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Article

Negative Capacitance Analysis of Multi-Quantum-Well Light-Emitting Diodes

1
Tianjin Key Laboratory of Optoelectronic Detection Technology and System, School of Electronics and Information Engineering, Tiangong University, Tianjin 300387, China
2
Chip R&D Department, Sanan Optoelectronics Co., Ltd., Tianjin 300392, China
3
Department of Electronic and Electrical Engineering, University of Bath, Bath BA2 7AY, UK
*
Author to whom correspondence should be addressed.
Electronics 2025, 14(3), 413; https://doi.org/10.3390/electronics14030413
Submission received: 16 December 2024 / Revised: 18 January 2025 / Accepted: 19 January 2025 / Published: 21 January 2025
(This article belongs to the Section Optoelectronics)

Abstract

:
To explain the negative capacitance (NC) characteristic of multi-quantum-well (MQW) LEDs, we calculated the continuity equation for a 10-period AlGaInP/GaInP multi-quantum-well (MQW) LED with a mesa size of 90 × 150 μm and build an MQW LED capacitor model. The carrier concentrations and capacitance–voltage characteristics across every quantum well region were analyzed by accounting for carrier spontaneous, Auger, and SRH recombination. In our model, a dynamic carrier lifetime iteration method with an iterative error of less than 1 × 10−14 ns was used to decouple carrier lifetime and electric field variables in the carrier continuity equation, providing a new way to enhance the accuracy of MQW continuous equations. Based on the calculated carrier concentration and lifetime of MQWs, we derived a multilayer epitaxial material LED capacitance equivalent circuit. The theoretical model characterizes the negative capacitance phenomenon at 1.75 V, which is consistent with the actual test results of the sample. Our theoretical analysis indicates that the negative capacitance mainly comes from the carrier recombination in the MQW region. Under low-frequency AC bias conditions, the negative capacitance phenomenon becomes more obvious. This work provides a useful reference for analyzing the capacitance and bandwidth characteristics of LEDs in the fields of display dimming and visible-light communication.

1. Introduction

The quantum confinement effect of multi-quantum-well (MQW) light-emitting diodes (LEDs) is used to achieve highly efficient light emission and fast response speed [1]. In recent years, the application of LEDs in visible-light communication (VLC) [2] and display backlights [3] has gained significant attention. As the core light-emission devices of VLC or display systems, LEDs need a wide bandwidth and high response speed in VLC modulation and PWM (Pulse-Width Modulation) display backlight dimming.
The characteristics of MQW LEDs, such as recombination rate and luminous efficiency, are influenced by carrier recombination within the quantum wells. In particular, the carrier lifetime, jointly determined by radiative recombination, Auger recombination, and surface recombination, plays a pivotal role in the spontaneous emission rate, carrier distribution, high-frequency response, and other aspects of LED device performance.
In related research, numerous studies have explored the impacts of factors such as the quantum well period, device size, material defects, buffer layer materials, and temperature on device performance [4,5,6,7,8,9,10]. However, these factors invariably manifest as the generation and recombination of carriers within the device (i.e., carrier lifetime). Therefore, the work presented in this paper simplifies the variables by focusing on three recombination mechanisms of carriers within the device. Based on this, a more detailed carrier transport model is established to better characterize the carrier distribution in various regions of the MQW LEDs.
In this work, we fabricated an AlGaInP/GaInP MQWs LED sample and built its carrier continuity equation model. With the AC small-signal analysis, the MQW capacitance at forward bias voltages was calculated. We checked the carrier distribution across different quantum well regions, and we assessed the impact of carriers’ recombination mechanisms on negative capacitance.

2. Experiments

An AlGaInP/GaInP MQW LED was fabricated to research the NC phenomenon. The MQW LED material was grown on a GaAs substrate by Metal–Organic Chemical Vapor Deposition (MOCVD) technology. The source materials were trimethylindium (TMI), trimethylgallium (TMG), methylaluminium (TMA), PH3, and AsH3. Dimethylzinc (DMZ) served as the doping source for the p-type layer, while biscyclopentadienylmagnesium (Cp2Mg) and SiH4 served as the doping sources for the n-type layer. The growth temperature was 650~680 °C and the total pressure was 9.3 × 103 Pa. The V/III ratio was ~550, and the growth rate was ~2 µm/h. The LED’s layers, from bottom to top, were as follows: a 0.3 μm undoped GaAs buffer layer, a 3 μm 2 × 1018 cm−3 n-doped AlGaInP layer, 10-period undoped AlGaInP (6 nm)/GaInP (4 nm) MQWs, a 0.4 μm 4 × 1017 cm−3 p-doped AlGaInP layer, and a 0.1 μm 1 × 1020 cm−3 p+-doped GaP contact layer. The epitaxial growth schematic of the MQW LED is shown in Figure 1a. In order to achieve better light output, the grown epitaxy layers were transferred onto a transparent sapphire substrate by the wafer bonding process, and the LED mesa size was set as 90 μm × 150 μm.
After LED mesa and N-layer ICP etching, a 600 nm SiO2 passivation layer was used to cover the P and N layers. For electrical contacts, a 200 nm thick Au/Ge/Ni alloy layer was deposited as the N-type electrode through electron beam evaporation, paralleled by a similarly dimensioned Au/Zn alloy layer serving as the P-type electrode. For the convenience of C-V testing, the P-pad and N-pad were evaporated on the surface of the P and N electrodes to achieve the connection between the chip and substrate. The microscope photo of this MQW LED is shown in Figure 1b.
Then, the LED chip was assembled on a test PCB circuit through flip-chip soldering. The capacitance–voltage (C-V) characteristics of the MQW LED were measured by a Keithley 4200A parameter analyzer connected to a probe station.

3. Theoretical Analysis

Based on the above LED device structure, we built a calculation model to research the MQW LED’s carrier distribution and capacitance characteristics. First, we used the carrier continuity equation and MQW boundary conditions to calculate the carrier concentration and total junction current. Then, the LED junction capacitance was verified with the AC small-signal analysis.
The MQW LED model’s structure is shown in Figure 2, including P, N, and AlGaInP doping layers and AlGaInP/GaInP MQWs. The 10-period MQWs are composed of 11 AlGaInP barrier layers sandwiched with 10 GaInP well layers. The left boundary of the MQWs is set as the x-axis 0 point, and the width of the MQWs is w d ; x1~x21 represent the boundary position of every AlGaInP/GaInP layer, and the MQWs’ last AlGaInP boundary x 21 = w d .
The steady-state continuous equations of electrons in the P-doped region and the MQWs are shown in Equations (1) and (2), respectively [11]:
D n 2 n x 2 n τ n = 0
D n i 2 n x 2 μ n i E i n x n τ n i = 0
In the LED’s P-doped region, the diffusion of non-equilibrium minority carrier electrons satisfies Equation (1), where n is the electron concentration, D n is the electron diffusion coefficient in the P-doped region, and τ n is the common lifetime of electrons. In different regions of the MQWs, there are electric fields E i (i = 1, 2⋯21) caused by bias voltage, and the electrons and holes in the MQWs exhibit diffusion, drift, and recombination. In Equation (2), D n i and μ n i are the MQWs’ material electron diffusion coefficient and electron mobility, respectively, and τ n i represents the different recombination lifetimes of the MQWs’ 21 layers.
The analysis of holes’ concentration is similar to that for electrons; holes are injected from the P-doped region, and the steady-state continuity equations of holes in the corresponding N-doped region and MQW region are shown in Equations (3) and (4), respectively:
D p 2 p x 2 p τ p = 0
D p i 2 p x 2 μ p i E i p x p τ p i = 0
where p is the hole concentration, while D p and τ p are the hole diffusion coefficient and lifetime in the N-doped region, respectively. The D p i ,   μ p i , a n d τ p i (i = 1, 2⋯21) are the hole diffusion coefficient, mobility, and recombination lifetime of the MQW layers, respectively.
To solve the second-order linear differential equations with constant coefficients as shown in Equations (1)–(4), given that the equations have one positive and one negative characteristic root, and considering the diffusion of carrier concentration along the positive direction of the x-axis [12], we selected the general solution containing the positive characteristic root as the practical solution for the carrier concentration of these equations.
The carrier recombination lifetime τ in Equations (1)–(4) is shown in Equation (5), combining the spontaneous radiation lifetime ( τ s p o n ), non-equilibrium carrier indirect recombination lifetime ( τ S R H ), and Auger recombination lifetime ( τ A u g e r ) [11].
1 τ = 1 τ s p o n + 1 τ S R H + 1 τ A u g e r
Under forward voltage bias, electrons are injected from the highly doped N region into the undoped quantum well region. Based on the large carrier injection [11], we set the electron intensity at the N region and MQW boundary ( x = x 21 = w d ) as follows:
n 21 x = w d = n i n t r i n s i c e x p q v η K T
where n i n t r i n s i c is the intrinsic electron concentration of AlGaInP, and η is an injection factor.
The electrons in the MQWs are driven by bias voltage v and built-in potential caused by the quantum well conduction band difference E c . We set the electron intensity n i (i = 1, 2⋯20) at the boundary of each region in the MQWs as shown in Equation (7):
n i x = x i = n i + 1 x = x i · exp E c η K T ,   i = 20 ,   18 ,   2 n i + 1 x = x i · exp E c η K T ,   i = 19 ,   17 ,   1
Then, the electrons diffuse into the P-type doping region through the MQWs, and the boundary conditions for x = 0 are given by Equation (8):
n p x = 0 = n 1 x = 0 e x p x τ n D n 1
For the holes injected from the highly doped P region into the MQWs, the boundary conditions at the interface between the P region and the MQWs are closely related to the electrons’ behavior and distribution in the adjacent regions. The built-in potential of the MQWs is caused by the quantum well valence band difference E v . With the carrier lifetime and boundary conditions described by Equations (5)–(8), we can determine the carrier concentrations by the solution of Equations (1)–(4).
Then, the LED total junction current J can be derived by the carrier concentration at the boundary of the PN region ( x = 0 and x = w d ) and MQWs.
J = j d + j r
where j d is the diffusion region current of the n and p regions, and j r is the sum of the carrier recombination currents within the MQWs.
j d = A q D n d n p d x | x = 0 + A q D p d p n d x | x = w d
j r = j = 1 21 A q τ n j a b n j x d x + j = 1 21 A q τ p j a b p j x d x
where A is the area of the active region, while a and b represent the upper and lower boundaries of each region, respectively.
Under the AC working condition, the DC bias voltage ( v 0 ) is mixed with AC small signals ( v 1 e j ω t ) , and the input voltage in Equation (6) changes to v = v 0 + v 1 e j ω t . The total current J in Equation (9) has a similar AC form, i.e., J = j 0 + j 1 e j ω t , where j 0 and j 1 are the DC and AC amplitude, respectively. The calculation parameters in this work include an AlGaInP barrier layer width of 6 nm, GaInP well layer width of 4 nm, total quantum well width w d of 106 nm, device area A of 1.35 × 10−8 m2, AC small-signal frequency ω of 1 kHz, AC voltage v 1 of 10 mV, and injection factor η of 1.5; the other material parameters of AlGaInP and GaInP were chosen from reference [13], and the main parameters used in the model are shown in Table 1.

4. Results and Discussion

In conventional numerical calculation software, the carrier lifetime is typically set as a constant based on test results or empirical values, but constant carrier lifetime values cannot accurately characterize the carrier recombination in quantum wells under different operating conditions.
In this paper, we used a dynamic carrier lifetime iterative calculation method to calculate the carrier concentration and lifetime under different bias voltages, thereby addressing the problem that, in the carrier equation, lifetime and input voltage cannot simultaneously be treated as variables. The flowchart illustrating this calculation method is shown in Figure 3.
The initial lifetime value in Equations (1)–(4) was assumed to be infinite, and there was no carrier recombination. We input the parameters (including the initial lifetime and material parameters) into the carrier continuity equation and solved Equations (1)–(4) for the carrier concentration. The results were substituted into Equation (5) to calculate the carrier lifetime. Then, we recalculated the carrier concentration distribution in Equations (1)–(4) based on the new carrier lifetime obtained from the last calculation. The iterations continued until the variation in the calculated carrier lifetime met the iteration error. In the iterative model, the iteration error was set such that the difference in carrier recombination lifetime at each voltage point among the last three iteration results did not exceed 1 × 10−14 ns. Upon meeting this condition, the final lifetime value of Equations (1)–(4) was chosen as the carrier lifetime from the last iteration.
Taking the first quantum well region (x1~x21) as an example, the calculated electron lifetimes are shown in Figure 4a, where the lifetime τ decreases with the DC bias voltage rather than maintaining a constant value. The carrier’s spontaneous lifetime τ s p o n is lowest from 1.49 V to 1.63 V, and the LED has much higher light-emission efficiency within this voltage range. Beyond a bias voltage of 1.63 V, the Auger lifetime τ A u g e r is minimal, and the carrier’s Auger recombination dominates the carrier recombination process, which will cause a decline in the LED’s light-emission efficiency.
Using these carrier lifetime results, we calculated the quantum well carrier concentration shown in Figure 4b. For the carrier concentration line, there is a decline in carrier concentration after 1.6 V bias voltage due to the short lifetime and high carrier recombination.
After adding an AC small signal to the DC bias voltage, according to Equations (9)–(11), it can be inferred that the AC component j 1 of the MQW LED is composed of the AC component of the diffusion current in the P and N doping regions and the AC component of the recombination current in the MQWs, and the capacitance comes from the imaginary part of the AC components of these two currents. Therefore, the total capacitance can be divided into P,N diffusion capacitance and MQW recombination capacitance, which is equivalent to the parallel connection of sub-capacitors in each region, as shown in Figure 5a.
The calculated capacitances of C t o t a l , C d i f f u s i o n , and C r e c o m b i n a t i o n are shown in Figure 5b. Due to the carrier recombination, the C r e c o m b i n a t i o n in the MQWs rapidly decreases after 1.6 V, resulting in the occurrence of negative capacitance. C r e c o m b i n a t i o n and C d i f f u s i o n form the total value of LED capacitance C t o t a l .
Comparing the capacitance in Figure 4d with the calculated carrier concentration in Figure 4b, the voltage position where the NC appears remains the same as the carrier concentration decreases. It can be theoretically verified that the NC of the LED mainly comes from the recombination of carriers in the MQWs, which conforms to the situation of C = d Q / d V < 0 .
Unlike the equivalent electrical model of an LED [14] as shown in Figure 5b, this paper establishes a capacitance model based on the generation and recombination of carriers within the quantum well from a microscopic perspective. The neglect of series resistance r s and shunt conductance G p is the reason for the calculated current being less than the measured current, as shown in Figure 4c. The relationship between current and voltage drop under the equivalent electrical model of an LED is expressed as follows:
I = I s e x p β ( V r s I ) n 1 + G p ( V r s I )
where β = q / k T , I s is the saturation current, and n is the ideality factor.
Further analysis of the capacitance within the MQWs (Figure 6a–d) shows the calculation results of the capacitance and carrier concentration of the MQWs’ barriers and wells under a DC bias voltage of 1.85 V. Due to the spontaneous recombination, the carrier recombination intensity in the GaInP well is higher than that in the AlGaInP barrier. So, there is a negative capacitance in the well region, while the capacitance is positive in the barrier regions, and the higher carrier concentrations correspond to a higher absolute value of NC. This can mainly be attributed to the short carrier lifetime and higher electron–hole recombination rate in the high-carrier-concentration region.
The relationship between the capacitance and frequency of LEDs under AC operating conditions was also analyzed. Figure 7a shows the calculated capacitance–voltage curves at different frequencies, which indicate that the NC characteristics of the LED weaken under high-frequency conditions. This weakening can primarily be attributed to the influence of frequency on the effective carrier lifetime.
Taking the electron lifetime as an example, under AC conditions, the electron concentration changes to n · e j ω t , and the steady-state Equation (2) changes into a transient-state Equation (13):
D n i 2 n x 2 μ n i E i n x n τ n i = n t
where n / t = n · j w . Merging n / t and n / τ n i , we can determine the electron equivalent lifetime ( τ n i * ) in the MQWs.
τ n i * = τ n i 1 + j w τ n i
In the low-frequency range, where ω τ n 1 ,   τ n i * τ n i , as the forward bias voltage increases, the carrier lifetime τ n i decreases, indicating enhanced carrier recombination and a decrease in carrier concentration from high, and C = d Q / d V < 0 , resulting in the NC phenomenon. In the high-frequency operating range, where ω τ n 1 and τ n * 1 / j ω , the voltage barely affects the variation in τ n * , resulting in a reduced impact of voltage on the capacitance C = d Q / d V . This leads to a flat trend in the voltage–capacitance curve and a weakening of the NC characteristics under high-frequency operating conditions.
In this paper, the capacitance of the LED used in the calculation model was also tested using the Keithley 4200A (Tektronix, Tiangong University, Tianjin, China). The measured apparent capacitance (Figure 7b) exhibited a similar phenomenon of NC reduction under high-frequency operation. However, the calculated ideal capacitance value was smaller than the apparent capacitance value due to the influence of parasitic series resistance and parallel conductance [14].

5. Conclusions

In this study, we first grew a 10-period AlGaInP/GaInP MQW LED material structure using MOCVD technology. This was then processed into individual LEDs with a mesa size of 90 × 150 μm. Then, we established a theoretical analysis model for this MQW LED and determined the carrier distribution, carrier lifetime, and capacitance of the MQW LED under forward bias voltage. Next, we established a theoretical analysis model based on the MQW LED samples, from which we derived the carrier concentrations, lifetimes, and capacitance values in the well and barrier regions within the MQW LED under forward biases ranging from 0 to 1.8 V. Therefore, the MQWs’ dynamic carrier lifetime continuous equations in this paper are more accurate than fixed lifetime calculation results.
The modeling and analysis results presented in this paper demonstrate that the carrier lifetime undergoes dynamic changes under the influence of differing carrier concentrations in both the potential well region and the potential barrier region, as well as due to the application of an external forward bias. Based on the calculations of the dynamic carrier lifetime, the distribution of carrier concentrations in the multiple quantum wells exhibits an initial increase followed by a decrease. This phenomenon is caused by efficient radiative carrier recombination, and the results of the carrier concentration analysis are close to the actual carrier variations observed in the device.
Our dynamic carrier lifetime iteration method provides a decoupling scheme for carrier lifetime and input voltage, which solves the problem that carrier lifetime and electric field cannot simultaneously be variables in the carrier continuity equation. Currently, widely used device modeling software can only set the carrier recombination lifetime within the device to a fixed value and is unable to accurately characterize the carrier recombination lifetime in various regions of multi-period quantum well devices in detail. Through this model, we solved for the carrier lifetimes in various regions within the MQWs, with an iterative error of less than 1 × 10−14 ns. The solution method of this model is applicable to micro- and nano-sized LEDs with MQWs of any period.
Based on the AlGaInP/GaInP MQW LED carrier concentration calculation, our model exhibits the NC phenomenon starting at 1.75 V, which is consistent with the test results obtained from actual samples, and we can confirm that the NC phenomenon of MQW LEDs is closely related to the recombination in the MQW region. Our capacitors’ equivalent circuits showed that the LED’s total capacitance can be divided into P,N diffusion capacitance and MQW recombination capacitance. Each quantum well’s electron capacitance and hole capacitance contribute to the LED’s negative capacitance.
We measured the capacitance characteristic curves of the samples within the frequency range of DC to 10 MHz, and we selected representative frequencies of 300 kHz, 1 MHz, and 10 MHz for detailed analysis. The measured and calculation results also showed a weakening of the NC characteristics under high-frequency AC operation conditions of the LED. Our analysis indicates that this is because the equivalent lifetime of carriers is a frequency-related variable and remains constant as the voltage changes.
In summary, the carrier distribution and capacitance of MQW LEDs are closely related to the carrier lifetime, which is modulated by the operating voltage and frequency of the LED device. This work can provide a reference for the device modeling of LEDs in display and communication applications. For instance, in higher-frequency LED optical communication applications, negative capacitance characteristics can affect the high-frequency response of the devices. Based on the device negative capacitance analysis method mentioned in this article, precise control of the device’s capacitance can be achieved to match the frequency response of specific-frequency communication systems.

Author Contributions

Conceptualization, H.T. and H.L.; Methodology, H.T. and H.L.; Software, Y.M.; Validation, P.Z.; Formal analysis, L.H.; Resources, D.Z. and S.G.; Data curation, X.F. and Y.M.; Writing—original draft, Y.X.; Writing—review & editing, P.S., H.T. and H.L.; Project administration, P.S., H.T. and H.L.; Funding acquisition, H.T. and H.L. All authors have read and agreed to the published version of the manuscript.

Funding

This research was funded by the Tianjin Municipal Science and Technology Bureau, Grant 23YDTPJC00370; in part by the China Scholarship Council (CSC), Grant 201809345004; and in part by the Tianjin Key Laboratory of Optoelectronic Detection Technology and System under Grant 2023LOTDS003.

Data Availability Statement

The original contributions presented in this study are included in the article. Further inquiries can be directed to the corresponding author.

Acknowledgments

The authors would like to thank the Analytical and Testing Center of Tiangong University and Sanan Optoelectronics Co., Ltd. for technical support.

Conflicts of Interest

Hongwei Liu reports that financial support was provided by the Tianjin Municipal Science and Technology Bureau, China Scholarship Council (CSC), and Tianjin Key Laboratory of Optoelectronic Detection Technology and System. Authors Dongyan Zhang and Shoushuai Gao were employed by the company Chip R&D Department, Sanan Optoelectronics Co., Ltd. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest.

References

  1. Jiang, Y.; Li, Y.; Li, Y.; Deng, Z.; Lu, T.; Ma, Z.; Zuo, P.; Dai, L.; Wang, L.; Jia, H.; et al. Realization of high-luminous-efficiency InGaN light-emitting diodes in the “green gap” range. Sci. Rep. 2015, 5, 10883. [Google Scholar] [CrossRef] [PubMed]
  2. Tao, Z.; Guan, X.; Wei, Z.; Liu, N.; Liu, Y.; Xu, Y. Realization of real-time OFDM-based visible light communication using an InGaN/GaN multiquantum-wells LED. Microw. Opt. Technol. Lett. 2020, 62, 1459–1465. [Google Scholar] [CrossRef]
  3. Chang, K.P.; Lien, P.C.; Yen, C.C.; Chen, P.W.; Horng, R.H.; Wuu, D.S. High Performance AlGaInP-Based Micro-LED Displays With Novel Pixel Structures. IEEE Photonics Technol. Lett. 2021, 33, 1375–1378. [Google Scholar] [CrossRef]
  4. Zhu, S.; Lin, S.; Li, J.; Yu, Z.; Cao, H.; Yang, C.; Li, J.; Zhao, L. Influence of quantum confined Stark effect and carrier localization effect on modulation bandwidth for GaN-based LEDs. Appl. Phys. Lett. 2017, 111, 171105. [Google Scholar] [CrossRef]
  5. Wang, C.D.; Zhu, C.Y.; Zhang, G.Y.; Shen, J.; Li, L. Accurate electrical characterization of forward AC behavior of real semiconductor diode: Giant negative capacitance and nonlinear interfacial layer. IEEE Trans. Electron Devices 2003, 50, 1145–1148. [Google Scholar] [CrossRef]
  6. Zhu, C.Y.; Feng, L.F.; Wang, C.D.; Cong, H.X.; Zhang, G.Y.; Yang, Z.J.; Chen, Z.Z. Negative capacitance in light-emitting devices. Solid-State Electron. 2009, 53, 324–328. [Google Scholar] [CrossRef]
  7. Wang, Y.; Chen, J.; Xu, J.; Li, X. Modeling of frequency-dependent negative differential capacitance in InGaAs/InP photodiode. Infrared Phys. Technol. 2018, 89, 41–45. [Google Scholar] [CrossRef]
  8. Bourim, E.M.; Han, J.I. Size Effect on Negative Capacitance at Forward Bias in InGaN/GaN Multiple Quantum Well-Based Blue LED. Electron. Mater. Lett. 2016, 12, 67–75. [Google Scholar] [CrossRef]
  9. Benzarti, Z.; Sekrafi, T.; Bougrioua, Z.; Khalfallah, A.; El Jani, B. Effect of SiN Treatment on Optical Properties of InxGa1−xN/GaN MQW Blue LEDs. Electron. Mater. 2017, 46, 4312–4320. [Google Scholar] [CrossRef]
  10. Mock, J.; Kallergi, M.; Groß, E.; Golibrzuch, M.; Rieger, B.; Becherer, M. Revealing the Negative Capacitance Effect in Silicon Quantum Dot Light-Emitting Diodes via Temperature-Dependent Capacitance-Voltage Characterization. IEEE Photonics J. 2022, 14, 8237309. [Google Scholar] [CrossRef]
  11. Sze, S.M.; Li, Y.; Ng, K.K. Physics of Semiconductor Devices, 3rd ed.; Xi’an Jiaotong University Press: Xi’an, China, 2021; pp. 47–48. [Google Scholar]
  12. Liu, E.; Zhu, B.; Luo, J. The Physics of Semiconductors, 7th ed.; Publishing House of Electronics Industry: Beijing, China, 2017; pp. 149–150. [Google Scholar]
  13. Sun, Y.; Perna, A.; Bermel, P. Comparing front-and rear-junction GaInP photovoltaic devices through detailed numerical and analytical modeling. IEEE J. Photovolt. 2019, 9, 437–445. [Google Scholar] [CrossRef]
  14. Aubry, V.; Meyer, F. Schottky diodes with high series resistance: Limitations of forward I-V methods. J. Appl. Phys. 1994, 76, 7973–7984. [Google Scholar] [CrossRef]
Figure 1. (a) Schematic of the MQW LED epitaxial growth structure. (b) Microscope photo of the LED.
Figure 1. (a) Schematic of the MQW LED epitaxial growth structure. (b) Microscope photo of the LED.
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Figure 2. (a) The schematic of the MQW LED calculation model. (b) The detail of the MQW structure.
Figure 2. (a) The schematic of the MQW LED calculation model. (b) The detail of the MQW structure.
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Figure 3. Flowchart for solving the continuous equations of the carrier calculation model.
Figure 3. Flowchart for solving the continuous equations of the carrier calculation model.
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Figure 4. (a) Electron lifetime of different recombination mechanisms in the first quantum well region (x1~x2). (b) Calculated carrier concentration in the first quantum well region. (c) The measured IV characteristic curve of the MQW LED, and the calculated result. (d) Capacitance values under different bias voltages.
Figure 4. (a) Electron lifetime of different recombination mechanisms in the first quantum well region (x1~x2). (b) Calculated carrier concentration in the first quantum well region. (c) The measured IV characteristic curve of the MQW LED, and the calculated result. (d) Capacitance values under different bias voltages.
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Figure 5. (a) Equivalent capacitance circuit of MQW LED. (b) Equivalent electrical model of LED.
Figure 5. (a) Equivalent capacitance circuit of MQW LED. (b) Equivalent electrical model of LED.
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Figure 6. (a) Capacitance and (b) carrier concentration in every barrier region. (c) Capacitance and (d) carrier concentration in every well region.
Figure 6. (a) Capacitance and (b) carrier concentration in every barrier region. (c) Capacitance and (d) carrier concentration in every well region.
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Figure 7. MQW LED’s capacitance at different frequencies: (a) Calculation results. (b) Measured apparent capacitance.
Figure 7. MQW LED’s capacitance at different frequencies: (a) Calculation results. (b) Measured apparent capacitance.
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Table 1. Main parameters of the calculation model.
Table 1. Main parameters of the calculation model.
SymbolAlGaInPGaInPDescription
Eg2.26 ev1.97 evBandwidth
n ¯ 4.44.5Refractivity
Δ0.125 ev0.105 evSpin–orbit splitting
mn*0.105 m0 ev0.11 m0 evElectron effective mass
mp*0.51 m0 ev0.48 m0 evHole effective mass
Dn2.59 × 10−4 m2/s1.295 × 10−4 m2/sElectron diffusion coefficient
Dp2.59 × 10−5 m2/s7.77 × 10−5 m2/sHole diffusion coefficient
μn1 × 10−2 m2/vs5 × 10−2 m2/vsElectron mobility
μp1 × 10−3 m2/vs3 × 10−3 m2/vsHole mobility
Nt7.3 × 1020 m−31 × 1019 m−3Recombination center concentration
rn3.52 × 10−14 m3/s6.67 × 10−11 m3/sElectron capture coefficient
rp1.64 × 10−14 m3/s3.12 × 10−11 m3/sHole capture coefficient
ce3 × 10−42 m6/s3 × 10−42 m6/sAuger recombination coefficient
ε/ε011.811.88Relative dielectric constant
* Inertial mass.
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MDPI and ACS Style

Xiao, Y.; Feng, X.; Meng, Y.; He, L.; Zhang, P.; Zhang, D.; Gao, S.; Shields, P.; Tian, H.; Liu, H. Negative Capacitance Analysis of Multi-Quantum-Well Light-Emitting Diodes. Electronics 2025, 14, 413. https://doi.org/10.3390/electronics14030413

AMA Style

Xiao Y, Feng X, Meng Y, He L, Zhang P, Zhang D, Gao S, Shields P, Tian H, Liu H. Negative Capacitance Analysis of Multi-Quantum-Well Light-Emitting Diodes. Electronics. 2025; 14(3):413. https://doi.org/10.3390/electronics14030413

Chicago/Turabian Style

Xiao, Yang, Xiaoyu Feng, Yuan Meng, Longzhen He, Pengzhe Zhang, Dongyan Zhang, Shoushuai Gao, Philip Shields, Haitao Tian, and Hongwei Liu. 2025. "Negative Capacitance Analysis of Multi-Quantum-Well Light-Emitting Diodes" Electronics 14, no. 3: 413. https://doi.org/10.3390/electronics14030413

APA Style

Xiao, Y., Feng, X., Meng, Y., He, L., Zhang, P., Zhang, D., Gao, S., Shields, P., Tian, H., & Liu, H. (2025). Negative Capacitance Analysis of Multi-Quantum-Well Light-Emitting Diodes. Electronics, 14(3), 413. https://doi.org/10.3390/electronics14030413

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