Study on Microstructure and Properties of Mechanically Deposited Zn-Sn Coating
Abstract
:1. Introduction
2. Experimental Materials and Methods
2.1. Coating Specimen Preparation Process
2.2. Characterization and Analysis of Coating
3. Results and Discussion
3.1. Analysis of the Microstructure of Zn-Sn Coating
3.2. Corrosion Resistance of Zn-Sn Coating
3.2.1. Electrochemical Polarization Analysis
3.2.2. Electrochemical Impedance Spectroscopy
3.2.3. Neutral Salt Spray Test Analysis
3.3. Passivation Process of Zn-Sn Coating
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
- Chung, P.P.; Esfahani, M.; Wang, J.; Cook, P.; Durandet, Y. Effects of heat treatment on microstructure evolution and corrosion performance of mechanically plated zinc coatings. Surf. Coat. Technol. 2019, 377, 124916. [Google Scholar] [CrossRef]
- Esfahani, M.; Zhang, J.; Wong, Y.C.; Durandet, Y.; Wang, J. Electrodeposition of nanocrystalline zinc-tin alloy from aqueous electrolyte containing gluconate in the presence of polyethylene glycol and hexadecyltrimethylammonium bromide. J. Electroanal. Chem. 2018, 813, 143–151. [Google Scholar] [CrossRef]
- Oladijo, O.P.; Mathabatha, M.H.; Popoola, A.P.I.; Ntsoane, T.P. Characterization and corrosion behaviour of plasma sprayed Zn-Sn alloy coating on mild stee. Surf. Coat. Technol. 2018, 352, 654–661. [Google Scholar] [CrossRef]
- Kim, K.Y.; Yang, B.Y. An electrochemical study on Zn−Sn-alloy-coated steel sheets deposited by vacuum evaporation. Part I. Surf. Coat. Technol. 1994, 64, 99–110. [Google Scholar] [CrossRef]
- Fatoba, O.S.; Popoola, A.P.I.; Fedotova, T.; Pityana, S.L. Electrochemical studies on the corrosion behaviour of laser alloyed Zn-Sn coatings on UNS G10150 steel in 1M HCl solution. Silicon 2015, 7, 357–369. [Google Scholar] [CrossRef]
- Chung, P.P.; Wang, J.; Durandet, Y. Deposition processes and properties of coatings on steel fasteners—A review. Friction 2019, 7, 389–416. [Google Scholar] [CrossRef] [Green Version]
- Davis, E.A. Mechanically Plated Fasteners in Bimetallic Assemblies; SAE Technical Paper No. 780253; SAE International: Warrendale, PA, USA, 1978. [Google Scholar] [CrossRef]
- Mason, R.; Neidbalson, M.; Klingenberg, M.; Khabra, P.; Handsy, C. Update on alternatives for cadmium coatings on military electrical connectors. Met. Finish. 2010, 108, 12–20. [Google Scholar] [CrossRef]
- AS3566.2-2002. 2002-2-28; Self-Drilling Screws for the Building and Construction Industries Part 2: Corrosion Resistance Requirements: Australia. Council of Standards Australia: Sydney, Australia, 2002.
- Sziráki, L.; Cziraki, A.; Vértesy, Z.; Kiss, L.; Ivanova, V.; Raichevski, G.; Vitkova, S.; Marinova, S.; Marinova, T. Zn and Zn–Sn alloy coatings with and without chromate layers. Part I: Corrosion resistance and structural analysis. J. Appl. Electrochem. 1999, 29, 927–937. [Google Scholar] [CrossRef]
- Alesary, H.F.; Ismail, H.K.; Shiltagh, N.M.; Alattar, R.A. Effects of additives on the electrodeposition of Zn-Sn alloys from choline chloride/ethylene glycol-based deep eutectic solvent. J. Electroanal. Chem. 2020, 874, 114–517. [Google Scholar] [CrossRef]
- Zhang, J.; Gu, C.; Tu, J. Potentiodynamical deposition and corrosion behavior of thin Zn-Sn coatings with layered structure and varied composition from deep eutectic solvent. Surf. Coat. Technol. 2017, 320, 640–647. [Google Scholar] [CrossRef]
- Salhi, Y.; Cherrouf, S.; Cherkaoui, M.; Abdelouahdi, K. Electrodeposition of nanostructured Sn–Zn coatings. Appl. Surf. Sci. 2016, 367, 64–69. [Google Scholar] [CrossRef]
- Pereira, J.C.; dos Santos, L.P.M.; Alcanfor, A.A.C.; de Sant’Ana, H.B.; Feitosa, F.X.; Campos, O.S.; Correia, A.N.; Casciano, P.N.S.; de Lima-Neto, P. Effects of electrodeposition parameters on corrosion resistance of Zn-Sn coatings on carbon steel obtained from eutectic mixture based on choline chloride and ethylene glycol. J. Alloys Compd. 2021, 886, 161159. [Google Scholar] [CrossRef]
- Hamid, Z.A.; Abd El Rehim, S.S.; Abou Shama, A.; Ebrahim, M. Improvement the corrosion resistance for the galvanized steel by adding Sn. J. Surf. Eng. Mater. Adv.Technol. 2016, 6, 58. [Google Scholar] [CrossRef] [Green Version]
- Benidir, S.; Madani, A.; Baka, O.; Kherfi, A.; Delhalle, J.; Mekhalif, Z. Influence of applied potential on tin content in electrodeposition of Zn–Sn alloy coatings and its effect on corrosion protection. Inorg. Nano-Met. Chem. 2022, 52, 899–909. [Google Scholar] [CrossRef]
- Lee, S.; Park, J.; Oh, J.-W.; Kang, Y.-C. Effect of compositional ratio of Sn in SnZn thin films on morphological and chemical properties. Phys. B Condens. Matter 2020, 591, 412257. [Google Scholar] [CrossRef]
- Hayatdavoudi, H.; Rahsepar, M. A mechanistic study of the enhanced cathodic protection performance of graphene-reinforced zinc rich nanocomposite coating for corrosion protection of carbon steel substrate. J. Alloys Compd. 2017, 727, 1148–1156. [Google Scholar] [CrossRef]
- Liu, B.; Mu, X.; Yang, Y.; Hao, L.; Ding, X.; Dong, J.; Zhang, Z.; Hou, H.; Ke, W. Effect of tin addition on corrosion behavior of a low-alloy steel in simulated costal-industrial atmosphere. J. Mater. Sci. Technol. 2019, 35, 1228–1239. [Google Scholar] [CrossRef]
- Mouanga, M.; Berçot, P. Comparison of corrosion behaviour of zinc in NaCl and in NaOH solutions; Part II: Electrochemical analyses. Corros. Sci. 2010, 52, 3993–4000. [Google Scholar] [CrossRef]
- Wang, S.; He, M.; Zhao, X. Bonding mechanism of mechanically deposited coating/substrate. Phys. Procedia 2013, 50, 315–321. [Google Scholar] [CrossRef]
- Xie, Y.; Chen, M.; Xie, D.; Zhong, L.; Zhang, X. A fast, low temperature zinc phosphate coating on steel accelerated by graphene oxide. Corros. Sci. 2017, 128, 1–8. [Google Scholar] [CrossRef]
- Peng, Y.; Lai, C.; Zhang, M.; Liu, X.; Yin, Y.; Li, Y.; Wu, Z. Zn–Sn alloy anode with repressible dendrite grown and meliorative corrosion resistance for Zn-air battery. J. Power Sources 2022, 526, 231173. [Google Scholar] [CrossRef]
- Fashu, S.; Gu, C.D.; Zhang, J.L.; Bai, W.Q.; Wang, X.L.; Tu, J.P. Electrodeposition and characterization of Zn–Sn alloy coatings from a deep eutectic solvent based on choline chloride for corrosion protection. Surf. Interface Anal. 2015, 47, 403–412. [Google Scholar] [CrossRef]
- Hosking, N.; Ström, M.; Shipway, P.; Rudd, C. Corrosion resistance of zinc–magnesium coated steel. Corros. Sci. 2007, 49, 3669–3695. [Google Scholar] [CrossRef]
- Mundhenk, N.; Huttenloch, P.; Bäßler, R.; Kohl, T.; Steger, H.; Zorn, R. Electrochemical study of the corrosion of different alloys exposed to deaerated 80 °C geothermal brines containing CO2. Corros. Sci. 2014, 84, 180–188. [Google Scholar] [CrossRef]
Sample | Ecorr/mV | Icorr/(µA·cm−2) | Rp/(Ω·cm2) |
---|---|---|---|
Zn | −1354 | 2.35 × 102 | 375 |
Zn-Sn | −1286 | 4.51 × 101 | 1493 |
Sample | Rs/ (Ω·cm2) | Rcoat/ (Ω·cm2) | Rct/ (Ω·cm2) | Qcoat/ (F∙cm−2) | Qdl/ (F∙cm−2) |
---|---|---|---|---|---|
Zn | 5.36 | 509.6 | 207 | 9.03 × 10−2 | 6.48 × 10−2 |
Zn-Sn | 4.39 | 1173 | 113.8 | 7.52 × 10−2 | 2.21 × 10−2 |
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Liu, P.; Wang, S.; Wang, C.; Zhao, X. Study on Microstructure and Properties of Mechanically Deposited Zn-Sn Coating. Coatings 2022, 12, 1919. https://doi.org/10.3390/coatings12121919
Liu P, Wang S, Wang C, Zhao X. Study on Microstructure and Properties of Mechanically Deposited Zn-Sn Coating. Coatings. 2022; 12(12):1919. https://doi.org/10.3390/coatings12121919
Chicago/Turabian StyleLiu, Peng, Shengmin Wang, Chengyu Wang, and Xiaojun Zhao. 2022. "Study on Microstructure and Properties of Mechanically Deposited Zn-Sn Coating" Coatings 12, no. 12: 1919. https://doi.org/10.3390/coatings12121919