Enhanced Photocatalytic H2 Evolution over ZnIn2S4 Flower-Like Microspheres Doped with Black Phosphorus Quantum Dots
Abstract
:1. Introduction
2. Experimental Section
2.1. Preparation
2.1.1. Preparation of Hexagonal ZnIn2S4 Flower-Like Microspheres
2.1.2. Preparation of a Dispersion of BPQDs
2.1.3. Preparation of BPQD–ZIS Materials
2.2. Characterization
2.3. Photoelectrochemical Measurements
2.4. Photocatalytic H2 Evolution
3. Results and Discussion
3.1. Characterization of the Photocatalysts
3.2. Photocatalytic H2 Evolution Performance of the Photocatalysts
3.3. Mechanism behind the Enhanced Photocatalytic Performance of the BPQD–ZIS Hybrids
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
- Gür, T.M.; Bent, S.F.; Prinz, F.B. Nanostructuring Materials for Solar-to-Hydrogen Conversion. J. Phys. Chem. C 2014, 118, 21301–21315. [Google Scholar] [CrossRef]
- Kudo, A.; Miseki, Y. Heterogeneous photocatalyst materials for water splitting. Chem. Soc. Rev. 2009, 38, 253–278. [Google Scholar] [CrossRef] [PubMed]
- Lv, X.J.; Fu, W.F.; Chang, H.X.; Zhang, H.; Cheng, J.S.; Zhang, G.J.; Song, Y.; Hu, C.Y.; Li, J.H. Hydrogen evolution from water using semiconductor nanoparticle/graphene composite photocatalysts without noble metals. J. Mater. Chem. 2012, 22, 1539–1546. [Google Scholar] [CrossRef]
- Fujishima, A.; Honda, K. Electrochemical photolysis of water at a semiconductor electrode. Nature 1972, 238, 37–39. [Google Scholar] [CrossRef] [PubMed]
- Xie, Y.P.; Yu, Z.B.; Liu, G.; Ma, X.L.; Cheng, H.M. CdS–mesoporous ZnS core–shell particles for efficient and stable photocatalytic hydrogen evolution under visible light. Energy Environ. Sci. 2014, 7, 1895. [Google Scholar] [CrossRef]
- Zhang, L.; Li, S.; Liu, B.; Wang, D.; Xie, T. Highly Efficient CdS/WO3 Photocatalysts: Z-Scheme Photocatalytic Mechanism for Their Enhanced Photocatalytic H2 Evolution under Visible light. ACS Catal. 2014, 4, 3724–3729. [Google Scholar] [CrossRef]
- Zhang, J.; Qiao, S.Z.; Qi, L.; Yu, J. Fabrication of NiS modified CdS nanorod p-n junction photocatalysts with enhanced visible-light photocatalytic H2-production activity. Phys. Chem. Chem. Phy. 2013, 15, 12088–12094. [Google Scholar] [CrossRef]
- Li, K.; Su, F.Y.; Zhang, W.D. Modification of g-C3N4 nanosheets by carbon quantum dots for highly efficient photocatalytic generation of hydrogen. Appl. Surf. Sci. 2016, 375, 110–117. [Google Scholar] [CrossRef]
- Zhou, Y.; Zhang, L.; Huang, W.; Kong, Q.; Fan, X.; Wang, M.; Shi, J. N-doped graphitic carbon-incorporated g-C3N4 for remarkably enhanced photocatalytic H2 evolution under visible light. Carbon 2016, 99, 111–117. [Google Scholar] [CrossRef]
- Akple, M.S.; Low, J.; Wageh, S.; Al-Ghamdi, A.A.; Yu, J.; Zhang, J. Enhanced visible light photocatalytic H2-production of g-C3N4/WS2 composite heterostructures. Appl. Surf. Sci. 2015, 358, 196–203. [Google Scholar] [CrossRef]
- Liu, E.; Chen, J.; Ma, Y.; Feng, J.; Jia, J.; Fan, J.; Hu, X. Fabrication of 2D SnS2/g-C3N4 heterojunction with enhanced H2 evolution during photocatalytic water splitting. J. Colloid Interface Sci. 2018, 524, 313–324. [Google Scholar] [CrossRef] [PubMed]
- Chen, G.; Ding, N.; Li, F.; Fan, Y.; Luo, Y.; Li, D.; Meng, Q. Enhancement of photocatalytic H2 evolution on ZnIn2S4 loaded with in-situ photo-deposited MoS2 under visible light irradiation. Appl. Catal. B Environ. 2014, 160–161, 614–620. [Google Scholar] [CrossRef]
- Xu, H.; Jiang, Y.; Yang, X.; Li, F.; Li, A.; Liu, Y.; Zhang, J.; Zhou, Z.; Ni, L. Fabricating carbon quantum dots doped ZnIn2S4 nanoflower composites with broad spectrum and enhanced photocatalytic Tetracycline hydrochloride degradation. Mater. Res. Bull. 2018, 97, 158–168. [Google Scholar] [CrossRef]
- Chen, Y.; Tian, G.; Ren, Z.; Pan, K.; Shi, Y.; Wang, J.; Fu, H. Hierarchical core-shell carbon nanofiber@ZnIn2S4 composites for enhanced hydrogen evolution performance. ACS Appl. Mater. Interfaces 2014, 6, 13841–13849. [Google Scholar] [CrossRef] [PubMed]
- Wang, J.; Chen, Y.; Zhou, W.; Tian, G.; Xiao, Y.; Fu, H.; Fu, H. Cubic quantum dot/hexagonal microsphere ZnIn2S4 heterophase junctions for exceptional visible-light-driven photocatalytic H2 evolution. J. Mater. Chem. A 2017, 5, 8451–8460. [Google Scholar] [CrossRef]
- Chen, J.; Zhang, H.; Liu, P.; Li, Y.; Liu, X.; Li, G.; Wong, P.K.; An, T.; Zhao, H. Cross-linked ZnIn2S4/rGO composite photocatalyst for sunlight-driven photocatalytic degradation of 4-nitrophenol. Appl. Catal. B Environ. 2015, 168–169, 266–273. [Google Scholar] [CrossRef]
- Peng, S.; Li, L.; Wu, Y.; Jia, L.; Tian, L.; Srinivasan, M.; Ramakrishna, S.; Yan, Q.; Mhaisalkar, S.G. Size-and shape-controlled synthesis of ZnIn2S4 nanocrystals with high photocatalytic performance. CrystEngComm 2013, 15, 1922. [Google Scholar] [CrossRef]
- Tian, F.; Zhu, R.; Song, K.; Niu, M.; Ouyang, F.; Cao, G. The effects of hydrothermal temperature on the photocatalytic performance of ZnIn2S4 for hydrogen generation under visible light irradiation. Mater. Res. Bull. 2015, 70, 645–650. [Google Scholar] [CrossRef]
- Chen, Y.; Huang, R.; Chen, D.; Wang, Y.; Liu, W.; Li, X.; Li, Z. Exploring the different photocatalytic performance for dye degradations over hexagonal ZnIn2S4 microspheres and cubic ZnIn2S4 nanoparticles. ACS Appl. Mater. Interfaces 2012, 4, 2273–2279. [Google Scholar] [CrossRef]
- Tan, C.; Zhu, G.; Hojamberdiev, M.; Lokesh, K.S.; Luo, X.; Jin, L.; Zhou, J.; Liu, P. Adsorption and enhanced photocatalytic activity of the {0001} faceted Sm-doped ZnIn2S4 microspheres. J. Hazard. Mater. 2014, 278, 572–583. [Google Scholar] [CrossRef]
- Shen, S.; Li, Z.; Zhou, Z.; Guo, L. Enhanced Photocatalytic Hydrogen Evolution over Cu-Doped ZnIn2S4 under Visible Light Irradiation. J. Phys. Chem. C 2008, 112, 16148–16155. [Google Scholar] [CrossRef]
- Li, H.; Liu, R.; Liu, Y.; Huang, H.; Yu, H.; Ming, H.; Lian, S.; Lee, S.T.; Kang, Z. Carbon quantum dots/Cu2O composites with protruding nanostructures and their highly efficient (near) infrared photocatalytic behavior. J. Mater. Chem. 2012, 22, 17470. [Google Scholar] [CrossRef]
- Lin, B.; Li, H.; An, H.; Hao, W.; Wei, J.; Dai, Y.; Ma, C.; Yang, G. Preparation of 2D/2D g-C3N4 nanosheet@ZnIn2S4 nanoleaf heterojunctions with well-designed high-speed charge transfer nanochannels towards high-efficiency photocatalytic hydrogen evolution. Appl. Catal. B Environ. 2018, 220, 542–552. [Google Scholar] [CrossRef]
- Li, W.; Lin, Z.; Yang, G. A 2D self-assembled MoS2/ZnIn2S4 heterostructure for efficient photocatalytic hydrogen evolution. Nanoscale 2017, 9, 18290–18298. [Google Scholar] [CrossRef] [PubMed]
- Kale, S.B.; Kalubarme, R.S.; Mahadadalkar, M.A.; Jadhav, H.S.; Bhirud, A.P.; Ambekar, J.D.; Park, C.J.; Kale, B.B. Hierarchical 3D ZnIn2S4/graphene nano-heterostructures: in-situ fabrication with dual mimics in solar hydrogen production and anode for Lithium ion battery. Phys. Chem. Chem. Phys. 2017, 17, 31850–31861. [Google Scholar] [CrossRef] [PubMed]
- Ding, N.; Fan, Y.; Luo, Y.; Li, D.; Meng, Q. Enhancement of H2 evolution over new ZnIn2S4/RGO/MoS2 photocatalysts under visible light. APL Mater. 2015, 3, 104417. [Google Scholar] [CrossRef]
- Hao, C.; Yang, B.; Wen, F.; Xiang, J.; Li, L.; Wang, W.; Zeng, Z.; Xu, B.; Zhao, Z.; Liu, Z.; et al. Flexible All-Solid-State Supercapacitors based on Liquid-Exfoliated Black-Phosphorus Nanoflakes. Adv. Mater. 2016, 28, 3194–3201. [Google Scholar] [CrossRef]
- Batmunkh, M.; Bat-Erdene, M.; Shapter, J.G. Phosphorene and Phosphorene-Based Materials—Prospects for Future Applications. Adv. Mater. 2016, 28, 8586–8617. [Google Scholar] [CrossRef]
- Chen, W.; Ouyang, J.; Liu, H.; Chen, M.; Zeng, K.; Sheng, J.; Liu, Z.; Han, Y.; Wang, L.; Li, J.; et al. Black Phosphorus Nanosheet-Based Drug Delivery System for Synergistic Photodynamic/Photothermal/ Chemotherapy of Cancer. Adv. Mater. 2017, 29, 1603864. [Google Scholar] [CrossRef]
- Yang, Y.; Gao, J.; Zhang, Z.; Xiao, S.; Xie, H.H.; Sun, Z.B.; Wang, J.H.; Zhou, C.H.; Wang, Y.W.; Guo, X.Y.; et al. Black Phosphorus Based Photocathodes in Wideband Bifacial Dye-Sensitized Solar Cells. Adv. Mater. 2016, 28, 8937–8944. [Google Scholar] [CrossRef]
- Tao, W.; Zhu, X.; Yu, X.; Zeng, X.; Xiao, Q.; Zhang, X.; Ji, X.; Wang, X.; Shi, J.; Zhang, H.; et al. Black Phosphorus Nanosheets as a Robust Delivery Platform for Cancer Theranostics. Adv. Mater. 2017, 29, 1603276. [Google Scholar] [CrossRef] [PubMed]
- Carvalho, A.; Wang, M.; Zhu, X.; Rodin, A.S.; Su, H.; Castro Neto, A.H. Phosphorene: from theory to applications. Nat. Rev. Mater. 2016, 1, 1–16. [Google Scholar] [CrossRef]
- Zhu, X.; Zhang, T.; Sun, Z.; Chen, H.; Guan, J.; Chen, X.; Ji, H.; Du, P.; Yang, S. Black Phosphorus Revisited: A Missing Metal-Free Elemental Photocatalyst for Visible Light Hydrogen Evolution. Adv. Mater. 2017, 29, 1605776. [Google Scholar] [CrossRef] [PubMed]
- Lee, H.U.; Lee, S.C.; Won, J.; Son, B.C.; Choi, S.; Kim, Y.; Park, S.Y.; Kim, H.S.; Lee, Y.C.; Lee, J. Stable semiconductor black phosphorus (BP)@titanium dioxide (TiO2) hybrid photocatalysts. Sci. Rep. 2015, 5, 8691. [Google Scholar] [CrossRef] [PubMed]
- Zhu, M.; Zhai, C.; Fujitsuka, M.; Majima, T. Noble metal-free near-infrared-driven photocatalyst for hydrogen production based on 2D hybrid of black Phosphorus/WS2. Appl. Catal. B Environ. 2018, 221, 645–651. [Google Scholar] [CrossRef]
- Zhang, X.; Xie, H.; Liu, Z.; Tan, C.; Luo, Z.; Li, H.; Lin, J.; Sun, L.; Chen, W.; Xu, Z.; et al. Black phosphorus quantum dots. Angew. Chem. 2015, 54, 3653–3657. [Google Scholar] [CrossRef]
- Kong, L.; Ji, Y.; Dang, Z.; Yan, J.; Li, P.; Li, Y.; Liu, S.F. g-C3N4 Loading Black Phosphorus Quantum Dot for Efficient and Stable Photocatalytic H2 Generation under Visible Light. Adv. Funct. Mater. 2018, 28, 1800668. [Google Scholar] [CrossRef]
- Huang, Y.; Qiao, J.; He, K.; Bliznakov, S.; Sutter, E.; Chen, X.; Luo, D.; Meng, F.; Su, D.; Decker, J.; et al. Interaction of Black Phosphorus with Oxygen and Water. Chem. Mater. 2016, 28, 8330–8339. [Google Scholar] [CrossRef] [Green Version]
- Guan, Z.; Xu, Z.; Li, Q.; Wang, P.; Li, G.; Yang, J. AgIn5S8 nanoparticles anchored on 2D layered ZnIn2S4 to form 0D/2D heterojunction for enhanced visible-light photocatalytic hydrogen evolution. Appl. Catal. B Environ. 2018, 227, 512–518. [Google Scholar] [CrossRef]
- Zheng, Y.; Yu, Z.; Ou, H.; Asiri, A.M.; Chen, Y.; Wang, X. Black Phosphorus and Polymeric Carbon Nitride Heterostructure for Photoinduced Molecular Oxygen Activation. Adv. Funct. Mater. 2018, 28, 1705407. [Google Scholar] [CrossRef]
- Xu, Y.; Wang, W.; Ge, Y.; Guo, H.; Zhang, X.; Chen, S.; Deng, Y.; Lu, Z.; Zhang, H. Stabilization of Black Phosphorous Quantum Dots in PMMA Nanofiber Film and Broadband Nonlinear Optics and Ultrafast Photonics Application. Adv. Funct. Mater. 2017, 27, 1702437. [Google Scholar] [CrossRef]
- Wang, J.; Wang, D.; Zhang, X.; Zhao, C.; Zhang, M.; Zhang, Z.; Wang, J. An anti-symmetric dual (ASD) Z-scheme photocatalytic system: (ZnIn2S4/Er3+: Y3Al5O12@ZnTiO3/CaIn2S4) for organic pollutants degradation with simultaneous hydrogen evolution. Int. J. Hydrogen Energy 2019, 44, 6592–6607. [Google Scholar] [CrossRef]
- Wang, B.; Deng, Z.; Fu, X.; Li, Z. MoS2/CQDs obtained by photoreduction for assembly of a ternary MoS2/CQDs/ZnIn2S4 nanocomposite for efficient photocatalytic hydrogen evolution under visible light. J. Mater. Chem. A 2018, 6, 19735–19742. [Google Scholar] [CrossRef]
- Ding, Y.; Gao, Y.; Li, Z. Carbon quantum dots (CQDs) and Co(dmgH)2PyCl synergistically promote photocatalytic hydrogen evolution over hexagonal ZnIn2S4. Appl. Surf. Sci. 2018, 462, 255–262. [Google Scholar] [CrossRef]
- Wang, B.; Ding, Y.; Deng, Z.; Li, Z. Rational design of ternary NiS/CQDs/ZnIn2S4 nanocomposites as efficient noble-metal-free photocatalyst for hydrogen evolution under visible light. Chin. J. Catal. 2019, 40, 335–342. [Google Scholar] [CrossRef]
- Chen, Y.; Tian, G.; Zhou, W.; Xiao, Y.; Wang, J.; Zhang, X.; Fu, H. Enhanced photogenerated carrier separation in CdS quantum dot sensitized ZnFe2O4/ZnIn2S4 nanosheet stereoscopic films for exceptional visible light photocatalytic H2 evolution performance. Nanoscale 2017, 9, 5912–5921. [Google Scholar] [CrossRef] [PubMed]
- Ishikawa, A.; Takata, T.; Kondo, J.N.; Hara, M.; Kobayashi, H.; Domen, K. Oxysulfide Sm2Ti2S2O5 as a stable photocatalyst for water oxidation and reduction under visible light irradiation (lambda < or = 650 nm). J. Am. Chem. Soc. 2002, 124, 13547–13553. [Google Scholar]
Photocatalyst | Sacrificial Reagent | Rate of Hydrogen Evolution (μmol·h−1·g−1) | References |
---|---|---|---|
BPQD–ZnIn2S4 | 0.25 M Na2SO3/0.35 M Na2S | 3675.9 | Our work |
Carbon quantum dots (CQDs)/MoS2/ZnIn2S4 | 0.25 M Na2SO3/0.35 M Na2S | 3000 | [43] |
Co/CQDs/ZnIn2S4 | 0.1 M triethanolamine | 1757.5 | [44] |
NiS/CQDs/ZnIn2S4 | 10 vol.% triethanolamine | 568 | [45] |
CdS QDs/ZnIn2S4 | 0.25 M Na2SO3/0.35 M Na2S | 2145 | [46] |
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Pan, X.; Shang, C.; Chen, Z.; Jin, M.; Zhang, Y.; Zhang, Z.; Wang, X.; Zhou, G. Enhanced Photocatalytic H2 Evolution over ZnIn2S4 Flower-Like Microspheres Doped with Black Phosphorus Quantum Dots. Nanomaterials 2019, 9, 1266. https://doi.org/10.3390/nano9091266
Pan X, Shang C, Chen Z, Jin M, Zhang Y, Zhang Z, Wang X, Zhou G. Enhanced Photocatalytic H2 Evolution over ZnIn2S4 Flower-Like Microspheres Doped with Black Phosphorus Quantum Dots. Nanomaterials. 2019; 9(9):1266. https://doi.org/10.3390/nano9091266
Chicago/Turabian StylePan, Xiaoying, Chaoqun Shang, Zhihong Chen, Mingliang Jin, Yongguang Zhang, Zhang Zhang, Xin Wang, and Guofu Zhou. 2019. "Enhanced Photocatalytic H2 Evolution over ZnIn2S4 Flower-Like Microspheres Doped with Black Phosphorus Quantum Dots" Nanomaterials 9, no. 9: 1266. https://doi.org/10.3390/nano9091266