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Coatings 2019, 9(3), 187; https://doi.org/10.3390/coatings9030187

Aluminum Coated Micro Glass Spheres to Increase the Infrared Reflectance

1
Ceramic Materials Engineering-Keylab Glastechnology, University of Bayreuth, 95440 Bayreuth, Germany
2
Deggendorf Institute of Technology, TAZ Spiegelau, 94518 Spiegelau, Germany
*
Author to whom correspondence should be addressed.
Received: 4 February 2019 / Revised: 1 March 2019 / Accepted: 8 March 2019 / Published: 12 March 2019
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Abstract

The reflective properties of micro glass spheres (MGS) such as Solid Micro Glass Spheres (SMGS, “glass beads”) and Micro Hollow Glass Spheres (MHGS, “glass bubbles”) are utilized in various applications, for example, as retro-reflector for traffic road stripe paints or facade paints. The reflection behavior of the spheres can be further adapted by coating the surfaces of the spheres, e.g., by titanium dioxide or a metallic coating. Such coated spheres can be employed as, e.g., mid infrared (MIR)-reflective additives in wall paints to increase the thermal comfort in rooms. As a result, the demand of heating energy can be reduced. In this paper, the increase of the MIR-reflectance by applying an aluminum coating on MGS is discussed. Aluminum coatings are normally produced via the well-known Physical Vapor Deposition (PVD) or Chemical Vapor Deposition (CVD). In our work, the Liquid Phase Deposition (LPD) method, as a new, non-vacuum method for aluminum coating on spherical spheres, is investigated as an alternative, scalable, and simple coating process. The LPD-coating is characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and reflection measurements. The results are compared to a reference PVD-coating. It is shown that both sphere types, SMGS and MHGS, can be homogeneously coated with metallic aluminum using the LPD method but the surface morphology plays an important role concerning the reflection properties. With the SMGS, a smooth surface morphology and a reflectance increase to a value of 30% can be obtained. Due to a structured surface morphology, a reflection of only 5% could be achieved with the MHGS. However, post-treatments showed that a further increase is possible. View Full-Text
Keywords: micro hollow glass spheres (MHGS); solid micro glass spheres (SMGS); liquid phase deposition (LPD); aluminum coating micro hollow glass spheres (MHGS); solid micro glass spheres (SMGS); liquid phase deposition (LPD); aluminum coating
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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
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Schwinger, L.; Lehmann, S.; Zielbauer, L.; Scharfe, B.; Gerdes, T. Aluminum Coated Micro Glass Spheres to Increase the Infrared Reflectance. Coatings 2019, 9, 187.

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