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Article

Extension of the Pt III Analysis

by
Alexander Ryabtsev
Institute of Spectroscopy, Russian Academy of Sciences, Troitsk, 108840 Moscow, Russia
Atoms 2023, 11(11), 148; https://doi.org/10.3390/atoms11110148
Submission received: 11 October 2023 / Revised: 11 November 2023 / Accepted: 14 November 2023 / Published: 16 November 2023
Review Reports Versions Notes

Abstract

:
Using a sliding spark and a 6.65 m normal incidence vacuum spectrograph, the third spectrum of platinum was analyzed. The transitions involving high-lying levels were studied. A total of 241 Pt III lines of the transitions from the levels of the 5d76p + 5d66s6p configurations in the region 728–2062 Å were classified, increasing the number of known Pt III lines to more than 1000. Ninety-one energy levels belonging mostly to the 5d66s6p configuration were added to Pt III. The odd Pt III levels were theoretically interpreted by means of multiconfiguration Dirak–Fock calculations and a least-squares fit of the calculated to the observed levels in the framework of the orthogonal parameters technique.

1. Introduction

The spectrum of doubly ionized platinum was first analyzed by Ryabtsev et al. [1]. They classified more than 800 lines in the 893–2022 Å region as transitions between the three lowest configurations, 5d8, 5d76s and 5d76p, and found 40 even and 93 odd levels. Later, Wyart [2] reported two levels of the 5d77s and five levels of the 5d76d configurations based on 30 lines identified in the region 1300–1750 Å. In a recent paper [3], the photoabsorption spectrum of Pt III was recorded between 98 and 180 Å using the dual laser plasma method. Several unresolved peaks were identified as transitions from the inner subshell 4f14 broadened by autoionization.
The observation of the spectra of chemically peculiar stars χ Lup and κ Cnc from the Goddard High Resolution Spectrograph (GHRS) onboard the Hubble Space Telescope (HST) have resulted in the first identification of the Pt III lines in any stellar spectrum [4]. The absorption spectrum of χ Lup recorded in the range 1249–2688 Å is so rich in Pt III lines that even the transitions from highly lying known levels of the 5d76s configuration are present [5]. The interest in Pt III was revived in connection with the interpretation of the spectrum of a binary neutron star merger, or a “kilonova”. Platinum is considered as one of the most interesting heavy elements to search for signatures in this spectrum. Recently, several theoretical studies of Pt III were published [6,7,8] pointing out the need for extended experimental atomic data.
The present investigation was undertaken to find the highly lying levels of Pt III (in particular, those of the 5d66s6p configuration) and to derive transition probabilities from a theoretical study using a formalism of orthogonal operators.

2. Experimental Details

The platinum spectrum was excited in a sliding spark operated with a capacitor of 3.2 µF charged to 0.6–1.2 kV. Auxiliary inductance up to 3 µH and resistance up to 1.5 Ω were introduced in the electric circuit. The spectrum containing high intensity Pt III lines was obtained at a current about 1 kA. Variation of the electric parameters served to distinguish between Pt III lines and platinum lines of the other stages of the ionization.
The spectra in the region 500–2400 Å were obtained on a 6.65 m normal incidence spectrograph with a 1200 L/mm grating and a plate factor of 1.25 Å/mm. The spectra were photographed on Ilford Q2 plates and measured using an automatic microdensitometer. The Pt II lines [9] were used as reference lines in the region above 1178 Å. Impurity lines of O I-III and C II-III were used as standards for the wavelengths below 1178 Å [10]. Some platinum lines were measured in second order against the Pt II lines and used as the secondary standards. The rms deviation of the reference lines from a correction curve was 0.005 Å in the whole measured region. It can be considered as an uncertainty of Pt III wavelength measurements. This uncertainty is generally consistent with the differences between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength).
The measured line blackening was transformed to intensity using an approximately modeled characteristic curve of the photoplate. The relative line intensities in arbitrary units are given in this work on a linear scale approximately matching the intensities of the lines reported in [1]. The changes with the wavelength of the characteristic curve and sensitivity of the photoplate, as well as the wavelength dependence of the spectrograph response, were not taken into account.

3. Results and Discussion

As mentioned above, 40 Pt III levels were found in the even 5d8 + 5d76s configurations and 93 levels in the odd 5d76p configuration [1]. The even levels in [1] were interpreted in a model of the mixed 5d8 + 5d76s + 5d66s2 configurations by means of the Cowan code [11,12], with the 53 cm−1 standard deviation of the calculated level energies from the measured ones. Later, the orthogonal parameters technique [13,14,15,16] was applied to the calculations of the even energy levels [17]. Wyart et al. [18] performed a systematic study of the (5d + 6s)8 mixed group in the isoelectronic sequence Ir II—Bi VIII by means of a generalized least-squares (GLS) fit. A standard deviation of 27 cm−1 of the calculated from the experimental levels was obtained for the whole sequence. Because the orthogonal parameters technique in an application to the odd configurations was not developed at that time, the calculations in [1] were made using the Cowan code. Fitting of the calculated level energies to the experimental ones for the 5d76p + 5d66s6p + 5d56s26p mixed group of the configurations resulted in average deviation of 190 cm−1.
In this study, the energy levels of the odd configurations and transition probabilities were calculated by means of the orthogonal parameters technique. The even levels were calculated in an approach adopted in [17] with comparable results.
At the beginning of the analysis, the energy levels of the 5d65s5p configuration were predicted using the Cowan code in a model of the 5d76p + 5d66s6p + 5d56s26p + 5d77p + 5d75f interacting configurations. The energy parameters for the 5d76p + 5d66s6p + 5d56s26p configurations were taken from [1] and estimated for the 5d77p and 5d75f configurations. The 5d8 + 5d76s +5d66s2 configurations were treated as in [1]. Thus, calculated energy levels and transition probabilities were used as entries to a program for visual identification of spectral lines and energy levels in optical spectra IDEN2 [19]. After finding enough 5d66s6p levels for meaningful fitting of the level energies, the orthogonal parameters technique was applied. As in the Cowan code calculations, the model of five interacting configurations was applied. The energy parameters obtained in the fitting were used for the prediction of the unknown level energies and transition probabilities. Further identification was continued as an iterative process. The results of the identification are collected in Table 1, Table 2 and Table 3. Newly identified lines in the (5d8 + 5d76s) − (5d76p + 5d66s6p) transition array of Pt III are listed in Table 1. Table 2 contains the energy of all known levels of the 5d76p + 5d66s6p configurations along with the LS composition of their wavefunctions, calculated with the final orthogonal energy parameters shown in Table 3.
Table 1 contains 241 lines; 3 of them were doubly classified. It was found that two levels at 94,814.1 and 95,251.9 cm−1 were incorrectly classified in [1] as 5d7(4F)6p 5F1 and 5d7(4F)6p 5G2, respectively. The classification of these two levels should be interchanged: the level 5d7(4F)6p 5G2 should be at 94,814.1 cm−1, whereas the energy 95,251.9 cm−1 should belong to the 5d7(4F)6p 5F1 level. The identification of the corresponding lines was changed. The questionable odd level at 127,385.8 cm−1 (J = 1) was confirmed, but it was not possible to confirm the level at 118,956.1 cm−1 (J = 1). Instead, this level was found at 118,591.0 cm−1.
The differences between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength) are also shown in Table 1. These differences are not higher than 0.010 Å for 235 lines. The wavelengths of five lines deviate from the corresponding Ritz values by 0.011–0.013 Å, and that of one line (1657.275 Å) deviates by 0.020 Å. Thus, the majority of the differences are located in the limit of two standard deviation of the measured wavelength uncertainty (0.005 Å).
As it is seen in Table 2, the wavefunction composition of many new levels consists of a mixture of the 5d76p and 5d66s6p configurations. In many cases, the leading percentages are low, and the level names in Table 1 have little physical meaning. Therefore, the J values and the energy values are also listed in Table 1 for unambiguous identification of the transitions. The “forbidden” transitions from some of the levels of the 5d66s6p configuration to the 5d8 one were found as a consequence of the configuration mixing of the upper levels.
The energies of the new levels were obtained using the program LOPT for least-squares optimization of energy levels [22]. It was observed, in the course of the identification using the IDEN2 program, that the most of the 5d76s level energies agree with an uncertainty of 0.1 cm−1 with those reported in [1]. Several level energies deviating by 0.2–0.5 cm−1 were corrected. They are marked by “c” in Table 1. Two new J = 0 levels of the 5d76s configuration were found close to positions predicted by Wyart et al. [18]: 52,119.1 cm−1 (43% (4P)3P + 28% (2P)2P) and 61,022.8 cm−1 (46% (4P)3P + 43% (2P)2P). All level energies of the 5d76s configuration established in [1] and corrected in this work were fixed at the optimization of the 5d76p + 5d66s6p levels. Ninety-one new odd levels are collected in Table 2. Their uncertainty varies from 0.1 to 1.0 cm−1, depending mostly on the number of lines available for the optimization. Table 2 also contains calculated energy levels truncated above the highest observed level in the matrixes of each J.
In comparison with the conventional Slater–Condon approach implemented in the Cowan code, the orthogonal operators technique permits small higher-order magnetic and electrostatic effects to be introduced in the fitting procedure. The energy parameters, representing these effects, used in the fitting of the odd levels, are shown in Table 3. The meaning of these parameters can be found in [15,16] and in the references therein. Ab initio values of these parameters were obtained by fitting the energy levels calculated using the Parpia et al. MCDF program [21]. Some of them were varied collectively keeping the ratios of the corresponding ab initio values. Table 3 gives a comparison of the fitted energy parameters of the odd system with ab initio calculated values. Only for the average energies (Eav) and configuration interaction integrals, the ab initio values are from Cowan’s Hartree–Fock program. In all other cases, they are obtained by fitting the results returned by the MCDF code [21].
The fitting of the 5d76p + 5d66s6p levels was carried out in two steps. In the first step, the energy parameters of the 5d76p configuration were varied, keeping the parameters of the 5d66s6p configuration fixed on predetermined values. Twenty-one strongly mixed levels were excluded from the fitting. The mean deviation of the fitting was 48 cm−1. It should be noted that the fitting using Cowan’s code in [1] resulted in an average deviation of 190 cm−1 for the 5d76p levels. In the final step, all energy levels were fitted. Most of the energy parameters describing the levels of the 5d76p configuration were fixed on the values obtained in the first step. The mean deviation of the final fitting was 89 cm−1.
Radial integrals for transitions between the levels of the odd and even configurations used for the calculation of the weighted transition probabilities gA in Table 1 were taken from the Cowan code. As was mentioned above, the observed relative line intensities should only be considered as rough qualitative estimates due to neglect of the wavelength dependence of the spectrograph efficiency and the sensitivity of the photographic plates, as well as due to the non-linearity of their response. Nevertheless, the relative line intensities follow the branching ratios represented by the calculated gA values, which was sufficient for the identification of the spectrum.

4. Conclusions

This study of the vacuum spark spectrum of twice-ionized platinum results in the identification of 241 new spectral lines in the range 728–2062 Å. New lines belong mostly to the 5d76s − (5d76p − 5d66s6p) transitions. The number of known Pt III lines was increased to more than 1000. Ninety-one new high-lying levels of the odd configurations were found. The levels of the 5d66s6p configuration strongly interact with the levels of the upper part of the 5d76p configuration, resulting in a mixture of their wavefunctions. The upper levels of the 5d66s6p configuration also overlap with those of the 5d77p and 5d75f configurations. Accurate predictions of their interaction, along with observations in the visible part of the spectrum, are needed for further extension of the Pt III analysis.

Funding

This work was supported by the research project FFUU-2022-0005 of the Institute of Spectroscopy of the Russian Academy of Sciences.

Data Availability Statement

All data that support the findings of this study are included within the article.

Acknowledgments

I am grateful to A J J Raassen and P H M Uylings for help in using their suite of codes for orthogonal parameters calculations.

Conflicts of Interest

The author declares no conflict of interest.

References

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Table 1. New lines in the (5d8 + 5d76s) − (5d76p + 5d66s6p) transition array of Pt III.
Table 1. New lines in the (5d8 + 5d76s) − (5d76p + 5d66s6p) transition array of Pt III.
Lower LevelUpper Level
gA,Int1λo.-c. 2νJElow3Name 4JEupperName 5Remark 6
107 s−1 (Å)(Å)(cm−1) (cm−1) (cm−1)
6214728.431−0.001137,281.439751.5 c1|3F2)2147,032.61|2D1)3D
1849762.0990.000131,216.5436,530.12|4F3)3F4167,746.72|1G2G,3F
31310785.4230.002127,319.9332,266.62|4F3)5F3159,586.92|5D4D,5F
16319788.2330.007126,866.0421,330.5 c1|1G2)3148,197.61|2D1)1F
24050790.9020.004126,437.9421,330.5 c1|1G2)3147,769.01|2D1)1FIV
18213792.6880.005126,153.0343,057.22|4F3)3F3169,211.02|3G2G,1F
46715798.092−0.001125,298.8427,888.22|4F3)5F5153,186.92|3H4H,5G
5517798.561−0.002125,225.2214,171.91|3F2)1139,396.91|2D1)3D
51524798.625−0.003125,215.2542,531.9 c2|2G3)3G4167,746.72|1G2G,3F
129614799.5840.001125,065.0648,134.22|2H3)3H5173,199.42|3H4H,3G
10722799.7090.001125,045.5521,836.72|4F3)5F4146,882.31|2D1)3F
57645804.607−0.001124,284.3427,888.22|4F3)5F4152,172.32|5D4D,3F
61766805.445 124,155.0521,836.72|4F3)5F6145,991.72|3G4G,5G
38415806.420−0.002124,004.9336,970.22|4P3)5P4160,974.82|3H4H,5H
36050812.623−0.002123,058.3521,836.72|4F3)5F5144,894.72|3G4G,5G
43850812.623−0.010123,058.3436,530.12|4F3)3F3159,586.92|5D4D,5F
59921813.690 122,896.9648,134.22|2H3)3H7171,031.12|3H2H,3I
24522815.5520.002122,616.3336,970.22|4P3)5P3159,586.92|5D4D,5F
587816.376−0.005122,492.6224,540.8 c1|1D2)2147,032.61|2D1)3D
65527817.606−0.001122,308.3445,438.62|2G3)3G4167,746.72|1G2G,3F
68855817.7270.000122,290.2521,836.72|4F3)5F5144,126.92|3H4H,5G
13510818.2620.002122,210.2445,438.62|2G3)3G3167,649.22|3G4G,3G
144913821.331−0.001121,753.6551,446.02|2H3)3H5173,199.42|3H4H,3G
2314821.406−0.004121,742.540.01|3F2)3121,741.92|5D6D,7F
98837821.818 121,681.4332,266.62|4F3)5F3153,948.02|3F4F,5F
5327822.467−0.001121,585.4427,888.22|4F3)5F4149,473.52|3H4H,5G
32946823.827−0.001121,384.7427,888.22|4F3)5F3149,272.72|3G4G,5G
13024824.759−0.002121,247.5436,530.12|4F3)3F4157,777.42|3F4F,5FIV
406824.8220.002121,238.3214,171.91|3F2)2135,410.52|5D6D,7D
98447826.580 120,980.4648,134.22|2H3)3H6169,114.62|3H4H,3I
6512827.8680.000120,792.2436,530.12|4F3)3F5157,322.32|3D4D,5F
19817829.545−0.008120,548.0427,888.22|4F3)5F4148,435.02|3F4F,5GRy
19221831.1920.002120,309.1427,888.22|4F3)5F3148,197.61|2D1)1F
9335832.888−0.003120,064.2116,781.61|3P2)2136,845.31|2D1)3P
510111833.7360.000119,942.0236,291.52|4P3)5P2156,233.62|3F4F,5FOIII
4312833.9900.001119,905.5332,266.62|4F3)5F4152,172.32|5D4D,3F
27041834.1640.002119,880.5427,888.22|4F3)5F3147,769.01|2D1)1F
4822838.472−0.008119,264.6336,970.22|4P3)5P2156,233.62|3F4F,5F
106339840.696 118,949.1551,446.02|2H3)3H6170,395.12|1I2I,3I
6339842.961−0.004118,629.5116,781.61|3P2)2135,410.52|5D6D,7D
19848843.6280.000118,535.7521,836.72|4F3)5F5140,372.42|3H4H,5I
109755844.2900.001118,442.7542,531.9 c2|2G3)3G4160,974.82|3H4H,5H
78729845.939 118,211.8332,266.62|4F3)5F4150,478.42|3F4F,5F
59320847.9080.005117,937.3542,531.9 c2|2G3)3G6160,469.92|3F4F,5G
647848.198−0.004117,897.0436,530.12|4F3)3F4154,426.52|3H4H,5G
28529848.744−0.005117,821.2427,888.22|4F3)5F3145,708.72|3G4G,5H
1777849.0170.002117,783.3349,963.2 c2|2G3)3G4167,746.72|1G2G,3F
43131849.347−0.007117,737.5427,888.22|4F3)5F4145,624.82|3G4G,5F
37879849.491 117,717.6421,330.5 c1|1G2)3139,048.11|2D1)3F
81527849.716−0.003117,686.4349,963.2 c2|2G3)3G3167,649.22|3G4G,3G
48628851.3810.001117,456.2336,970.22|4P3)5P4154,426.52|3H4H,5G
47825851.482 117,442.3542,531.9 c2|2G3)3G5159,974.22|3F4F,5F
25238852.6880.007117,276.2421,330.5 c1|1G2)3138,607.72|3D4D,5F
15910852.752−0.004117,267.4436,530.12|4F3)3F5153,797.02|5D4D,5F
63557853.1920.000117,206.9332,266.62|4F3)5F4149,473.52|3H4H,5G
41021853.257−0.004117,198.0452,013.62|2G3)1G3169,211.02|3G2G,1F
82261854.6540.001117,006.4427,888.22|4F3)5F5144,894.72|3G4G,5G
66038855.287 116,919.8542,531.9 c2|2G3)3G5159,451.72|3H4H,5H
43037856.657 116,732.8140,963.6 c2|4P3)5P1157,696.42|3F4F,5D
114953857.213−0.002116,657.1436,530.12|4F3)3F5153,186.92|3H4H,5G
2805121857.7490.001116,584.2521,836.72|4F3)5F4138,421.02|5D6D,5D
42438858.557 116,474.5445,438.62|2G3)3G4161,913.12|1G2G,3G
302119858.885−0.007116,430332,266.62|4F3)5F3148,695.72|5D4D,5D
2784119858.885 116,430.0521,836.72|4F3)5F5138,266.72|5D6D,5F
34431859.8620.001116,297.7332,266.62|4F3)5F2148,564.41|2D1)3D
140474860.2990.000116,238.7427,888.22|4F3)5F5144,126.92|3H4H,5G
42534860.8250.006116,167.6332,266.62|4F3)5F4148,435.02|3F4F,5G
24643861.1240.002116,127.3421,330.5 c1|1G2)3137,458.12|3F4F,5G
128628864.0590.002115,732.8452,013.62|2G3)1G4167,746.72|1G2G,3F
54031864.7370.001115,642.1436,530.12|4F3)3F4152,172.32|5D4D,3F
35311864.784−0.002115,635.8452,013.62|2G3)1G3167,649.22|3G4G,3G
4911864.7840.002115,635.8116,781.61|3P2)2132,417.72|3F4F,5G
2646124865.207 115,579.3521,836.72|4F3)5F6137,416.02|3H4H,5G
17721865.782−0.001115,502.5332,266.62|4F3)5F3147,769.01|2D1)1F
60233867.7140.001115,245.3542,531.9 c2|2G3)3G4157,777.42|3F4F,5F
60428870.575−0.003114,866.6542,531.9 c2|2G3)3G6157,398.12|1I2I,3H
15322870.6560.001114,855.9224,540.8 c1|1D2)1139,396.91|2D1)3D
69439871.149−0.004114,790.9542,531.9 c2|2G3)3G5157,322.32|3D4D,5F
1589871.3440.006114,765.2332,266.62|4F3)5F2147,032.61|2D1)3D
30523871.4910.002114,745.9233,949.62|4F3)5F3148,695.72|5D4D,5D
40111871.6870.001114,720.1343,057.22|4F3)3F4157,777.42|3F4F,5F
12210872.4900.002114,614.5233,949.62|4F3)5F2148,564.41|2D1)3D
9417874.330−0.001114,373.3134,912.52|4F3)5F0149,285.72|5D4D,3P
82736875.3070.010114,245.6236,291.52|4P3)5P3150,538.42|3H4H,5G
18337875.982−0.004114,157.6332,266.62|4F3)5F2146,423.72|3F4F,5F
55737875.982 114,157.6354,095.72|2D3)3D3168,253.32|3D2D,1F
333979876.126 114,138.8648,134.22|2H3)3H6162,273.02|1I2I,3H
63261878.6420.006113,812.0427,888.22|4F3)5F4141,701.02|3H4H,5H
14612879.1010.003113,752.6542,531.9 c2|2G3)3G6156,284.82|1I2I,3K
20764880.210 113,609.3116,781.61|3P2)0130,390.91|2D3)3P
5038880.519−0.009113,569.4336,970.22|4P3)5P3150,538.42|3H4H,5G
7512881.5160.009113,440.9332,266.62|4F3)5F3145,708.72|3G4G,5H
19411882.036−0.002113,374.1648,134.22|2H3)3H5161,508.02|3D4D,5F
2411882.153−0.006113,359.0332,266.62|4F3)5F4145,624.82|3G4G,5F
90078883.8600.000113,140.1427,888.22|4F3)5F3141,028.32|5D4D,3D
9119885.1040.001112,981.1236,291.52|4P3)5P3149,272.72|3G4G,5G
20127885.395−0.004112,943.9436,530.12|4F3)3F4149,473.52|3H4H,5G
97542886.170 112,845.2648,134.22|2H3)3H7160,979.42|3H4H,3I
20558888.557 112,542.0521,836.72|4F3)5F6134,378.72|3H4H,5H
4715889.013−0.001112,484.3427,888.22|4F3)5F5140,372.42|3H4H,5I
18918889.0940.000112,474.0233,949.62|4F3)5F2146,423.72|3F4F,5F
34445889.300 112,448.0521,836.72|4F3)5F4134,284.72|3H4H,5I
8011890.185−0.004112,336.2648,134.22|2H3)3H6160,469.92|3F4F,5G
19768890.4390.003112,304.2224,540.8 c1|1D2)2136,845.31|2D1)3P
3638891.538−0.001112,165.7436,530.12|4F3)3F3148,695.72|5D4D,5D
85750893.485−0.002111,921.3542,531.9 c2|2G3)3G6154,452.92|3H4H,5G
10632893.6180.002111,904.6436,530.12|4F3)3F4148,435.02|3F4F,5G
5410896.101−0.003111,594.6336,970.22|4P3)5P2148,564.41|2D1)3D
34862896.226−0.004111,579.0421,330.5 c1|1G2)3132,909.11|2P3)3D
9012896.7710.000111,511.2134,912.52|4F3)5F2146,423.72|3F4F,5F
100951896.9470.002111,489.3551,446.02|2H3)3H5162,935.52|1I2I,3H
2716898.622−0.003111,281.539751.5 c1|3F2)4121,032.62|5D6D,7F
68127898.7570.003111,264.8542,531.9 c2|2G3)3G5153,797.02|5D4D,5F
18812899.053−0.006111,228.1336,970.22|4P3)5P3148,197.61|2D1)1F
286900.442−0.001111,056.6245,177.22|4F3)3F2156,233.62|3F4F,5F
10210902.534−0.003110,799.1336,970.22|4P3)5P3147,769.01|2D1)1F
5414903.0080.001110,741.0236,291.52|4P3)5P2147,032.61|2D1)3D
6315903.1830.000110,719.5427,888.22|4F3)5F3138,607.72|3D4D,5F
3423906.1770.002110,353.7332,266.62|4F3)5F3142,620.62|3F4F,5DRy
17140906.514−0.001110,312.7521,836.72|4F3)5F4132,149.241|2F3)3F
2328906.8650.002110,270.040.01|3F2)4110,270.32|5D6D,7D
27516908.5810.002110,061.7551,446.02|2H3)3H5161,508.02|3D4D,5F
939909.8900.008109,903.4146,329.22|2P3)1P2156,233.62|3F4F,5F
187910.985−0.005109,771.3214,171.91|3F2)1123,942.532|5D6D,7F
45214913.288−0.001109,494.5452,013.62|2G3)1G5161,508.02|3D4D,5F
11311913.554−0.002109,462.6233,949.62|4F3)5F3143,412.02|3G4G,5H
52328915.2160.001109,263.8648,134.22|2H3)3H6157,398.12|1I2I,3H
1229915.4250.002109,238.9358,410.12|2F3)3F3167,649.22|3G4G,3G
8830917.4040.003109,003.2014,939.01|3P2)1123,942.532|5D6D,7F
43222917.5360.003108,987.5445,438.62|2G3)3G4154,426.52|3H4H,5G
30631917.845 108,950.9542,531.9 c2|2G3)3G5151,482.82|3F4F,5G
1229919.438−0.003108,762.1332,266.62|4F3)5F3141,028.32|5D4D,3D
50038919.534 108,750.7648,134.22|2H3)3H7156,885.02|1I2I,3K
705919.6450.008108,737.6336,970.22|4P3)5P3145,708.72|3G4G,5H
5121920.2380.001108,667.5214,171.91|3F2)2122,839.52|5D6D,7F
457920.3540.006108,653.8336,970.22|4P3)5P4145,624.82|3G4G,5F
10717922.776−0.004108,368.7224,540.8 c1|1D2)3132,909.11|2P3)3D
2997924.6410.004108,150.1648,134.22|2H3)3H6156,284.82|1I2I,3K
2310925.0610.000108,101.0214,171.91|3F2)1122,272.92|5D6D,7F
20027926.980−0.003107,877.2224,540.8 c1|1D2)2132,417.72|3F4F,5G
17941928.0910.002107,748.1445,438.62|2G3)3G5153,186.92|3H4H,5GRy
5834931.6730.001107,333.8014,939.01|3P2)1122,272.92|5D6D,7F
278933.174−0.002107,161.2116,781.61|3P2)1123,942.532|5D6D,7F
13818933.5300.002107,120.3236,291.52|4P3)5P3143,412.02|3G4G,5H
188935.0900.000106,941.6542,531.9 c2|2G3)3G4149,473.52|3H4H,5G
916940.5710.003106,318.4648,134.22|2H3)3H6154,452.92|3H4H,5G
35235942.590−0.001106,090.7436,530.12|4F3)3F3142,620.62|3F4F,5D
1269943.8240.001105,952.0551,446.02|2H3)3H6157,398.12|1I2I,3H
1111947.9500.005105,490.8116,781.61|3P2)1122,272.92|5D6D,7F
12437948.8600.001105,389.6521,836.72|4F3)5F4127,226.42|5D4D,3F
19511949.5920.003105,308.4452,013.62|2G3)1G5157,322.32|3D4D,5F
1625951.861−0.007105,057.439751.5 c1|3F2)3114,808.12|5D6D,7D
7931952.4430.001104,993.2214,171.91|3F2)1119,165.212|5D6D,7D
37426953.838−0.007104,839.6551,446.02|2H3)3H6156,284.82|1I2I,3K
7012954.823−0.006104,731.5336,970.22|4P3)5P4141,701.02|3H4H,5H
15343957.677 104,419.3521,836.72|4F3)5F5126,256.02|5D6D,7D
3935959.4560.004104,225.7014,939.01|3P2)1119,165.212|5D6D,7D
7251960.590 104,102.7436,530.12|4F3)3F4140,632.82|3H4H,5I
1148961.0040.002104,057.8336,970.22|4P3)5P3141,028.32|5D4D,3D
986961.2190.003104,034.6445,438.62|2G3)3G4149,473.52|3H4H,5G
11331964.767 103,652.0014,939.01|3P2)1118,591.02|5D6D,7D
628966.103−0.001103,508.6233,949.62|4F3)5F3137,458.12|3F4F,5G
255969.5210.002103,143.7332,266.62|4F3)5F2135,410.52|5D6D,7D
406971.2840.000102,956.5146,329.22|2P3)1P0149,285.72|5D4D,3P
117971.875−0.001102,893.9460,041.7 c2|2H3)3H5162,935.52|1I2I,3H
4216973.7520.001102,695.6224,540.8 c1|1D2)3127,236.52|5D4D,5D
655974.159−0.011102,652.6343,057.22|4F3)3F3145,708.72|3G4G,5H
3912979.6480.001102,077.5436,530.12|4F3)3F3138,607.72|3D4D,5F
23635981.963 101,836.8648,134.22|2H3)3H7149,971.02|3H4H,5H
8421983.8930.004101,637.1336,970.22|4P3)5P3138,607.72|3D4D,5FRy
13820985.6990.000101,450.8336,970.22|4P3)5P4138,421.02|5D6D,5D
913995.894−0.009100,412.3421,330.5 c1|1G2)3121,741.92|5D6D,7F
17101002.982−0.00699,702.7421,330.5 c1|1G2)4121,032.62|5D6D,7F
80341006.559−0.00199,348.4427,888.22|4F3)5F3127,236.52|5D4D,5DRy
43231006.654−0.00899,339.0427,888.22|4F3)5F4127,226.42|5D4D,3F
56381008.104−0.00299,196.1521,836.72|4F3)5F4121,032.62|5D6D,7F
53961025.5880.00297,505.0134,912.52|4F3)5F2132,417.72|3F4F,5GRy
18121031.7880.00096,919.1349,963.2 c2|2G3)3G4146,882.31|2D1)3F
26111045.3550.00395,661.3349,963.2 c2|2G3)3G4145,624.82|3G4G,5F
19121050.646−0.00595,179.5336,970.22|4P3)5P4132,149.241|2F3)3F
15181051.757−0.00295,079.0116,781.61|3P2)0111,860.431|4F3)5D
3191053.0830.00694,959.3332,266.62|4F3)5F4127,226.42|5D4D,3F
5101056.809−0.00194,624.5224,540.8 c1|1D2)1119,165.212|5D6D,7D
63291065.480−0.00893,854.4427,888.22|4F3)5F3121,741.92|5D6D,7F
32101104.078−0.00590,573.3332,266.62|4F3)5F2122,839.52|5D6D,7F
9211111.6220.00189,958.625293.11|1D2)195,251.801|4F3)5FCh
691115.849−0.00689,617.9542,531.9 c2|2G3)3G4132,149.241|2F3)3F
991155.2040.00186,564.8445,438.62|2G3)3G5132,003.42|3G4G,5H
29131170.2700.00085,450.4236,291.52|4P3)5P3121,741.92|5D6D,7F
51161179.6400.00184,771.6336,970.22|4P3)5P3121,741.92|5D6D,7F
26111189.5920.00084,062.4336,970.22|4P3)5P4121,032.62|5D6D,7F
16241192.3410.00983,868.6648,134.22|2H3)3H5132,003.42|3G4G,5H
211301213.852−0.00482,382.4427,888.22|4F3)5F4110,270.32|5D6D,7DIV
1291239.1100.00280,703.1551,446.02|2H3)3H4132,149.241|2F3)3F
6191240.0570.01080,641.5214,171.91|3F2)294,813.991|4F3)5GCh
18261241.3510.00180,557.4551,446.02|2H3)3H5132,003.42|3G4G,5H
6751245.125−0.00780,313.2014,939.01|3P2)195,251.801|4F3)5F
1981247.880−0.00480,135.9452,013.62|2G3)1G4132,149.241|2F3)3F
3151274.3750.00678,469.8116,781.61|3P2)195,251.801|4F3)5FCh
15111281.1750.00378,053.3354,095.72|2D3)3D4132,149.241|2F3)3F
17111284.7210.00077,837.9336,970.22|4P3)5P3114,808.12|5D6D,7D
30151288.4390.00177,613.3146,329.22|2P3)1P1123,942.532|5D6D,7F
26231299.575−0.00576,948.2134,912.52|4F3)5F0111,860.431|4F3)5D
10131316.649−0.00375,950.4246,322.72|4P3)3P1122,272.92|5D6D,7F
20121328.6170.00675,266.2052,119.222|4P3)3P1127,385.801|2F3)3DRy
56851364.2580.00373,299.9336,970.22|4P3)5P4110,270.32|5D6D,7D
26371372.182−0.00672,876.6349,963.2 c2|2G3)3G2122,839.52|5D6D,7F
41431390.683−0.00671,907.1366,700.92|2F3)1F3138,607.72|3D4D,5F
60481410.5020.00270,896.7140,963.6 c2|4P3)5P0111,860.431|4F3)5D
7181414.2150.00870,710.6224,540.8 c1|1D2)195,251.801|4F3)5FCh
81261415.0060.00370,671.1561,332.202|2H3)1H5132,003.42|3G4G,5H
60231440.1180.00269,438.8154,503.72|4P3)3P1123,942.532|5D6D,7F
13201441.5580.00369,369.4445,438.62|2G3)3G3114,808.12|5D6D,7D
60101455.961−0.00468,683.2464,226.12|2F3)3F3132,909.11|2P3)3D
153421472.248−0.00467,923.3464,226.12|2F3)3F4132,149.241|2F3)3F
163201475.410−0.00967,777.8464,226.12|2F3)3F5132,003.42|3G4G,5H
119171478.107−0.01367,654.1061,022.82|4P3)3P1128,676.301|2P3)3S
384711493.6510.00766,950.0265,958.72|2D3)1D3132,909.11|2P3)3DRy
80231493.9490.00566,936.7354,095.72|2D3)3D4121,032.62|5D6D,7F
30121516.7460.00765,930.6256,908.62|2F3)3F2122,839.52|5D6D,7F
14131525.9930.00365,531.1146,329.22|2P3)1P0111,860.431|4F3)5D
128311527.9320.00965,447.9366,700.92|2F3)1F4132,149.241|2F3)3F
57711546.5160.00164,661.5154,503.72|4P3)3P1119,165.212|5D6D,7DIV
37141563.2510.00863,969.3257,772.32|2F3)3F3121,741.92|5D6D,7F
11261598.777−0.01162,547.81332,266.62|4F3)5F294,813.991|4F3)5G
46461606.254−0.00162,256.65256,908.62|2F3)3F1119,165.212|5D6D,7D
59401608.561−0.00262,167.37052,119.222|4P3)3P1114,286.501|4P3)3P
63261616.181−0.00261,874.26061,022.82|4P3)3P1122,897.001|2D3)1P
5111631.255−0.00861,302.49233,949.62|4F3)5F195,251.801|4F3)5FCh
56981642.992−0.00560,864.57233,949.62|4F3)5F294,813.991|4F3)5G
501201657.275−0.02060,340.0134,912.52|4F3)5F195,251.801|4F3)5FCh
37331666.938−0.00159,990.230521,19.222|4P3)3P1112,109.401|2P3)3D
1181361669.401−0.00759,901.73134,912.52|4F3)5F294,813.991|4F3)5GCh
53711696.0590.00358,960.21236,291.52|4P3)5P195,251.801|4F3)5FCh
941031708.7530.00858,522.21236,291.52|4P3)5P294,813.991|4F3)5GCh
1871719.914−0.00158,142.44061,022.82|4P3)3P1119,165.212|5D6D,7D
4291728.787−0.00757,844.03336,970.22|4P3)5P294,813.991|4F3)5G
36121750.3320.01257,132.02061,022.82|4P3)3P1118,155.201|4P3)3S
48891842.0230.00254,288.14140,963.6 c2|4P3)5P195,251.801|4F3)5FCh
29581856.995−0.00253,850.44140,963.6 c2|4P3)5P294,813.991|4F3)5G
22391997.0200.00050,074.61245,177.22|4F3)3F195,251.801|4F3)5FCh
36862013.9920.00849,636.60245,177.22|4F3)3F294,813.991|4F3)5G
10222043.1200.00248,929.05246,322.72|4P3)3P195,251.801|4F3)5F
9272061.5780.01148,491.03246,322.72|4P3)3P294,813.991|4F3)5G
1 Relative intensity in arbitrary units. 2 Difference between the observed wavelength and the wavelength derived from the final level energies (Ritz wavelength). A blank value indicates that the upper level is derived only from that line. 3 The level values are from [1]. The values marked by “c” are corrected in this work. 4 The number preceding the “|” symbol has the following meaning: 1 stands for 5d8 and 2 stands for 5d76s. 5 The number preceding the “|” symbol has the following meaning: 1 stands for 5d76p and 2 stands for 5d66s6p. 6 IV—identified also as Pt IV [20]; OIII—blended by strong O III line, Ritz wavelength and wavenumber are listed; Ry—belongs also to the (5d8 + 5d7s)—5d76p transition array [1]; Ch—identification in [1] is changed.
Table 2. Observed and calculated using the orthogonal parameters technique energy levels (cm−1) of the 5d76p + 5d66s6p configurations of Pt III.
Table 2. Observed and calculated using the orthogonal parameters technique energy levels (cm−1) of the 5d76p + 5d66s6p configurations of Pt III.
EobsUnc. aNbEcalco.-c. cComposition d
J = 0
149,285.70.4 149,349−6326% 2|5D4D,3P+14% 2|5D6D,5D+12% 2|3P4P,5D
147,317 25% 2|5D4D,5D+19% 2|1S2S,3P+11% 2|3P4P,5D
146,374 60% 1|2D1)3P+6% 2|3P4P,5D+5% 2|3P4P,5D
143,134 26% 2|3D4D,5D+23% 2|3P4P,5D+17% 2|1S2S,3P
133,880 23% 2|5D4D,5D+13% 2|5D6D,5D+13% 2|3D4D,5D
130,390.90.71130,452−6151% 1|2D3)3P+10% 1|2D1)3P+10% 1|2P3)1S
123,702.4 123,734−3253% 1|4P3)3P+24% 1|2P3)1S+6% 1|4F3)5D
122,331 71% 2|5D6D,7F+12% 2|3P4P,5D+4% 2|5D6D,5D
111,860.430.164111,901−4141% 1|4F3)5D+16% 1|4P3)5D+15% 1|2P3)1S
110,739.0 110,7063359% 1|2P3)3P+14% 1|4F3)5D+13% 1|4P3)5D
102,848 33% 1|2P3)1S+23% 1|4P3)3P+ 20% 1|2D3)3P
95,833.6 95,829553% 1|4P3)5D+24% 1|2P3)3P+13% 1|4F3)5D
J = 1
157,696.40.71157,735−3941% 2|3F4F,5D+8% 2|3D4D,5D+8% 2|3F4F,5F
155,885 11% 2|5D6D,5D+10% 2|3G4G,5F+10% 2|5D4D,5D
155,097 16% 2|3G4G,5F+13% 2|3D2D,3D+7% 2|3D2D,1P
154,597 13% 2|3D4D,5P+12% 2|1S2S,3P+9% 2|5D6D,5D
153,183 35% 2|3P4P,5D+13% 2|3P4P,5D+6% 2|3P4P,3P
152,810 15% 1|2D1)1P+9% 2|3D4D,5P+9% 2|5D4D,3D
152,767 22% 1|2D1)1P+9% 2|3P4P,5P+6% 1|2D1)3D
151,301 18% 2|5D4D,3D+13% 1|2D1)1P+6% 2|5D4D,3P
149,758 22% 2|3D4D,5F+12% 2|3F4F,5F+10% 2|5D4D,5F
146,578 25% 1|2D1)3P+21% 2|5D6D,5P+12% 1|2D1)3D
145,546 13% 2|5D6D,5P+11% 1|2D1)3P+8% 1|2D1)3D
145,413 10% 2|3P2P,3S+8% 2|3F4F,5F+6% 2|3D4D,5D
144,108 11% 1|2D1)3P+8% 2|5D4D,3P+8% 2|3F4F,5D
142,425 18% 2|3F4F,5F+18% 2|3D4D,5F+7% 2|5D4D,5D
140,355 17% 2|3D4D,5D+14% 2|3P4P,5D+13% 2|3D4D,5F
139,396.90.52139,504−10737% 1|2D1)3D+14% 1|2D1)3P+12% 1|2D1)1P
136,376 19% 2|5D4D,5F+16% 2|3D4D,5F+11% 2|5D6D,5F
133,752.0 133,832−8018% 1|2D3)3D+18% 1|2P3)1P+8% 1|2D1)1P
132,855 16% 2|5D4D,5D+8% 2|5D6D,5D+7% 1|2D3)3P
128,676.30.61128,704−2732% 1|2P3)3S+10% 1|4P3)3P+9% 1|4P3)3D
127,385.80.31127,25213448% 1|2F3)3D+15% 1|2D3)1P+7% 1|2P3)1P
123,942.530.185123,77516731% 2|5D6D,7F+14% 1|2D3)3P+12% 1|4F3)5D
122,897.00.091122,899−228% 1|2D3)1P+12% 1|4P3)3D+11% 1|2P3)3P
122,272.90.34122,2373624% 2|5D6D,7F+18% 1|2D3)3P+10% 2|5D6D,7D
119,165.210.116119,217−5225% 2|5D6D,7D+11% 1|2D3)3D+9% 1|4P3)3D
118,591.00.51118,668−7730% 2|5D6D,7D+14% 1|2D3)3D+8% 2|5D6D,7F
118,155.20.131118,281−12617% 1|4P3)3S+13% 1|2P3)3D+12% 1|4F3)3D
114,286.50.091114,286022% 1|4P3)3P+19% 1|4F3)3D+14% 1|2P3)3P
112,109.40.091112,0129824% 1|2P3)3D+16% 1|4P3)3S+13% 1|4P3)5D
110,136.2 110,152−1531% 1|4P3)3P+18% 1|2P3)1P+14% 1|4P3)3D
108,594.2 108,5217324% 1|4F3)3D+20% 1|4P3)3S+10% 1|4P3)5D
107,563.6 107,594−3028% 1|4F3)5F+28% 1|4P3)5P+9% 1|2D3)3P
104,357.2 104,2926536% 1|4F3)5D+17% 1|2P3)3D+9% 1|2D3)3P
100,009.8 99,9367419% 1|4P3)5D+16% 1|4P3)5P+11% 1|4F3)5F
95,251.800.081095,269−1727% 1|4F3)5F+26% 1|4P3)5D+10% 1|4F3)3D
88,207.8 88,260−5320% 1|2P3)3P+13% 1|2D3)3D+10% 1|4P3)5D
J = 2
156,233.60.54156,11212115% 2|3F4F,5F+8% 2|3D4D,5D+8% 2|1D2D,3P
155,772 20% 2|5D6D,5D+ 10% 2|5D4D,5F+9% 2|5D4D,5D
154,420 14% 2|5D4D,3F+10% 2|3F4F,5D+10% 2|3G4G,5F
153,809 13% 2|3D4D,5P+9% 2|3F4F,5F+8% 2|3D4D,5F
153,236 18% 2|3P4P,5D+15% 2|3H4H,5G+10% 2|3D4D,5F
150,933 13% 2|5D4D,3D+11% 2|3H4H,5G+7% 2|5D6D,5P
150,302 15% 2|3H4H,5G+7% 1|2D1)1D+6% 2|5D4D,3D
149,714 28% 1|2D1)1D+7% 1|2D3)1D+6% 1|2D1)3P
148,564.40.44148,636−7119% 1|2D1)3D+12% 2|5D4D,3F+4% 1|2D1)1D
147,032.60.54147,028529% 1|2D1)3D+7% 2|3D4D,5F+7% 2|3F4F,5D
146,423.70.43146,499−758% 2|3F4F,5F+7% 2|5D6D,5F+6% 2|5D6D,5P
146,037 10% 2|3D4D,5F+8% 2|5D6D,5F+7% 2|5D4D,3D
145,832 29% 2|5D4D,3P+13% 2|3G4G,5G+5% 2|3P4P,5D
143,113 10% 2|3P4P,5S+10% 2|5D4D,3D+6% 2|3F4F,5D
142,544 19% 2|5D6D,5P+9% 2|5D4D,5P+7% 2|3G4G,5G
140,507 15% 2|3D4D,5F+14% 2|3F4F,5G+8% 2|5D4D,5F
139,096 35% 2|3F4F,5G+12% 2|3D4D,5F+6% 2|3F4F,5F
137,347 18% 2|5D6D,7P+13% 1|2D1)3P+7% 2|5D4D,5D
136,845.30.62136,59624917% 1|2D1)3P+15% 1|2D1)3F+ 14% 2|5D6D,7P
136,444 27% 1|2D1)3F+22% 2|5D6D,7P+6% 2|5D4D,5F
135,410.50.43135,509−9817% 2|5D6D,7D+13% 2|5D6D,7P+9% 1|2D1)3P
133,233.6 133,225814% 1|2F3)3D+14% 1|2F3)1D+13% 1|2D3)3D
132,417.70.43132,649−23112% 2|3F4F,5G+9% 2|5D4D,5F+8% 1|2D1)3F
129,491 13% 2|5D4D,5D+8% 2|3P4P,5S+8% 2|5D6D,7F
129,160.1 129,0778413% 1|2F3)3D+11% 1|2P3)3P+10% 1|2F3)1D
127,875.4 127,899−2423% 1|2P3)1D+13% 1|2F3)3F+10% 1|2D3)1D
125,841.1 125,8122912% 1|2F3)3F+9% 1|2D1)3P+9% 1|2F3)3D
124,596.7 124,5663129% 1|2P3)3D+ 10% 1|2D3)1D+9% 1|2G3)3F
122,839.50.24122,7637637% 2|5D6D,7F+11% 2|5D6D,7D+5% 2|3P4P,5D
121,453.7 121,4282611% 1|4P3)3D+10% 1|2D3)3P+10% 1|2F3)3D
119,574.4 119,5136125% 1|2G3)3F+12% 1|2D3)3F+10% 1|2P3)3P
117,247.1 117,287−4016% 1|2P3)3D+13% 1|4P3)3D+9% 1|4F3)3F
116,104 51% 2|5D6D,7D+16% 2|5D6D,7F+6% 2|3P4P,5P
115,421.4 115,3754613% 1|2F3)1D+13% 1|2D3)3P+12% 1|4F3)3D
113,020.4 113,023−319% 1|4P3)5P+14% 1|4P3)5D+9% 1|2P3)1D
112,195.4 112,269−7423% 1|2F3)3F+15% 1|4F3)3D+13% 1|2F3)1D
110,120.4 110,1011919% 1|4P3)3P+15% 1|4F3)3F+12% 1|4P3)5P
108,482.2 108,519−3616% 1|4P3)3D+12% 1|4F3)5F+10% 1|2D3)3F
107,247.0 107,341−9417% 1|4F3)5F+15% 1|4F3)5G+12% 1|4P3)5D
105,352.8 105,2955812% 1|4F3)5G+11% 1|4F3)3D+11% 1|2P3)1D
103,891.0 103,8622916% 1|4F3)3F+14% 1|4P3)3P+12% 1|4F3)5F
102,608.9 102,5802923% 1|4F3)5D+17% 1|2P3)3P+15% 1|2D3)3D
94,813.990.10994,7635136% 1|4F3)5G+17% 1|4P3)5D+12% 1|2D3)3F
92,944.1 92,999−5533% 1|4P3)5S+20% 1|4F3)5F+10% 1|4P3)5P
89,707.2 89,752−4413% 1|4P3)5D+12% 1|4F3)5F+10% 1|2P3)3D
88,420.3 88,467−4721% 1|4P3)5S+9% 1|2P3)3P+9% 1|2P3)3D
J = 3
169,211.00.72169,209212% 2|3G2G,1F+10% 2|3G2G,3F+6% 4|4F3)3D
168,430 10% 2|3F2F,3F+10% 2|3F4F,5G+9% 2|1G2G,3F
168,253.30.81168,1936013% 2|3D2D,1F+10% 2|3D4D,3D+6% 2|3D2D,3D
167,649.20.44167,697−4710% 2|3G4G,3G+8% 2|3G2G,1F+7% 2|3G2G,3G
167,251 19% 2|1G2G,3G+14% 2|3G4G,3F+4% 4|4F3)3D
165,979 7% 2|3P4P,5D+7% 2|1D2D,3F+6% 2|3G2G,1F
164,989 15% 2|3F4F,5D+9% 2|3F2F,3G+7% 2|3G4G,5F
163,914 10% 2|3D4D,3D+9% 2|3D4D,3F+7% 2|3D2D,3D
162,629 18% 2|3H4H,5G+7% 2|3F4F,3D+6% 2|3H2H,3G
161,633 17% 2|3D4D,5D+8% 2|3F4F,5D+6% 2|3P4P,5P
161,492 8% 2|1F2F,3G+7% 2|3G4G,5G+6% 2|3P4P,5D
160,392 13% 2|3H4H,3G+13% 2|3H2H,3G+8% 2|3F2F,3D
159,586.90.63159,693−10612% 2|5D4D,5F+11% 2|5D4D,5P+8% 2|3D4D,5D
158,999 20% 2|5D4D,5F+7% 2|5D4D,5D+6% 2|3P2P,3D
158,372 15% 2|3F4F,5F+6% 2|1F2F,3D+5% 2|3G2G,3F
157,279 10% 2|3D2D,3F+7% 2|5D6D,5P+6% 2|1F2F,3G
156,755 13% 2|3F2F,3G+9% 2|3G4G,5F+8% 2|3D4D,5D
155,965 12% 2|3D4D,5P+7% 2|3G2G,3G+7% 2|5D6D,5P
155,352 9% 2|1F2F,3D+9% 2|3G4G,5H+8% 2|3D2D,3F
155,018 5% 2|1F2F,3G+5% 2|3P4P,5D+5% 2|5D6D,5P
153,948.00.71153,94449% 2|3F4F,5F+9% 2|1F2F,3G+8% 2|3G4G,5F
152,496 18% 2|3H4H,5H+8% 1|2D1)3D+8% 2|3F2F,3G
151,989 12% 2|5D6D,5D+11% 2|5D4D,5D+10% 2|5D4D,5P
151,519 26% 1|2D1)3D+14% 1|2D1)1F+6% 1|2D3)3D
150,538.41.02150,768−23013% 2|3H4H,5G+11% 2|3D4D,5P+9% 2|5D6D,5P
149,272.70.52149,636−36322% 2|3G4G,5G+6% 2|3G4G,5F+6% 2|3F2F,3G
148,695.70.53148,53616011% 2|5D4D,5D+9% 2|3H4H,5G+8% 2|5D4D,3D
148,197.60.63148,294−9613% 1|2D1)1F+10% 2|5D4D,3F+9% 1|2D1)3F
147,769.00.44147,826−5722% 1|2D1)1F+17% 1|2D1)3F+9% 2|3D4D,5P
145,708.70.64145,58012819% 2|3G4G,5H+18% 2|3F4F,5G+9% 2|5D4D,3F
144,601 15% 2|5D4D,3F+7% 2|3P4P,5P+6% 2|3F4F,5G
143,412.00.42143,3664619% 2|3G4G,5H+8% 2|3F4F,5F+8% 2|5D6D,5F
142,620.60.42142,771−15018% 2|3F4F,5D+17% 2|3D4D,5D+14% 2|5D4D,3D
141,028.30.43141,194−16612% 2|5D4D,3D+10% 2|5D6D,5P+8% 2|5D6D,5D
139,048.10.71139,115−6718% 1|2D1)3F+11% 1|2D1)1F+7% 2|5D6D,7F
138,607.70.35138,746−1388% 2|3D4D,5F+7% 2|5D6D,5P+6% 1|2F3)1F
137,458.10.42137,510−5219% 2|3F4F,5G+15% 2|5D6D,7F+8% 1|2D1)3F
135,434.8 135,4161955% 1|2F3)1F+12% 1|2F3)3D+5% 1|2G3)3G
134,798 15% 2|3H4H,5H+11% 2|3G4G,5G+8% 2|5D4D,5P
134,002 45% 2|5D6D,7P+10% 2|5D6D,7D+3% 1|2D3)3F
132,909.10.24132,8753414% 1|2P3)3D+13% 1|2D3)3F+12% 1|2D3)1F
132,330 11% 2|5D6D,7P+9% 2|5D4D,5F+9% 2|5D6D,7D
129,079.0 129,0621634% 1|2H3)3G+19% 1|2G3)1F+10% 1|2F3)3F
127,236.50.42127,330−9314% 2|5D4D,5D+9% 2|5D4D,5P+5% 2|5D4D,3D
125,699.3 125,6504916% 1|2F3)3D+16% 1|2F3)3F+11% 1|2F3)1F
122,430.1 122,4042623% 1|2F3)3F+11% 2|5D6D,7F+10% 1|2D3)3D
121,741.90.26121,6499329% 2|5D6D,7F+6% 1|2D3)1F+5% 2|5D6D,7P
121,054.8 121,046814% 1|2G3)1F+13% 1|2G3)3F+ 11% 1|2H3)3G
119,568.8 119,598−2914% 1|2P3)3D+11% 1|4P3)5D+8% 1|4F3)5G
118,315.5 118,2486842% 1|2G3)3G+14% 1|2F3)3D+8% 1|2G3)3F
114,964.3 114,971−727% 1|2G3)3F+11% 1|2H3)3G+8% 1|2F3)3G
114,808.10.23114,7614755% 2|5D6D,7D+15% 2|5D6D,7F+10% 2|5D6D,7P
111,973.8 111,9551927% 1|4P3)3D+23% 1|2F3)3G+10% 1|4F3)3G
110,867.0 110,941−7412% 1|2F3)3D+12% 1|4F3)3G+9% 1|2G3)1F
110,652.3 110,730−7833% 1|4P3)5P+10% 1|4P3)3D+9% 1|4F3)3F
108,804.8 108,804018% 1|4P3)5D+17% 1|4F3)5G+9% 1|4F3)3G
107,420.1 107,3972420% 1|4F3)3F+13% 1|2D3)3D+11% 1|2F3)3G
105,326.6 105,352−2618% 1|2G3)3G+13% 1|4F3)3D+10% 1|4F3)3F
103,517.5 103,525−719% 1|4F3)3G+19% 1|2P3)3D+14% 1|4P3)5P
102,813.0 102,7793438% 1|4F3)5D+13% 1|4P3)3D+12% 1|4F3)5F
98,104.7 98,109−455% 1|4F3)3D+9% 1|2G3)3F+6% 1|4F3)5G
97,138.5 97,0984126% 1|4P3)5D+20% 1|4F3)5G+10% 1|4F3)3F
90,415.7 90,3764028% 1|4F3)5G+16% 1|4F3)5F+6% 1|4P3)5D
88,294.4 88,310−1637% 1|4F3)5D+28% 1|4F3)5F+10% 1|4P3)5D
J = 4
167,746.70.45167,63311417% 2|1G2G,3F+8% 2|3F4F,5D+7% 2|3G4G,3G
166,986 12% 2|3D4D,3F+11% 2|3D2D,3F+10% 2|3F4F,5F
166,932 15% 2|3G2G,3G+10% 4|4F3)5D+10% 2|3G4G,3H
165,871 13% 2|3H2H,1G+13% 2|3F2F,1G10% 2|3F4F,5D
164,825 22% 4|4F3)5D+11% 4|4F3)3F+ 10% 4|4F3)5F
163,402 10% 2|1G2G,3F+7% 2|3D4D,3F+6% 2|3F4F,5D
162,763 20% 2|3D4D,5D+15% 2|3D4D,5F+5% 2|3F4F,3G
161,913.10.71161,991−7811% 2|1G2G,3G+9% 2|3G4G,5G+6% 2|1G2G,3H
160,974.80.52161,023−4811% 2|3H4H,5H+7% 2|3F4F,3F+6% 2|3F4F,3F
160,693 15% 2|1G2G,3H+15% 2|1I2I,3H+12% 2|3F2F,1G
160,086 37% 2|5D4D,5F+10% 2|5D6D,5F+7% 2|3F2F,3G
159,688 11% 2|3D4D,5D+7% 2|3F4F,5D+7% 2|3F4F,5G
158,217 10% 2|3G4G,5F+9% 2|3G2G,1G+8% 2|3D4D,5F
157,777.40.43157,844−6613% 2|3F4F,5F+7% 2|3H2H,3G+6% 2|3G2G,3H
157,075 17% 2|1F2F,3G+14% 2|3F4F,5G+7% 2|1F2F,3F
154,694 11% 2|3F4F,5G+9% 2|3G2G,3H+9% 2|1I2I,3H
154,426.50.43154,517−9115% 2|3H4H,5G+9% 2|3D4D,5F+8% 2|3G2G,3G
152,172.30.43152,171114% 2|5D4D,3F+14% 2|3G4G,5F+8% 2|3H4H,5H
150,975 12% 2|5D6D,5F+12% 2|3P4P,5D+12% 2|5D4D,5D
150,844 14% 2|5D4D,5D+ 10% 2|3H4H,5I+7% 2|3F2F,3G
150,478.40.71150,36011814% 2|3F4F,5F+8% 2|3F4F,5F+8% 2|5D6D,5D
149,473.50.35149,26620814% 2|3H4H,5G+13% 2|3G4G,5G+8% 2|3H2H,1G
148,435.00.63148,17226321% 2|3F4F,5G+13% 2|3G4G,5G+7% 2|3F4F,5D
146,882.30.42146,893−1036% 1|2D1)3F+11% 2|3G4G,5H+7% 1|2D3)3F
145,904 14% 2|3G4G,5H+14% 1|2D1)3F+11% 2|3D4D,5F
145,624.80.44145,49812714% 2|3G4G,5F+11% 2|3H4H,5H+9% 2|3D4D,5F
141,701.00.72141,719−1820% 2|3H4H,5H+12% 2|5D6D,5F+12% 2|3H4H,5G
140,632.80.51140,5557913% 2|3H4H,5I+9% 2|3G4G,5G+7% 2|5D6D,5F
140,379 21% 2|5D4D,3F+12% 2|3F4F,5G+7% 2|5D6D,5F
138,421.00.42138,3784324% 2|5D6D,5D+12% 2|5D4D,5D+10% 2|3H4H,5I
134,284.70.61134,1968822% 2|3H4H,5I+10% 2|5D6D,5D+9% 2|3G4G,5H
132,149.240.178132,04710316% 1|2F3)3F+7% 2|5D4D,5D+6% 2|3G4G,5G
131,370.1 131,381−1129% 1|2F3)3F+6% 1|2G3)3G+6% 2|5D4D,3F
129,878 34% 2|5D6D,7P+30% 2|5D6D,7D+14% 2|5D6D,7F
128,317.2 128,3061141% 1|2H3)3H+18% 1|2H3)3G+6% 1|2G3)1G
127,226.40.43127,1031239% 2|5D4D,3F+9% 2|5D4D,5D+7% 2|5D6D,7D
125,228.1 125,2022740% 1|2F3)1G+23% 1|2F3)3G+8% 1|2H3)3H
123,222.7 123,1962741% 1|2H3)1G+29% 1|2G3)1G+10% 1|2F3)1G
122,004.8 122,025−2038% 1|2D3)3F+8% 1|2D1)3F+8% 1|4F3)5G
121,032.60.25120,93210036% 2|5D6D,7F+22% 2|5D6D,7P+8% 2|5D6D,5F
119,420.3 119,486−6620% 1|2H3)1G+12% 1|2F3)3G+11% 1|2F3)1G
117,094.5 117,124−2943% 1|2G3)3G+15% 1|2G3)3H+12% 1|2F3)3F
115,528.1 115,4933538% 1|2H3)3G+17% 1|2F3)3G+13% 1|2G3)3H
111,395.5 111,3266924% 1|2G3)3F+18% 1|2G3)1G+15% 1|2H3)3H
110,270.30.23110,338−6837% 2|5D6D,7D+19% 2|5D6D,7P+8% 2|5D6D,7F
108,036.9 108,084−4739% 1|4P3)5D+20% 1|4F3)3G+16% 1|4F3)5G
104,963.8 104,970−632% 1|2G3)3H+14% 1|4F3)3F+7% 1|2G3)1G
103,950.5 103,960−923% 1|4P3)5D+18% 1|2G3)3H+ 3% 1|4F3)5G
102,449.2 102,448225% 1|4F3)3G+21% 1|4F3)3F+16% 1|4F3)5F
100,462.2 100,475−1335% 1|4F3)5F+16% 1|2G3)3F+9% 1|4F3)5G
94,771.1 94,766530% 1|4F3)5D+28% 1|4F3)3F+13% 1|2G3)1G
90,510.5 90,4654643% 1|4F3)5G+19% 1|4F3)3G+17% 1|4F3)5F
79,260.8 79,312−5143% 1|4F3)5D+21% 1|4F3)5F+12% 1|2G3)3F
J = 5
173,199.40.62173,1128714% 2|3H4H,3G+12% 2|1I2I,3I+10% 2|1I2I,3H
172,717 16% 2|3F4F,3G+15% 2|3F4F,5F+9% 2|1F2F,3G
171,098 15% 2|3G2G,1H+13% 2|3G2G,3G+8% 2|3H4H,3H
170,491 15% 2|3G2G,1H+5% 2|3H2H,1H+5% 2|1G2G,3H
168,505 32% 2|1F2F,3G+24% 2|3F4F,5G+6% 2|1I2I,3I
168,044 45% 4|4F3)5F+16% 4|4F3)3G+8% 4|2G3)3G
166,948 11% 2|3G2G,3G+9% 2|3G2G,3H+7% 2|3F4F,3G
165,927 11% 2|3F2F,3G+10% 2|3G4G,3H+8% 2|3G4G,3G
164,341 13% 4|4F3)3G+9% 4|4F3)5F+8% 2|3G4G,3H
163,316 18% 4|4F3)3G+13% 2|3H2H,3G+11% 2|1I2I,3I
162,935.50.42162,949−1431% 2|1I2I,3H+14% 2|3H2H,1H+6% 2|3F4F,5F
161,508.00.43161,4971133% 2|3D4D,5F+7% 2|3H2H,1H+7% 2|1I2I,3H
159,974.20.71160,028−5415% 2|3F4F,5F+10% 2|1G2G,3G+7% 2|3H4H,3I
159,451.70.71159,509−5810% 2|3H4H,5H+8% 2|3G4G,5F+6% 2|3G4G,3G
158,982 16% 2|1I2I,3I+12% 2|3F4F,5G+11% 2|3H2H,3G
157,322.30.43157,2923115% 2|3D4D,5F+15% 2|3G2G,1H+9% 2|3H2H,1H
155,140 17% 2|3G2G,3H+11% 2|5D4D,5F+6% 2|3F4F,5G
153,797.00.52153,66513232% 2|5D4D,5F+7% 2|3F4F,3G+6% 2|3D4D,5F
153,186.90.43153,0969115% 2|3H4H,5G+10% 2|3H2H,3G+8% 2|1I2I,3I
151,482.80.61151,478422% 2|3F4F,5G+18% 2|3H4H,5H+8% 2|5D4D,5F
149,308 14% 2|3H2H,3I+12% 2|3F4F,5F+10% 2|3G4G,5F
146,994 29% 2|3G4G,5H+13% 2|3H4H,5H+9% 2|3H4H,5I
144,894.70.62144,974−8024% 2|3G4G,5G+13% 2|3H4H,5G+9% 2|3H2H,3I
144,126.90.52144,169−4218% 2|3H4H,5G+12% 2|3G4G,5F+10% 2|3H2H,3G
140,372.40.52140,3571531% 2|3H4H,5I+16% 2|3G4G,5F+6% 2|3G4G,5G
138,266.70.71138,316−4922% 2|5D6D,5F+21% 2|3H4H,5G+7% 2|3G4G,5F
134,343 32% 2|5D6D,7F+22% 2|5D6D,5F+12% 2|3G4G,5F
132,003.40.25131,9337114% 2|3G4G,5H+14% 2|3H4H,5I+11% 2|3G4G,5G
131,684.0 131,727−4337% 1|2F3)3G+8% 1|2G3)1H+6% 1|2H3)3H
129,523.3 129,559−3634% 1|2H3)1H+19% 1|2F3)3G+16% 1|2H3)3H
126,256.00.61126,264−835% 2|5D6D,7D+30% 2|5D6D,7F+12% 2|5D6D,5F
120,721.9 120,6715037% 1|2H3)1H+29% 1|2H3)3H+16% 1|2H3)3G
118,078.2 118,070941% 1|2G3)1H+27% 1|2G3)3H+15% 1|2F3)3G
115,106.1 115,0644237% 1|2H3)3I+21% 1|2G3)3H+19% 1|2H3)3H
112,273.2 112,319−4644% 1|2G3)3G+20% 1|2H3)3I+6% 2|5D6D,7D
111,983 48% 2|5D6D,7D+18% 2|5D6D,7F+7% 2|5D6D,5F
106,212.1 106,251−3968% 1|2H3)3G+10% 1|2H3)3H+7% 1|2H3)1H
102,752.2 102,806−5467% 1|4F3)5G+18% 1|4F3)3G+5% 1|4F3)5F
99,330.4 99,3042624% 1|2G3)3H+22% 1|2H3)3I+14% 1|2G3)3G
92,592.2 92,584850% 1|4F3)5F+28% 1|4F3)3G+6% 1|2G3)1H
81,371.7 81,3423033% 1|4F3)5F+29% 1|4F3)3G+21% 1|4F3)5G
J = 6
170,395.10.71170,3771848% 2|1I2I,3I+26% 2|3H4H,3H+6% 2|1I2I,3K
169,114.60.71169,124−922% 2|3H4H,3I+17% 2|3G2G,3H+15% 2|3H2H,3I
168,230 79% 4|4F3)5G+18% 4|2G3)3H+1% 4|2H3)3I
164,785 21% 2|3H2H,1I+17% 2|3G4G,3H+9% 2|1I2I,3I
162,273.00.71162,1987517% 2|1I2I,3H+13% 2|3H2H,3H+10% 2|1G2G,3H
160,469.90.62160,3917928% 2|3F4F,5G+18% 2|3H4H,3I+13% 2|3H2H,1I
157,398.10.43157,504−10628% 2|1I2I,3H+22% 2|3G4G,5H+13% 2|1I2I,3K
156,284.80.53156,348−6333% 2|1I2I,3K+16% 2|3H2H,3I+10% 2|3H2H,1I
154,452.90.52154,23022319% 2|3H4H,5G+18% 2|1I2I,3I+12% 2|1I2I,3H
150,650 39% 2|3H4H,5H+13% 2|1I2I,3K+13% 2|3G4G,5H
149,363 24% 2|3H4H,5I+14% 2|3G4G,5G+13% 2|3H2H,1I
145,991.70.81146,034−4219% 2|3G4G,5G+13% 2|3F4F,5G+11% 2|1G2G,3H
142,218 19% 2|1I2I,3K+15% 2|3H2H,3I+12% 2|3G4G,5G
137,416.00.71137,647−23149% 2|3H4H,5G+14% 2|3G4G,5G+9% 2|3G4G,5H
134,378.70.61134,3493026% 2|3H4H,5H+24% 2|3H4H,5I+13% 2|3H4H,5G
126,331.9 126,357−2534% 1|2H3)3I+ 33% 1|2H3)1I+26% 1|2G3)3H
124,783 84% 2|5D6D,7F+8% 2|3F4F,5G+5% 2|3F4F,5G
119,120.9 119,159−3878% 1|2H3)3H+11% 1|2H3)1I+7% 1|2H3)3I
110,820.4 110,832−1254% 1|2G3)3H+20% 1|2H3)1I+15% 1|4F3)5G
104,831.9 104,8151748% 1|2H3)3I+32% 1|2H3)1I+17% 1|2H3)3H
93,150.2 93,150181% 1|4F3)5G+16% 1|2G3)3H+1% 1|2H3)3I
J = 7
171,031.10.81171,106−7546% 2|3H2H,3I+24% 2|1I2I,3I+13% 2|1I2I,1K
168,108 41% 2|1I2I,3I+19% 2|1I2I,3K+11% 2|3H4H,3I
160,979.40.61161,011−3235% 2|3H4H,3I+29% 2|3G4G,5H+17% 2|3H4H,5I
156,885.00.61156,885−050% 2|1I2I,3K+20% 2|1I2I,3I+13% 2|3H4H,5I
149,971.00.51150,015−4449% 2|3H4H,5H+15% 2|3H4H,5I+14% 2|1I2I,3K
148,862 54% 2|3G4G,5H+19% 2|3H4H,5I+10% 2|3H4H,3I
137,395 36% 2|3H4H,5I+34% 2|3H4H,5H+13% 2|3H4H,3I
116,060.0 116,056498% 1|2H3)3I+1% 2|3H4H,3I+0% 2|3H2H,3I
a Uncertainty of new or changed energy level. Blanks correspond to previously known levels [1]. Their uncertainties were estimated [1] as better than 0.8 cm−1. b Number of lines used to identify new or changed energy level; blank corresponds to previously [1] known level. c Difference between the observed and calculated energy level. d LS-composition of the level. The number preceding the “|” symbol has the following meaning: 1 stands for 5d76p, 2 stands for 5d66s6p, and 4 stands for 5d77p.
Table 3. Fitted and calculated parameter values (cm−1) in the 5d76p + 5d66s6p + 5d56s26p + 5d77p + 5d75f system of Pt III.
Table 3. Fitted and calculated parameter values (cm−1) in the 5d76p + 5d66s6p + 5d56s26p + 5d77p + 5d75f system of Pt III.
Parameter Name aFitted ValueError bMCDF cFitted/MCDFParameter
Status d
5d76p
Eav116,97651117,340.00.99691
O26481197755.30.836r1
O2′3933375295.20.743r2
Ea69(9) 0
Eb25(15) 0
T1−0.2(0.6) 0
T20.6(0.5) 0
ζ5d4895.9124619.71.05981
Ac41.6(7.3)45.70.91r3
A36.9 7.60.91r3
A48.2 9.10.91r3
A510.7 11.80.91r3
A617.7 19.40.91r3
A1−6.4 −7.00.91r3
A25.3 5.80.91r3
A0−5.7 −6.30.91r3
C122723025770.881r4
C220182624970.808r5
C310152513500.752r6
S1204(8) 1
S2−87(13) 1
ζ6p8235.3217205.51.14291
Sd.Lp−97.4(6.2)−132.60.73r7
Sp.Ld−18.5 −25.20.73r7
Z2(pp)−47.8 −65.00.73r7
Z2(dd)28.5 38.90.73r7
Z1(pp)151.7 206.50.73r7
Z1(dd)−16.9 −23.10.73r7
Z3(pp)44.2 60.20.73r7
Z3(dd)−12.4 −16.90.73r7
SS02−13.6 −18.50.73r7
SS20−2.1 −3.00.73r7
t16−6.7(11) 0
t172.8(9) 0
t181.6(9) 0
t19−2.9(11) 0
t20−41.9(24) 0
t21−6.2(8) 0
t220.9(12) 0
t23−12.7(10) 0
t24−17.7(11) 0
t250.5(9) 0
t26−50.0(18) 0
t270.4(10) 0
t2831.7(14) 0
t2919.0(10) 0
t3063.1(13) 0
t31−16.9(10) 0
t324.7(10) 0
t3312.3(12) 0
t341.5(10) 0
t3518.7(12) 0
5d66s6p
Eav166,36139168,1230.99051
O265742679640.8251
O2′37568354180.6931
Ea5328680.7681
Eb240241.0000
ζ5d51732348881.0581
T10.21 1
T23.61.1 1
Ac551945.71.20r8
A38.6 7.11.20r8
A414.8 12.31.20r8
A517.4 14.41.20r8
A622.3 18.51.20r8
A1−6.1 −5.11.20r8
A29.3 7.81.20r8
A0−4.5 −3.71.20r8
Cds29993836260.8271
Amso(ds)8716691.2981
Ass−120−1210
C125453527900.9121
C219372826180.7491
C312232713950.8861
S1111192040.5571
S2−3834−800.4871
ζ6p90178484501.0671
Sd.Lp−11311−1380.821r9
Sp.Ld−20.2 −24.60.821r9
Z2(pp)−48.4 −58.90.821r9
Z2(dd)41.6 50.60.821r9
Z1(pp)174.3 211.80.821r9
Z1(dd)−12.9 −15.80.821r9
Z3(pp)54.2 65.90.821r9
Z3(dd)−11.9 −14.40.821r9
Csp94518312,8400.7361
Amso(sp)−732202−7440.9851
R2(dd;ds)12−22,716450−26,0350.8721
R2(dp;sp)12−19,009605−21,4690.8851
R1(dp;ps)12−16,699434−19,6200.8511
5d56s26p
Eav236,401 236,40110
O26824 81660.836r1
O2′4113 55380.743r2
ζ(5d)5449 51411.0600
C12642 29960.881r4
C22219 27460.808r5
C31074 14280.752r6
ζ6p11,210 98421.140
R2(dd;ss)1319,692 23,1670.850
R2(dd;ds)23−22,181 −26,0960.850
R2(dp;sp)23−18,835 −22,1590.850
R1(dp;ps)23−17,138 −201,620.850
5d77p
Eav194,872 194,87210
O26584 78760.836r1
O2′3984 53650.743r2
ζ5d5734 54101.0600
C1733 8320.881r4
C2466 5770.808r5
C3214 2850.752r6
ζ7p2651 23161.140
5d75f
Eav204,702 204,70210
O26584 78810.836r1
O2′3988 53680.743r2
ζ5d5405 50981.0600
C1594 6990.850
C2−22 −260.850
C3476 5600.850
C4373 4390.850
C5647 7620.850
ζ5f10 1010
R2(dp;dp)147738 91040.850
R1(dp;pd)143981 46840.850
R3(dp;pd)143462 40730.850
R2(dp;df)15−9561 −11,2480.850
R4(dp;df)15−4276 −50300.850
R1(dp;fd)15−4375 −51470.850
R3(dp;fd)15−2974 −34990.850
R2(sp;dp)24−5877 −69150.850
R1(sp;pd)24−5709 −67170.850
R2(sp;df)259791 11,5190.850
R3(sp;fd)255946 69950.850
R2(dp;df)45−1408 −16570.850
R4(dp;df)45−1474 −17340.850
R1(dp;fd)45−1971 −23190.850
R3(dp;fd)45−1410 −16590.850
a Trailing digits xy in the R-integral labels denote interaction between configurations x and y, where 1 stands for 5d76p, 2 stands for 5d66s6p, 3 stands for 5d56s26p, 4 stands for 5d77p, and 5 stands for 5d75f. b Errors in parentheses refer to the values obtained from the fitting of only 5d76p levels (see the text). c Ab initio value (cm−1) of the parameter. It was obtained from the calculations using the multiconfiguration Dirak–Fock (MCDF) code GRASP92 [21]. The average energies and the values of the R-integrals for configuration interactions were obtained from the calculations using the Cowan code [11,12]. d Parameter status: 0—parameter is fixed; 1—parameter is varied; r1, r2—parameter is linked at the MCDF ratio to O2, O2′, respectively, in the 5d76p configuration; r3—parameter is linked at the MCDF ratio to Ac; r4–r6—parameter is linked at the MCDF ratio to C1–C3, respectively, in the 5d76p configuration; r7 — parameter is linked at the MCDF ratio to Sd.Lp; r8—parameter is linked at the MCDF ratio to Ac in the 5d66s6p configuration; r9—parameter is linked at the MCDF ratio to Sd.Lp in the 5d66s6p configuration.
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