Influence of Individual Ions on Silica Nanoparticles Interaction with Berea Sandstone Minerals
Abstract
:1. Introduction
2. Materials and Methods
2.1. Nanoparticle Slug Injection
2.2. Electric Double Layer Interaction
3. Results and Discussions
3.1. Nanoparticle and Tracer Profiles
3.2. Double Layer Interaction
3.3. NPs/Mineral Interaction and Possible Mechanism(s)
3.3.1. MgCl2 Brine
3.3.2. Na2SO4 Brine
3.3.3. NaCl Brine
4. Summary and Conclusions
- All the used single salt brines showed reduced mineral dissolution, however to different degrees. This is related to the degree of adsorption on the minerals, where the highest were about 82% in the cases of Mg and SO4 single brines, compared to about 34% in the case of Na single brine. It is demonstrated that specific ions rather than brine ionic strength/salinity are the major influencing factor on adsorption of silica NPs on Berea mineral surface.
- The possible mechanism for the influence of Mg2+ on the adsorption is due to renewing and increasing of the contacted surface area at the mineral surfaces by a possible exchange reaction between Ca2+ and Mg2+. The mechanism in the case of SO42− ions, is due to their adsorption on kaolinite and release of OH−, which is followed by neutralization of the resulted negative charge by participation of neighboring Al ions resulting in ring formation, as suggested in the literature. This may also be supported by the increasing trends of the pH and the zeta potentials of the cations/minerals which are more negative than that in the case of SO4 brine. Another possible supporting point is that in the case of SO4 brine, the double layer interaction is less repulsive than those of the other brines.
- Clay minerals have exchangeable cations so for the addition of sodium brine, an exchange between Na+ with H+ releases hydrogen ions. This process changes the surface charge distribution; hence affecting the adsorption of materials such as NPs. This is supported by that in the case of Na brine, the lowest adsorption of NPs (~34%) occurred. The two other observations that may support the exchange mechanism are the domination of the repulsive double layer (Figure 5) and that Na brine has the highest negative zeta potential, for NPs/Berea in presence of NaCl as stabilizing fluid.
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Ion | SSW (mol/L) | Na Brine (mol/L) | Mg Brine (mol/L) | SO4 Brine (mol/L) |
---|---|---|---|---|
HCO3− | 0.002 | 0 | 0 | 0 |
Cl− | 0.525 | 0.400068 | 0.089033 | 0 |
SO42− | 0.0240 | 0 | 0 | 0.096 |
Mg2+ | 0.045 | 0 | 0.178066 | 0 |
Ca2+ | 0.013 | 0 | 0 | 0 |
Na+ | 0.450 | 0.400068 | 0 | 0.048 |
K+ | 0.010 | 0 | 0 | 0 |
Ionic strength | 0.68 | 0.4 | 0.13 | 0.072 |
Name | Initial Saturating Fluid | Pre-flush Fluid | NP Slug | Post-Flush Fluid |
---|---|---|---|---|
BRT 1 | SSW | Mg Brine | 1 (g/L) NP in Mg Brine with 0.1 M LiCl tracer | Mg Brine |
OBRT 2 | SSW | SO4 Brine | 1 (g/L) NP in SO4 Brine with 0.1 M LiCl tracer | SO4 Brine |
BRT 3 | SSW | Na Brine | 1 (g/L) NP in Na Brine with 0.1 M LiCl tracer | Na Brine |
BRT 4 | SSW | SSW | 1 (g/L) NP in SSW with 0.1 M LiCl tracer | SSW |
Experiment | % Nanoparticles Retained in the Core |
---|---|
BRT1 SSW Slug | 81.7 |
BRT2 MG Slug | 81.3 |
BRT3 SO4 Slug | 68.2 |
BRT4 Na Slug | 33.9 |
Dispersing Fluid | Average Hydrodynamic Radius of the NPs (nm) |
---|---|
SSW | 28.2 |
Na Brine | 19.6 |
Mg Brine | 19.4 |
SO4 Brine | 19.5 |
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Hamouda, A.A.; Abhishek, R. Influence of Individual Ions on Silica Nanoparticles Interaction with Berea Sandstone Minerals. Nanomaterials 2019, 9, 1267. https://doi.org/10.3390/nano9091267
Hamouda AA, Abhishek R. Influence of Individual Ions on Silica Nanoparticles Interaction with Berea Sandstone Minerals. Nanomaterials. 2019; 9(9):1267. https://doi.org/10.3390/nano9091267
Chicago/Turabian StyleHamouda, Aly A., and Rockey Abhishek. 2019. "Influence of Individual Ions on Silica Nanoparticles Interaction with Berea Sandstone Minerals" Nanomaterials 9, no. 9: 1267. https://doi.org/10.3390/nano9091267