Recent Developments in the Use of Covalent Organic Frameworks for Photocatalytic Water Decontamination
Abstract
:1. Introduction
2. Structure–Activity Relationships
2.1. Donor–Acceptor
2.2. Conjugation Tunning
2.3. Bandgap Modulation and Band Positioning for Optimal Photocatalysis
2.4. Synergistic Strategies
3. General Photocatalytic Mechanisms
3.1. Electron Transfer: Reductive Quenching vs. Oxidative Quenching
3.2. Generation of Radical Species: Superoxide, Hydroxyl, and Organic Radicals
3.3. Energy Transfer: Singlet Oxygen and Direct Energy Transfer
4. Pollutants Tackled
5. Concluding Remarks
Funding
Institutional Review Board Statement
Data Availability Statement
Conflicts of Interest
Abbreviations
COF | Covalent Organic Frameworks |
ROS | Reactive Oxygen Species |
VB | Valence Band |
CB | Conduction Band |
ISC | Intersystem Crossing |
EIS | Electrochemical Impedance Spectroscopy |
XPS | X-ray Photoelectron Spectroscopy |
UPS | Ultraviolet Photoelectron Spectroscopy |
D-A | Donor–Acceptor |
BPA | Bisphenol A |
MOFs | Metal–Organic Frameworks |
Vfb | Flat Band Potential |
Ef | Fermi Level |
HOMO | Highest Occupied Molecular Orbital |
LUMO | Lowest Unoccupied Molecular Orbital |
SET | Single Electron Transfer |
EnT | Energy Transfer |
PC | Photocatalyst |
SED | Sacrificial Electron Donor |
FRET | Förster Resonance Energy Transfer |
Ered | Reduction Potential |
Eox | Oxidation Potential |
EPR | Electron Paramagnetic Resonance |
TC | Tetracycline |
ACTP | Acetaminophen |
SMT | Sulfamethazine |
SMX | Sulfamethoxazole |
RhB | Rhodamine B |
MB | Methylene Blue |
MO | Methyl Orange |
MB17 | Mordant Black 17 |
EBA | Eriochrome Black A |
EBT | Eriochrome Black T |
RB | Rose Bengal |
MG | Methyl Green |
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Pollutant | COF Name (Linkage Type) | Design Principle | ROS Involved | Ref. |
---|---|---|---|---|
Tetracycline | COF-R (imine) | Donor–acceptor COFs | ·O2−/·OH | [70] |
sp2c-COF (olefin) | Extended conjugation of COFs | ·OH | [71] | |
MoS2/COF (imine) | MoS2/COF heterojunction | ·OH/·O2− | [72] | |
Acetaminophen | COF-TD1 (imine) | Donor–acceptor COFs | ·O2− | [73] |
COF-PD/AgI (imine) | COF/AgI heterojunction | ·O2− | [38] | |
Heptazine-COF@TiO2 (imine) | COF/TiO2 heterojunction | ·O2− | [74] | |
Sulfamethazine | SQ-COF-1 (imine) | Extended conjugation of COFs | ·O2− | [75] |
COF/CN-3 (C-N bond) | COF/g-C3N4 heterojunction | ·O2−/1O2/·OH/ SO4−· | [76] | |
Sulfamethoxazole | COF-909(Cu) (imine) | COF(Cu) | ·O2−/·OH | [77] |
Pollutant | COF Name (Linkage Type) | Design Principle | ROS Involved | Ref. |
---|---|---|---|---|
U(VI) | TpTt-COF (imine) | Donor–acceptor COFs | ·O2− | [78] |
DQTP-COF (imine) | Donor–acceptor COFs | ·O2− | [79] | |
COF-AQ (imine) | Donor–acceptor COFs | - | [80] | |
COF-4-Pd-AO (imine) | COF/Pd heterojunction | - | [81] | |
Cr(VI) | COFs-OMe (imine) | Donor–acceptor COFs | ·O2− | [70] |
TPB-BT-COF (imine) | Donor–acceptor COFs | - | [82] | |
HDU-26-COF (imine) | Donor–acceptor COFs | ·O2− | [83] | |
TAPP-2F-COF (imine) | Halogenated COFs | ·O2− | [84] |
Pollutant | COF Name (Linkage Type) | Design Principle | ROS Involved | Ref. |
---|---|---|---|---|
Rhodamine B | COF-PD/AgI (imine) | COF/AgI heterojunction | ·O2− | [38] |
MoS2/COF (imine) | MoS2/COF heterojunction | ·O2−/·OH | [72] | |
COF-HFeTBD (imine) | Donor–acceptor COFs | 1O2 | [85] | |
HDU-105-COF (olefin) | Donor–acceptor COFs | ·O2−/·OH | [54] | |
Methylene blue | HDU-105-COF (olefin) | Donor–acceptor COFs | ·O2−/·OH | [54] |
C6-TRZ-TPA COF (imine) | Donor–acceptor COFs | ·O2−/·OH | [86] | |
TTO-COF (olefin) | Extended conjugation of COFs | ·O2− | [87] | |
Methyl orange | TTO-COF (olefin) | Extended conjugation of COFs | ·O2− | [87] |
COFA+C (imine) | N-rich COFs | ·O2−/·OH | [88] | |
Rose bengal | C6-TRZ-TPA COF (imine) | Donor–acceptor COFs | ·O2−/·OH | [86] |
Mordant black 17 | TpBD-COF (imine) | Pure COF | ·O2−/1O2/·OH | [89] |
Eriochrome black T | TpBD-COF (imine) | Pure COF | ·O2−/1O2/·OH | [89] |
TFA-TTA-COF (imine) | Fluorinated COF | ·O2−/1O2 | [90] | |
Eriochrome black A | TFA-TTA-COF (imine) | Fluorinated COF | ·O2−/1O2 | [90] |
Methyl green | CuO/COF (imine) | CuO/COF heterojunction | ·O2− | [91] |
Pollutant | COF Name (Linkage Type) | Design Principle | ROS Involved | Ref. |
---|---|---|---|---|
Diazinon and parathion | PS@COF-366 (imine) | Sulfured COF | ·O2−/1O2/·OH | [92] |
Imidacloprid | Fe3O4@HMN-COF (imine) | Fe3O4/COF heterojunction | - | [93] |
Pymetrozine | Ag3PO4/TpPa-1-COF (imine) | Ag3PO4/COF heterojunction | ·O2−/·OH | [94] |
Pollutant | COF Name (Linkage Type) | Design Principle | ROS Involved | Ref. |
---|---|---|---|---|
Phenol | COFA+C (imine) | N-rich COFs | ·O2−/·OH | [88] |
GCN/TD-COF (imine) | GCN/COF heterojunction | ·O2−/·OH | [95] | |
Bisphenol-A | CdS/TFp-Azo-COF (imine) | CdS/COF heterojunction | ·O2−/·OH | [39] |
NM-125(Ti)0.4@TpTta-COF (imine) | MOF/COF heterojunction | ·O2−/1O2/·OH | [36] | |
MIL-101-NH2@COF-TpMA (imine) | MOF/COF heterojunction | ·OH/SO4−· | [63] | |
4-chlorophenol | Bi/TP-BDDA-COF (imine) | Bi/COF heterojunction | ·O2−/·OH | [96] |
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Cepa-López, V.; Sánchez-Fuente, M.; Moya, A.; Mas-Ballesté, R. Recent Developments in the Use of Covalent Organic Frameworks for Photocatalytic Water Decontamination. Inorganics 2025, 13, 152. https://doi.org/10.3390/inorganics13050152
Cepa-López V, Sánchez-Fuente M, Moya A, Mas-Ballesté R. Recent Developments in the Use of Covalent Organic Frameworks for Photocatalytic Water Decontamination. Inorganics. 2025; 13(5):152. https://doi.org/10.3390/inorganics13050152
Chicago/Turabian StyleCepa-López, Víctor, Miguel Sánchez-Fuente, Alicia Moya, and Rubén Mas-Ballesté. 2025. "Recent Developments in the Use of Covalent Organic Frameworks for Photocatalytic Water Decontamination" Inorganics 13, no. 5: 152. https://doi.org/10.3390/inorganics13050152
APA StyleCepa-López, V., Sánchez-Fuente, M., Moya, A., & Mas-Ballesté, R. (2025). Recent Developments in the Use of Covalent Organic Frameworks for Photocatalytic Water Decontamination. Inorganics, 13(5), 152. https://doi.org/10.3390/inorganics13050152