1. Introduction
The area of time-varying materials has received great attention lately, with the idea that time can be used to achieve additional control of electromagnetic waves. Many applications, especially related to temporal modulations of metamaterials [
1], have been seen so far, and include frequency conversion, wave amplification, and the foundations of photonic time crystals, among many others. Photonic time crystals are systems which undergo periodic temporal variations while maintaining spatial uniformity [
2].
While the applications are vast, the mathematical analysis related to the Maxwell equations, in particular, in such time-varying media is lacking in comparison (in no small part due to the mathematical challenges of time-varying material parameters). For mathematical results in the time domain with time-varying material parameters, we make particular mention of [
3] for numerical investigations using a so-called Magnus expansion and [
4] (Section 5) which considers weak solutions for the time-dependent Maxwell system with both space and time-varying permittivity. We also mention various works that consider time dependence through temperature-dependent material parameters; see, in particular, Refs. [
5,
6,
7] and the references therein.
In this paper, we focus on the particular case of temporal interfaces. A temporal interface occurs [
8] when a material parameter is changed in time rapidly while an optical wave is present in the material. One way this can be obtained is through strong optical nonlinearity and an ultrafast (on the order of 5–10 femtoseconds) laser pulse [
9].
At a temporal interface, forward and backward waves in time (waves that propagate along the same and opposite directions of the original wave) are known to result [
10,
11,
12]. This is the temporal analog of classical reflected and transmitted waves at a spatial interface, which are known to occur when a plane wave is incident upon such an interface [
13]. We continue to refer to these as reflected, transmitted, and incident waves in this paper.
See
Figure 1 for a graphical illustration of this phenomenon. In this Figure,
and
denote the refractive indices on either side of the temporal interface.
For a temporal interface, the wavelength for the forward and backward waves are the same as the original wave, but the frequency changes due to the change in wave velocity. Moreover, at the temporal interface (unlike the classical spatial interface), the energy needed to change the material can affect the electromagnetic wave energy, so energy is not conserved (it can increase or decrease). We will derive these results from a rigorous mathematical perspective, and, in particular, quantify the deviation from conservation of energy—see Equations (
35) and (
36), which describe the reflection and transmission coefficients in terms of the material parameters on either side of the temporal interface.
The objective of this paper is to derive the Snell Law at temporal interfaces from fundamental principles. To achieve this, we will utilize the Maxwell equations. Given that the waves being considered are generally discontinuous, it is advantageous to approach this derivation from the perspective of distributions or generalized functions, thereby facilitating a comprehensive understanding of the Maxwell system. A similar distributional analysis of Maxwell equations in the context of spatial metasurfaces has been conducted in [
14].
This work considers more general time-dependent material parameters than have been previously considered. In particular, this work sets a mathematical foundation to study general time-varying media and even more complicated materials, such as those with space–time interfaces [
12]. This framework is useful to precisely understand how light propagates across non-standard interfaces.
The outline of this paper is as follows. In
Section 2, we analyze the Maxwell system in the sense of space–time distributions. Under certain assumptions on fields which are discontinuous at a certain time, we derive a formula for the distributional time derivative of such a field; see Equation (
12). Then in
Section 3, under particular assumptions of the material parameters
, we provide a rigorous derivation of the boundary conditions satisfied by the electric and magnetic fields at a temporal interface. Again, the time-dependent Maxwell system is understood in the distributional sense here. In
Section 4 we use these boundary conditions to derive a fully rigorous Snell’s Law for reflection and refraction at a temporal interface in the case when
vary in time but not in space (Proposition 2). From here, in
Section 4.1, we consider the simplified case when
jump from one value to another (a common assumption in practice) and rigorously obtain formulas for the amplitudes (Proposition 3), and for the reflection and transmission coefficients in
Section 4.1. We also note that the amplitudes of the incident, transmitted, and reflected waves are generally not arbitrary, but rather subject to the divergence equations in the Maxwell system—see
Section 4.2.
2. Maxwell Equations in the Sense of Distributions
Recall the Maxwell system of equations (in CGS units)
where
denotes the electric field,
the magnetic field,
the electric flux density,
the magnetic flux density, and
c the speed of light. See [
13] Sections 1.1–1.2. We assume the charge density
and the current density
, and consider the constitutive equations given by
where we assume that
and
are positive functions of
, and
for some
, that satisfy appropriate piecewise smoothness assumptions that will be described in a moment.
We begin by recalling the notions needed to analyze the Maxwell system in a distributional sense. Let
be an open domain, which could be the whole space, and let
be an open interval that could be infinite. A generalized function or distribution defined in
is a complex-valued continuous linear functional defined on the class of test functions denoted by
, that is, the class of functions are infinitely differentiable in
and have compact support in
. More precisely,
g is a distribution in
if
is a linear function such that for each compact
there exist a constant
C and an integer
k such that
for each
. As customary,
denotes the class of distributions in
.
Numerous references are available for distributions; however, we only cite the seminal work by L. Schwartz, [
15], and also [
16].
If
, then
denotes the value of the distribution
g on the test function
. If
g is a locally integrable function in
, then
g gives rise to a distribution defined by
for each
.
We say that
is a vector-valued distribution in
if each component
,
. The divergence of
with respect to
x is the scalar distribution defined by
and the curl of
is the vector-valued distribution in
defined by
Then it follows that
in the sense of distributions. When the distribution
is given by a locally integrable function in
, we obtain from (
6) and (
7) that
The derivative of
with respect to
t in the sense of distributions is by definition the distribution
defined by
for each
.
Therefore, the fields
, and
solve the Maxwell system in the sense of distributions if
, and
are vector-valued distributions in
that satisfy Equations (
1)–(4) in the sense of distributions.
4. Snell’s Law for Time-Varying Media
The organization of this section is as follows.
We make an ansatz for the electric and magnetic fields and obtain a generalized Snell’s Law in Proposition 2.
Remark 2 is a formulation of this law in the scalar case.
In
Section 4.1, we assume that
jump between two constant values, and we calculate the corresponding magnetic fields.
Next, we compute the amplitudes of the reflected and transmitted waves in terms of the incident wave amplitude in Proposition 3.
In
Section 4.1, from the previous formulas, we deduce the reflection and transmission coefficients.
In
Section 4.2, we use the divergence equations in the Maxwell system which were used in the calculation of the amplitudes previously.
In
Section 4.3, we prove a Lemma on exponentials which is used in the calculation of the amplitudes.
In this section, we assume that the material parameters
and
vary in time but not in space. Suppose that time
corresponds to a temporal interface, and that
are as in the previous section, now independent of space. Define the velocities
and
We further assume that
are integrable in time so that condition (
11) is verified. This means that we need to assume that the quantities
i.e., the
, are integrable in time. Notice that if
are bounded below by a positive constant, then the integrability follows from (H2). Clearly this condition is trivially satisfied if
and
are positive constants in time.
Let us make the ansatz for the incident field
where the amplitude
is a 3-d non-zero vector with complex components,
, and
is a unit vector. Suppose that the transmitted wave has a part with the direction
and a part with the direction
, given as follows. For the transmitted field, we make the ansatz:
and for the reflected field:
where, once again,
are non-zero complex vectors and
are unit vectors. Here,
and
are real numbers different from zero and we will show that their signs will determine the directions of the wave vectors. If
and
, then the jump of these fields at
is given by
Remark 1. Compare this idea with the case of a spatial interface. In such a situation, since the incident wave and reflected wave are on the same side of the interface, one instead takes and . See for instance [17]. Now, if the field
satisfies the Maxwell Equation (
13) in the sense of distributions and the form of the fields
, and
implies that they satisfy (
9)–(
11), it follows that the boundary condition (
15) is applicable, and we obtain
for all
.
If we define
with
and
, then we obtain an equation of the form
where
Now, from Lemma 1, Equation (
19) implies that
, i.e.,
This gives the following proposition showing general relationships between the wave vectors
,
, and
.
Proposition 2. Under the previous assumptions, we haveSince the wave vectors are all units, taking absolute values in (
21) yields
which implies
We have assumed at the outset that
. So, if
, then
, which is consistent with [
18] [Equation (
5)]. Moreover, the fact that
is precisely the Snell’s Law for the transmitted wave in [
11] [Equations (13) and (14)]. On the other hand, if
, we then obtain
. A similar analysis with
yields that
if
, and
if
. This agrees with [
1] [Equation (
4)] and [
11] [Equation (
13)].
Remark 2. As mentioned above, Equation (21) can be seen as a generalized Snell’s Law at a temporal interface which does not require that the velocities on either side of the interface be constant. Indeed, this can be written asandwhere . In the plane , one can define an angle α similar to the incidence angle θ in the plane with spatial interfaces, such that . This angle can be called the angle of temporal incidence [19]. Then, from (22) and (23) we obtain the scalar lawwhich agrees with the scalar law in Equation (15) in [11]. Since can take on any real value, we see that there is no notion of total internal reflection as in the case of classical spatial interfaces. That is, there is no wave that propagates backwards in time. Finally, the material parameters ε and μ should be differentiable in time away from the interface and could in principle also vary in space. However, with spatially varying velocities, it is not clear if Lemma 1 applies, so we have not considered this case. 4.1. Case When and Are Jump Functions and Calculation of the Amplitudes
Now consider the case when
with
positive constants. So
for
and
for
are both constant. This is a common application in practice; see, e.g., Ref. [
18] and the references therein. This form of velocities also enables us to compute the associated magnetic fields and establish the boundary conditions for them. Together with the boundary conditions already obtained for the electric fields, we will be able to calculate the amplitudes of the transmitted and reflected waves.
In fact, let us calculate first the magnetic fields. Consider the following Maxwell Equation (3) for the incident field when
: seek
satisfying
Since
we see that
and so integrating in time yields
plus a field depending only on
x which is assumed to be zero. Now suppose
. Since
we similarly find that
plus a field depending only on
x which is also assumed to be zero. Finally, since
we find that
Now we may consider the magnetic boundary condition (
18). The jump of
by definition is given by
and at
. Here,
. The boundary condition (
18) then implies that
for all
x.
But since we know from (
20) that the exponentials in
x are all equal, we obtain
that is,
cancelling
yields
so
From (
20) and letting
in (
19) we obtain
If we set
then we need to solve
and
in the system of equations
which can be written as
We now proceed to find
and
from this system of equations. We shall prove the following.
Proposition 3. If , thenandIf , then Proof. The augmented matrix of the system (
29)–(30) is
If we let
(notice
) then the matrix
M without the last column equals
The system of equations can then be written as
where the unknowns are
. This means
From the first equation,
and substituting in the second equation yields
which gives
Case when . Then
must solve
which means that to have a solution
the vector
must be in the image of
N. Given a 3-d vector
X we have
. So the vector
must satisfy the equation
which means the vector
must be parallel to the vector
, that is,
but since
, from (
42) below and (
21), dotting the last equation with
yields
and we then obtain that (
31). We also obtain from this that
which is (
32).
Case when . We have
from (30), and since
, if there is a solution
then the vector
must satisfy
which is equivalent to
In this case (
29) and (30) are the same equation, and so we get
which has infinitely many solutions
. In this case, from (
21), we have
and therefore the electric field
showing that there are no distinctive transmitted and reflected waves. This means the amplitudes of the transmitted and reflected waves satisfy
Note that (
43) must hold in this case, so the amplitudes
cannot be arbitrary. □
Also note that when , we have , but the relation to depends on the sign of the frequencies. Indeed, if then , but if then we have .
Reflection and Transmission Coefficients
Defining the reflection coefficient
as
, we see that, if
and if
, then from (
31) we have
since
, and
. Since
, in this case we obtain
That is, we have shown that the reflection coefficient
is given by
which agrees with [
20] [Equation (
4)]. Note that the quantity inside the absolute value can be positive or negative depending on the relationship between the impedances. We also see that the transmission coefficient
, defined by
, is given by
This agrees with [
20] [Equation (
5)]. Note that we do not have conservation of energy in this case, but rather we see that
depends on the impedances on either side of the interface. Indeed, let
and
. If
then we have
If
then we have
Now, if
and
while
, then we find that
and
That is, the transmission and reflection coefficients have switched roles in this case.
Finally, note that negative time refraction is also possible [
21,
22,
23]. So now suppose that
but
with
, so that
. Then in particular we have
. The previous analysis up to Equation (
20) does not show these material parameters, so this result still holds. Now, (
21) then gives
and so, again after taking absolute values, if
have the same sign then we obtain
because now, in this case,
. Similarly, if
have different signs, then we obtain
. Similarly, if
(i.e.,
have different signs), then again from (
20) we find that
and hence
4.2. Divergence-Free Conditions
Recall that we have defined
Assuming zero charge density, we also have the following divergence equations from the Maxwell system:
and
recalling that we associate
with
and
with
. Again, let us assume that each
are positive constants. First consider
. In light of (
39) we find that
We also need to verify (
40) with
given by (
24). Note that we find
where
We find that
But by the previous calculation of
above, since
appears twice in the term
, we find that
. Hence (
40) is satisfied for
.
Consider now the total field
In light of (
39), we find that we must have
Now, if
, this yields
If
, we have
We also need to verify (
40) with
. Let us compute
. Since
we see that
and so integrating in time yields
plus a field depending only on
x which is assumed to be zero.
Similar to the above, we find that
and both cross products will end up being zero. Hence (
40) is satisfied with
as well.
4.3. Exponential Lemma
In our previous analysis, we required the following exponential lemma:
Lemma 1. Let , and . Ifthen . Proof. Suppose first that
. Differentiating (
45)
k times with respect to
x yields
. If we let
then the vector
satisfies the system of equations
and therefore the determinant
by the Vandermonde determinant formula. Therefore all
are equal, and so the lemma follows for
.
Suppose next that
. Write
,
. So (
45) implies
for
. Suppose, by contradiction, that not all
are equal. Then there exists
such that relabeling
we can write
and
for
. Hence we can write
for all
, which, written in components, means
for
. From the case when
, we obtain
for
. Consequently, the vectors
for
, which leads to a contradiction.
□