Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves
Abstract
:1. Introduction
2. Materials and Methods
2.1. Reagents
2.2. Preparation Method for Adsorbents
2.3. Batch Adsorption Experiments
2.4. Column Adsorption Experiment
2.5. Evaluation of Adsorption Measurements
3. Results and Discussion
3.1. Adsorption of Cesium Ions on Crude and Crosslinked Tea Leaves
3.2. Effect of Shaking Time on Adsorption of Alkali Metal Ions
3.3. Effect of pH on Adsorption of Alkali Metal Ions
3.4. Adsorption Isotherms of Na+ and Cs+ Ions on CFT and CUT Adsorbents
3.5. Chromatography Separation of Cs+ over Na+ Ion Using Crosslinked Tea Leaves
3.6. Fourier-Transfer Infrared Analysis
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Adsorbent | Cs+ | K+ | Na+ | |||
---|---|---|---|---|---|---|
Slope | R2 | Slope | R2 | Slope | R2 | |
CFT | 0.822 | 0.9863 | 0.858 | 0.9953 | 0.831 | 0.9919 |
CUT | 0.997 | 0.9795 | 0.861 | 0.9860 | 0.780 | 0.9510 |
CUT Adsorbent | CFT Adsorbent | |||||
---|---|---|---|---|---|---|
Qm (mmol g−1) | B (dm3 mmol−1) | R2 | Qm (mmol g−1) | B (dm3 mmol−1) | R2 | |
Na+ | 2.40 | 0.6431 | 0.999 | 2.25 | 0.3182 | 0.999 |
Cs+ | 2.48 | 0.2802 | 0.997 | 2.56 | 0.9950 | 0.996 |
Adsorbent | Adsorption Capacity (mmol g−1) | pH | Temperature(K) | Reference |
---|---|---|---|---|
Layered metal sulfide (KMS−1) | 1.70 | ≈7.0 (pHe) | 298 | [24] |
Sericite | 0.050 | 5.0 (pHi) | 298 | [25] |
RIP of clay minerals | 0.250 | 7.0 (pHi) | * | [26] |
Prussian blue | 1.254 | Water | 298 | [27] |
Biomass of marine algae | 0.248 | 5.5 (pHi) | 303 | [28] |
Arca shell biomass | 0.036 | 5.5 (pHi) | 298 | [29] |
CUT | 2.48 | 7.0 ± 1.0 (pHe) | 303 | Present work |
CFT | 2.56 | 7.0 ± 1.0 (pHe) | 303 | Present work |
CUT Adsorbent | CFT Adsorbent | |||||
---|---|---|---|---|---|---|
Adsorbed (mmol g−1) | Eluted (mmol g−1) | % Recovery | Adsorbed (mmol g−1) | Eluted (mmol g−1) | % Recovery | |
Na+ | 0.491 | 0.484 | 98.57 | 0.528 | 0.497 | 94.13 |
Cs+ | 0.804 | 0.716 | 89.05 | 0.992 | 0.951 | 95.78 |
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Yu, D.; Morisada, S.; Kawakita, H.; Ohto, K.; Inoue, K.; Song, X.; Zhang, G. Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves. Processes 2019, 7, 412. https://doi.org/10.3390/pr7070412
Yu D, Morisada S, Kawakita H, Ohto K, Inoue K, Song X, Zhang G. Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves. Processes. 2019; 7(7):412. https://doi.org/10.3390/pr7070412
Chicago/Turabian StyleYu, Dan, Shintaro Morisada, Hidetaka Kawakita, Keisuke Ohto, Katsutoshi Inoue, Ximing Song, and Guolin Zhang. 2019. "Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves" Processes 7, no. 7: 412. https://doi.org/10.3390/pr7070412