The Functional Fe3O4@SiO2@AuNPs SERS Nanomaterials for Rapid Enrichment and Detection of Mercury Ions in Licorice
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials and Apparatus
2.2. Synthesis of Fe3O4@SiO2
2.3. Amination of Fe3O4@SiO2
2.4. Synthesis of Fe3O4@SiO2@AuNPs
2.5. Preparation of DMcT-Functionalized Fe3O4@SiO2@AuNPs
2.6. Sample Preparation and Raman Spectroscopy Analytical Parameters
2.7. Data Processing
3. Results and Discussion
3.1. Synthesis and Characterization of Fe3O4@SiO2@AuNPs
3.2. Magnetic Adsorption Performance of Fe3O4@SiO2@AuNPs
3.3. Principle of Hg2+ Detection Based on Fe3O4@SiO2@AuNPs-DMcT
3.4. SERS Detection of Hg2+
3.5. Enrichment of Hg2+ in Licorice Extract and SERS Detection
3.6. Reproducibility and Specificity Examination
3.7. Comparison with Other Substrate Materials
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Raman DMcT Power | Raman Shift of DMcT | Assignment |
---|---|---|
1514 m | —— | v (C=N) asym |
1456 vs | 1418 vs | v (C=N) asym |
1363 m | ||
1287 m | —— | —— |
1120 w | —— | Ring stretch |
1089 m | 1061 m | Ring stretch |
1048 m | —— | Ring stretch |
725 m | 668 s | v (C–S) asym |
666 s | 554 m | o.p. dist. |
545 m | —— | |
499 m | 389 m | δ (CSC) + δ (CSH) |
379 s | —— | |
322 | o.p. dist. |
Samples | Added | Detected | Recovery (%) | RSD (%) n = 5 |
---|---|---|---|---|
Licorice extract | 10 ng/mL | 8.9 ng/mL | 89.10 | 4.75 |
Licorice extract | 30 ng/mL | 33.3 ng/mL | 111.00 | 5.39 |
Licorice extract | 50 ng/mL | 48.6 ng/mL | 97.20 | 4.88 |
Licorice extract | 80 ng/mL | 77.1 ng/mL | 96.37 | 6.97 |
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Zhu, J.; Wang, B.; Yang, P.; Li, J.; Xiao, G.; Yao, J.; Gong, X.; Yan, J.; Zhang, H. The Functional Fe3O4@SiO2@AuNPs SERS Nanomaterials for Rapid Enrichment and Detection of Mercury Ions in Licorice. Chemosensors 2022, 10, 403. https://doi.org/10.3390/chemosensors10100403
Zhu J, Wang B, Yang P, Li J, Xiao G, Yao J, Gong X, Yan J, Zhang H. The Functional Fe3O4@SiO2@AuNPs SERS Nanomaterials for Rapid Enrichment and Detection of Mercury Ions in Licorice. Chemosensors. 2022; 10(10):403. https://doi.org/10.3390/chemosensors10100403
Chicago/Turabian StyleZhu, Jieqiang, Baoling Wang, Ping Yang, Junmei Li, Guyu Xiao, Jiangyu Yao, Xingchu Gong, Jizhong Yan, and Hui Zhang. 2022. "The Functional Fe3O4@SiO2@AuNPs SERS Nanomaterials for Rapid Enrichment and Detection of Mercury Ions in Licorice" Chemosensors 10, no. 10: 403. https://doi.org/10.3390/chemosensors10100403