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Article

Heavy Metal Ion Detection by Carbonized Metal–Organic–Framework (MOF-C) Nanocomposite-Modified Electrochemical Sensors

1
Guangdong Provincial Key Laboratory of Intelligent Equipment for South China Sea Marine Ranching, Guangdong Ocean University, Zhanjiang 524088, China
2
College of Naval Architecture and Shipping, Guangdong Ocean University, Zhanjiang 524088, China
3
Marine Engineering College, Dalian Maritime University, Dalian 116026, China
4
Fisheries College, Guangdong Ocean University, Zhanjiang 524088, China
5
Guangdong Provincial Key Laboratory of Aquatic Animal Disease Control and Healthy Culture, College of Fisheries, Guangdong Ocean University, Zhanjiang 524088, China
*
Author to whom correspondence should be addressed.
These authors contributed equally to this work.
Chemosensors 2026, 14(2), 40; https://doi.org/10.3390/chemosensors14020040
Submission received: 23 December 2025 / Revised: 30 January 2026 / Accepted: 1 February 2026 / Published: 3 February 2026

Abstract

Efficient detection of heavy metal ions in complex marine environments is essential to the safety of marine organisms and human beings. This study developed a novel screen-printed-electrode (SPE) electrochemical sensor for rapid on-site determination of typical heavy metal ions such as Cu2+, Pb2+, Cd2+, and Hg2+ in seawater. The sensor employs a three-electrode system, with the working electrode modified with a composite of metal–organic framework-derived carbon (MOF-C) and multiwalled carbon nanotubes (MWCNTs), thereby significantly enhancing detection sensitivity and selectivity. By optimizing square-wave anodic stripping voltammetry (SWASV) parameters, detection limits of 0.83, 0.40, 1.05, and 0.30 μM for the detection of Cu2+, Pb2+, Cd2+, and Hg2+ ions were achieved. In mixed-ion detection, excellent peak separation and strong resistance to interferences were demonstrated. Experimental results demonstrate that the sensor exhibits good linear response, excellent interference resistance, and high practicality, providing a new approach for rapid on-site determination of heavy metal pollution in marine environments.
Keywords: SPE electrochemical sensor; heavy metal ion detection; metal–organic framework; square wave anodic stripping voltammetry SPE electrochemical sensor; heavy metal ion detection; metal–organic framework; square wave anodic stripping voltammetry

Share and Cite

MDPI and ACS Style

Wang, W.; Zhao, P.; Wang, C.; Xu, A.; Ma, W.; Wang, G.; Han, Z.; Lu, Y.; Yan, J.; Peng, R. Heavy Metal Ion Detection by Carbonized Metal–Organic–Framework (MOF-C) Nanocomposite-Modified Electrochemical Sensors. Chemosensors 2026, 14, 40. https://doi.org/10.3390/chemosensors14020040

AMA Style

Wang W, Zhao P, Wang C, Xu A, Ma W, Wang G, Han Z, Lu Y, Yan J, Peng R. Heavy Metal Ion Detection by Carbonized Metal–Organic–Framework (MOF-C) Nanocomposite-Modified Electrochemical Sensors. Chemosensors. 2026; 14(2):40. https://doi.org/10.3390/chemosensors14020040

Chicago/Turabian Style

Wang, Wei, Peiting Zhao, Chenjie Wang, Aixuan Xu, Wei Ma, Gan Wang, Zehua Han, Yishan Lu, Jin Yan, and Ran Peng. 2026. "Heavy Metal Ion Detection by Carbonized Metal–Organic–Framework (MOF-C) Nanocomposite-Modified Electrochemical Sensors" Chemosensors 14, no. 2: 40. https://doi.org/10.3390/chemosensors14020040

APA Style

Wang, W., Zhao, P., Wang, C., Xu, A., Ma, W., Wang, G., Han, Z., Lu, Y., Yan, J., & Peng, R. (2026). Heavy Metal Ion Detection by Carbonized Metal–Organic–Framework (MOF-C) Nanocomposite-Modified Electrochemical Sensors. Chemosensors, 14(2), 40. https://doi.org/10.3390/chemosensors14020040

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