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Enhanced Efficiency of Dye-Sensitized Solar Counter Electrodes Consisting of Two-Dimensional Nanostructural Molybdenum Disulfide Nanosheets Supported Pt Nanoparticles

1
Department of Engineering and System Science, National Tsing Hua University, Hsinchu 30013, Taiwan
2
Department of Chemical Engineering, Tatung University, Taipei 104, Taiwan
3
Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 24301, Taiwan
*
Author to whom correspondence should be addressed.
Academic Editors: Federico Cesano and Domenica Scarano
Coatings 2017, 7(10), 167; https://doi.org/10.3390/coatings7100167
Received: 5 September 2017 / Revised: 7 October 2017 / Accepted: 10 October 2017 / Published: 13 October 2017
This paper reports architecturally designed nanocomposites synthesized by hybridizing the two-dimensional (2D) nanostructure of molybdenum disulfide (MoS2) nanosheet (NS)-supported Pt nanoparticles (PtNPs) as counter electrodes (CEs) for dye-sensitized solar cells (DSSCs). MoS2 NSs were prepared using the hydrothermal method; PtNPs were subsequently reduced on the MoS2 NSs via the water–ethylene method to form PtNPs/MoS2 NSs hybrids. The nanostructures and chemical states of the PtNPs/MoS2 NSs hybrids were characterized by high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy. Detailed electrochemical characterizations by electrochemical impedance spectroscopy, cyclic voltammetry, and Tafel-polarization measurement demonstrated that the PtNPs/MoS2 NSs exhibited excellent electrocatalytic activities, afforded a higher charge transfer rate, a decreased charge transfer resistance, and an improved exchange current density. The PtNPs/MoS2 NSs hybrids not only provided the exposed layers of 2D MoS2 NSs with a great deal of catalytically active sites, but also offered PtNPs anchored on the MoS2 NSs enhanced I3 reduction. Accordingly, the DSSCs that incorporated PtNPs/MoS2 NSs CE exhibited an outstanding photovoltaic conversion efficiency (PCE) of 7.52%, which was 8.7% higher than that of a device with conventional thermally-deposited platinum CE (PCE = 6.92%). View Full-Text
Keywords: MoS2 nanosheets; Pt nanoparticles; counter electrode; dye-sensitized solar cells MoS2 nanosheets; Pt nanoparticles; counter electrode; dye-sensitized solar cells
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MDPI and ACS Style

Cheng, C.-K.; Lin, J.-Y.; Huang, K.-C.; Yeh, T.-K.; Hsieh, C.-K. Enhanced Efficiency of Dye-Sensitized Solar Counter Electrodes Consisting of Two-Dimensional Nanostructural Molybdenum Disulfide Nanosheets Supported Pt Nanoparticles. Coatings 2017, 7, 167.

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