 4.03 ± 0.1 c | 10.7 ± 0.3 b | 13.3 ± 0.5 a,b | 14.8 ± 0.8 a | ** |
phenylacetaldehyde | 1055 | 1047 | 0.29 ± 0.1 b | 1.01 ± 0.1 a | 1.14 ± 0.0 a | 1.05 ± 0.0 a | * |
2-octenal (E)- | 1063 | 1063 | 5.69 ± 0.2 c | 9.54 ± 0.0 b | 9.88 ± 0.2 a,b | 10.7 ± 0.1 a | ** |
nonanal | 1107 | 1102 | 3.63 ± 1.8 | 6.45 ± 0.6 | 4.69 ± 0.4 | 4.98 ± 0.4 | No |
esters | |||||||
methyl acetate t | <600 | 522 | 0.22 ± 0.0 | 0.21 ± 0.0 | 0.34 ± 0.0 | 0.28 ± 0.1 | No |
ethyl acetate | 615 | 628 | 15.2 ± 0.4 | 15.9 ± 1.5 b | 20.9 ± 0.4 a,b | 23.3 ± 1.4 a | * |
propyl acetate | 715 | 695 | 0.50 ± 0.0 b | 0.59 ± 0.1 b | 0.64 ± 0.0 a,b | 1.02 ± 0.1 a | * |
methyl butanoate | 724 | 710 | 1.00 ± 0.1 | 0.81 ± 0.1 | 0.88 ± 0.0 | 0.84 ± 0.1 | No |
butyl acetate | 812 | 802 | 8.02 ± 0.1 b | 9.52 ± 0.9 b | 12.43 ± 0.4 a | 17.63 ± 1.2 a | * |
2-methyl butyl acetate | 877 | 880 | 24.5 ± 0.6 b | 36.7 ± 2.7 a,b | 40.8 ± 1.2 a | 49.3 ± 3.3 a | * |
pentyl acetate | 911 | 926 | 1.04 ± 0.1 d | 3.16 ± 0.1 c | 5.72 ± 0.0 b | 7.22 ± 0.3 a | ** |
ethyl-3-hydroxy-butanoate | 935 | 945 | 2.75 ± 0.1 b | 2.93 ± 0.1 a | 3.20 ± 0.3 a | 1.58 ± 0.1 a | * |
butyl butanoate | 995 | 1002 | 2.03 ± 0.1 b | 8.17 ± 0.8 a | 7.15 ± 0.1 a | 7.59 ± 0.7 a | * |
3-hexen-1-yl acetate (Z) | 1001 | 996 | 1.04 ± 0.4 d | 11.5 ± 0.5 c | 22.6 ± 0.4 b | 29.8 ± 2.2 a | ** |
2-hexen-1-yl acetate (E) | 1013 | 1017 | 5.83 ± 2.1 c | 195 ± 9.6 b | 244 ± 2.7 a | 237 ± 12.4 a,b | ** |
hexyl acetate | 1011 | 1011 | 18.5 ± 1.4 c | 153 ± 9.3 b | 279 ± 5.7 a | 315 ± 20.7 a | ** |
2-methyl butyl butanoate | 1042 | 1041 | 3.88 ± 0.6 b | 11.0 ± 0.9 a | 12.3 ± 0.3 a | 10.8 ± 1.1 a | * |
methyl octanoate | 1123 | 1129 | 0.18 ± 0.1 b | 2.10 ± 0.6 a | 0.57 ± 0.1 a,b | 0.41 ± 0.0 a,b | * |
hexyl-2-methylpropanoate | 1147 | 1138 | 0.30 ± 0.0 b | 1.92 ± 0.1 a | 2.23 ± 0.0 a | 2.54 ± 0.3 a | ** |
hexyl-2-methyl butanoate | 1238 | 1236 | 9.27 ± 0.8 c | 65.4 ± 0.1 b | 104 ± 0.4 a | 101 ± 5.9 a | ** |
pentyl hexanoate | 1287 | 1282 | 0.29 ± 0.0 b | 3.01 ± 0.0 a | 3.53 ± 0.1 a | 3.20 ± 0.3 a | ** |
butyl octanoate | 1387 | 1393 | 0.63 ± 0.1 c | 3.06 ± 0.1 b | 4.45 ± 0.1 a | 4.21 ± 0.0 a | ** |
hexyl hexanoate | 1386 | 1386 | 4.19 ± 0.3 c | 28.7 ± 1.5 b | 48.7 ± 1.7 a | 48.5 ± 0.6 a | ** |
3-methylbutyl octanoate | 1451 | 1450 | 0.16 ± 0.1 c | 0.67 ± 0.0 b,c | 1.43 ± 0.2 a | 1.11 ± 0.1 a,b | * |
methyljasmonate | 1672 | 1647 | 1.29 ± 0.2 | 0.89 ± 0.1 | 1.38 ± 0.2 | 1.15 ± 0.0 | No |
terpenoids | |||||||
2-methyl 1,3-pentadiene (E)- t | 669 | n/a | 0.12 ± 0.0 b | 0.88 ± 0.1 a | 0.87 ± 0.1 a | 1.11 ± 0.1 a | * |
linalool oxide isomer I t | 1084 | n/a | 11.6 ± 0.6 b | 22.2 ± 1.6 a | 26.8 ± 0.0 a | 26.9 ± 1.3 a | * |
linalool oxide isomer II t | 1099 | n/a | 11.5 ± 0.5 c | 19.9 ± 0.5 b | 23.4 ± 0.6 a | 23.2 ± 0.6 a | ** |
β-damascenone | 1408 | 1400 | 4.06 ± 0.2 | 4.25 ± 0.8 | 4.50 ± 0.9 | 5.72 ± 0.3 | No |
β-ionone | 1511 | 1493 | 4.74 ± 0.4 b | 7.25 ± 0.1 a | 6.27 ± 0.1 a | 7.32 ± 0.1 a | * |
α-farnesene | 1517 | 1508 | 21.4 ± 13.5 | 32.6 ± 4.5 | 60.0 ± 9.6 | 48.0 ± 4.4 | No |
miscellaneous | |||||||
2-ethylfuran | 703 | 702 | 1.52 ± 0.2 a | 1.28 ± 0.1 a,b | 0.84 ± 0.1 b | 0.73 ± 0.0 b | * |
2-pentylfuran | 995 | 991 | 0.67 ± 0.1 | 1.86 ± 0.5 | 1.59 ± 0.4 | 1.11 ± 0.3 | No |
hexanal dimethyl acetal | 978 | 980 | 6.95 ± 0.9 a | 7.02 ± 0.4 a | 1.81 ± 0.3 b | 1.90 ± 0.3 b | * |
Ethanol [%v/v] | Residual Sugar [g L−1] | Titratable Acid § [g L−1] | Malic Acid [g L−1] | Lactic Acid [g L−1] | |
---|---|---|---|---|---|
AW1 | 7.4 | <1.7 | 6.2 | 7.0 | n.d. |
AW2 | 7.3 | 2.5 | 6.8 | 7.4 | n.d. |
AW3 | 7.4 | 8.3 | 5.9 | 2.2 | 2.3 |
AW4 | 7.3 | 3.0 | 6.8 | 7.2 | n.d. |
AW5 | 7.2 | 8.1 | 5.8 | 2.1 | 2.3 |
Compound | RI [DB5] exp § | RI [DB5] lit. $ | AW1 Mean ± SD [µg L−1] | AW2 Mean ± SD [µg L−1] | AW3 Mean ± SD [µg L−1] | AW4 mean ± SD [µg L−1] | AW5 mean ± SD [µg L−1] | Significance |
---|---|---|---|---|---|---|---|---|
acids | ||||||||
3-methyl butanoic acid | 823 | 835 | 8.0 ± 1.2 c | 12.1 ± 0.8 a,b | 13.6 ± 0.6 a | 11.25 ± 0.2 b | 13.2 ± 1.1 a,b | ** |
2-methyl butanoic acid | 835 | 846 | 10.1 ± 2.1 c | 18.6 ± 0.3 b | 30.7 ± 2.5 a | 17.30 ± 1.7 b | 27.4 ± 2.5 a | ** |
hexanoic acid | 969 | 980 | 403 ± 45.7 a | 357 ± 22 a | 105 ± 8.7 b | 375.47 ± 12.4 a | 102 ± 12 b | ** |
octanoic acid | 1164 | 1178 | 721 ± 158 a | 889 ± 177 a | 169 ± 10.3 b | 977.1 ± 211.4 a | 152 ± 15 b | ** |
alcohols | ||||||||
2-methyl-1-butanol | 719 | 730 | 437 ± 38.3 c | 580 ± 16 b | 800 ± 84 a | 569 ± 22 b | 777 ± 15 a | ** |
3-methyl-1-butanol | 722 | 743 | 3526 ± 230 | 3 812 ± 417 | 3 648 ± 315 | 3 936 ± 87 | 3 864 ± 343 | no |
1-pentanol | 753 | 766 | 4.0 ± 0.2 c | 6.9 ± 0.3 b | 11.0 ± 1.2 c | 6.27 ± 0.6 b | 10.5 ± 0.3 c | ** |
2,3-butanediol | 779 | 773 | 54.0 ± 18.7 | 51.1 ± 27.9 | 24.7 ± 4.5 | 42.77 ± 13.5 | 18.3 ± 3.8 | no |
3-ethoxy-1-propanol | 836 | 816 | 58.7 ± 2.8 a | 27.7 ± 1.7 b | 5.9 ± 3.2 d | 18.73 ± 1.5 c | 4.1 ± 1.6 d | ** |
3-hexen-1-ol (E) | 848 | 858 | 3.8 ± 0.7 c | 17.2 ± 0.8 b | 22.0 ± 0.7 a | 16.14 ± 0.6 b | 21.3 ± 0.8 a | ** |
1-hexanol | 865 | 867 | 434 ± 31.4 c | 1 158 ± 48 b | 1 388 ± 78 a | 1 097 ± 23.8 b | 1 388 ± 59 a | ** |
1-heptanol | 968 | 970 | 0.9 ± 0.2 b | 1.5 ± 0.2 b | 19.6 ± 0.3 a | 1.38 ± 0.1 b | 18.9 ± 0.6 a | ** |
2-methyl-6-hepten-1-ol | 992 | 994 | 49.6 ± 2.0 c | 54.6 ± 2.3 c | 79.4 ± 5.0 a | 50.8 ± 2.3 c | 71.6 ± 1.8 b | ** |
3-ethyl-4-methylpentan-1-ol | 1024 | 1020 | 0.3 ± 0.1 c | 3.5 ± 0.1 b | 4.2 ± 0.3 c | 3.47 ± 0.1 b | 4.1 ± 0.1 c | ** |
2-ethylhexanol | 1029 | 1029 | 4.8 ± 0.4 | 5.8 ± 1.0 | 5.6 ± 0.2 | 5.98 ± 0.5 | 5.8 ± 0.2 | no |
benzyl alcohol | 1041 | 1032 | 1.2 ± 0.2 c | 5.1 ± 0.6 c | 76.4 ± 3.4 a | 4.84 ± 0.4 c | 67.7 ± 2.8 b | ** |
1-octanol | 1069 | 1069 | 4.3 ± 0.5 d | 18.1 ± 0.7 c | 33.9 ± 0.8 a | 17.19 ± 0.8 c | 30.9 ± 1.3 b | ** |
phenylethyl alcohol | 1127 | 1113 | 629 ± 48 a | 727 ± 55 a,b | 618 ± 17 b | 611 ± 39 b | 558 ± 20 b | * |
carbonyls | ||||||||
benzaldehyde | 971 | 961 | 6.8 ± 0.9 c | 11.1 ±1.3 b | 19.5 ±1.6 a | 10.3 ±0.3 b | 18.5 ± 0.8 a | ** |
nonanal | 1106 | 1101 | 8.5 ± 3.4 | 7.3 ± 3.2 | 6.6 ± 1.3 | 7.0 ± 5.8 | 5.8 ± 1.2 | no |
2-butanone | 601 | 600 | 9.5 ± 1.3 | 8.3 ±1.3 | 7.5 ±1.1 | 9.8 ±0.9 | 9.1 ±1.2 | No |
esters | ||||||||
ethyl acetate | 614 | 628 | 315 ± 63 a | 311 ± 52 a | 143 ± 32 b | 309 ± 20 a | 168 ± 20 b | ** |
ethyl propanoate | 692 | 706 | 1.4 ± 0.4 b | 2.5 ± 0.3 a,b | 3.3 ± 0.8 a | 2.0 ± 0.2 b | 3.12 ± 0.3 a | ** |
propyl acetate | 694 | 695 | 4.5 ± 1.0 a | 3.9 ± 0.4 a | 1.2 ± 0.2 b | 3.7 ± 0.4 a | 1.2 ± 0.2 b | ** |
ethyl butanoate | 791 | 808 | 31.3 ± 8.6 a | 36.5 ± 3.1 a | 6.4 ± 1.6 b | 30.5 ± 2.2 a | 5.5 ± 2.2 b | ** |
butyl acetate | 805 | 802 | 29.4 ± 5.4 a | 26.0 ± 1.7 a | 9.9 ± 0.5 b | 23.2 ± 1.0 a | 11.4 ± 0.4 b | ** |
ethyl 2-methyl butanoate | 846 | 850 | 0.9 ± 0.3 b | 2.1 ± 0.2 b | 5.9 ± 1.3 a | 1.5 ± 0.2 b | 5.6 ± 0.9 a | ** |
2-methylbutyl acetate | 876 | 880 | 114 ± 33 a | 95.4 ± 6.3 a | 13.1 ± 1.2 b | 81.7 ± 7.2 a | 15.7 ± 1.9 b | ** |
3-methylbutyl acetate | 873 | 876 | 1028 ± 254 a | 770 ± 46 a,b | 106 ± 9.5 c | 670 ± 48 b | 121 ± 12 c | ** |
methyl hexanoate | 923 | 936 | 7.5 ± 2.6 c | 18.7 ± 2.1 a,b | 12.8 ± 1.9 b,c | 19.7 ± 3.3 a | 13.4 ± 1.6 b,c | ** |
ethyl-3-hydroxy butanoate | 934 | 945 | 1.0 ± 0.1 c | 2.1 ± 0.2 b | 2.4 ± 0.1 a | 1.0 ± 0.1 c | 1.2 ± 0.2 c | ** |
ethyl hexanoate | 997 | 999 | 956 ± 258 a | 980 ± 47 a | 587 ± 15 b | 846 ± 46 a | 275 ± 37 b | ** |
hexyl acetate | 1010 | 1011 | 1072 ± 290 a | 795 ± 44 a,b | 47.0 ± 1.5 c | 657 ± 32 b | 55.4 ± 6.3 c | ** |
isoamyl lactate | 1071 | 1065 | 0.3 ± 0.1 c | 0.2 ± 0.1 c | 23.8 ± 1.4 a | 0.3 ± 0.1 c | 20.5 ± 1.1 b | ** |
methyl octanoate | 1123 | 1129 | 216 ± 78 a | 233 ± 63 a | 69.9 ± 17.2 b | 241 ± 69 a | 66.8 ± 15.6 b | * |
ethyl benzoate | 1183 | 1170 | 0.7 ± 0.1 c | 1.4 ± 0.0 c | 12.8 ± 0.3 a | 1.6 ± 0.1 c | 10.8 ± 0.7 b | ** |
ethyl octanoate | 1196 | 1194 | 2083 ± 479 a | 2148 ± 123 a | 561 ± 46 b | 1 994 ± 101 a | 483 ± 77 b | ** |
hexyl-2-methylbutanoate | 1238 | 1234 | 0.5 ± 0.1 b | 3.1 ± 0.1 b | 36.9 ± 2.8 a | 2.2 ± 0.2 b | 32.4 ± 4.9 a | ** |
ethylphenyl acetate t | 1255 | n/a | 0.8 ± 0.1 c | 2.0 ± 0.2 b | 11.6 ± 0.5 a | 1.9 ± 0.2 b | 11.4 ± 0.6 a | ** |
phenethyl acetate | 1269 | 1256 | 222 ± 16.8 a | 140.1 ± 6.0 b | 16.7 ± 0.9 d | 113 ± 4.2 c | 15.5 ± 0.4 d | ** |
methyl decanoate | 1324 | 1324 | 387 ± 81 a | 368 ± 81 a | 56.8 ± 13 b | 363 ± 70 a | 51.3 ± 11 b | ** |
2-methylpropyl octanoate | 1348 | 1345 | 6.0 ± 1.7 a | 6.3 ± 0.8 a | 1.1 ± 0.2 b | 6.4 ± 1.1 a | 1.0 ± 0.2 b | ** |
ethyl decanoate | 1395 | 1392 | 2177 ± 445 a | 1832 ± 160 a | 279 ± 41 b | 1 941 ± 245 a | 230 ± 40 b | ** |
3-methylbutyl octanoate | 1448 | 1450 | 104 ± 30 a | 88.7 ± 10.8 a | 9.2 ± 1.6 b | 94.8 ± 18.1 a | 7.2 ± 1.2 b | ** |
methyl dodecanoate | 1525 | 1526 | 276 ± 16.6 a | 291 ± 41 a | 61.8 ± 7.0 b | 285 ± 26.2 a | 52.8 ± 5.2 b | ** |
hexyl octanoate | 1584 | 1571 | 3.3 ± 1.2 b | 8.5 ± 1.0 a | 0.9 ± 0.2 b | 9.0 ± 2.2 a | 0.8 ± 0.2 b | ** |
ethyl dodecanoate | 1594 | 1597 | 547 ± 194 a | 395 ± 61 a | 53.3 ± 12.2 b | 533 ± 134 a | 43.4 ± 10.4 b | ** |
3-methylbutyl decanoate | 1647 | 1649 | 108.9 ± 31.2 a | 96.0 ± 10.5 a | 6.4 ± 1.5 b | 109 ± 18.4 a | 5.1 ± 1.1 b | ** |
2-methylbutyl decanoate | 1651 | 1647 | 16.4 ± 5.4 a | 17.0 ± 2.1 a | 2.5 ± 0.2 b | 21.5 ± 4.5 a | 2.3 ± 0.2 b | ** |
2-phenylethyl hexanoate | 1664 | 1650 | 5.4 ± 0.7 a | 4.5 ± 0.2 b | 0.6 ± 0.1 c | 3.8 ± 0.2 b | 0.6 ± 0.1 c | ** |
ethyl tetradecanoate | 1794 | 1794 | 26.9 ± 8.8 a | 17.7 ± 2.6 a,b | 3.6 ± 1.6 b | 26.1 ± 5.8 a | 5.7 ± 0.8 b | ** |
3-methylbutyl dodecanoate | 1848 | 1844 | 6.8 ± 1.6 ab | 4.8 ± 0.9 b | 0.9 ± 0.2 c | 7.2 ± 0.7 a | 0.8 ± 0.1 c | ** |
methyl hexadecanoate | 1927 | 1933 | 132 ± 32 | 135 ± 38 | 86 ± 12 | 147 ± 41 | 89 ± 19 | no |
ethyl-9-hexadecenoate | 1979 | 1977 | 7.2 ± 1.2 c | 16.6 ± 1.8 a | 4.2 ± 0.7 d | 13.3 ± 0.9 b | 2.9 ± 0.2 d | ** |
ethyl hexadecanoate | 1994 | 1978 | 53.1 ± 3.1 a | 35.7 ± 4.3 b | 25.8 ± 2.2 c | 53.0 ± 5.3 a | 24.2 ± 1.3 c | ** |
terpenoids | ||||||||
linalool oxide (furanoid) | 1083 | 1073 | 5.9 ± 0.1 c | 9.0 ± 0.5 a | 9.2 ± 0.5 a | 7.4 ± 0.0 b | 8.1 ± 0.2 b | ** |
linalool | 1103 | 1101 | 3.6 ± 0.5 d | 5.5 ± 0.1 a | 4.8 ± 0.1 b,c | 5.1 ± 0.1 b,c | 4.4 ± 0.2 a,b | ** |
α-farnesene | 1517 | 1508 | 2.0 ± 0.3 c | 7.3 ± 0.5 a,b | 9.2 ± 1.7 a | 6.3 ± 0.8 b | 8.1 ± 1.0 a,b | ** |
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Ruppert, V.; Innerhofer, G.; Voit, J.; Hiden, P.; Siegmund, B. The Impact of the Fermentation Strategy on the Flavour Formation of Ilzer Rose (Malus domestica Borkh.) Apple Wine. Foods 2021, 10, 2348. https://doi.org/10.3390/foods10102348
Ruppert V, Innerhofer G, Voit J, Hiden P, Siegmund B. The Impact of the Fermentation Strategy on the Flavour Formation of Ilzer Rose (Malus domestica Borkh.) Apple Wine. Foods. 2021; 10(10):2348. https://doi.org/10.3390/foods10102348
Chicago/Turabian StyleRuppert, Valerie, Georg Innerhofer, Jörg Voit, Peter Hiden, and Barbara Siegmund. 2021. "The Impact of the Fermentation Strategy on the Flavour Formation of Ilzer Rose (Malus domestica Borkh.) Apple Wine" Foods 10, no. 10: 2348. https://doi.org/10.3390/foods10102348