Robust Polymer Nanocomposite Membranes Incorporating Discrete TiO2 Nanotubes for Water Treatment
Abstract
:1. Introduction
2. Materials and Methods
2.1. Chemical and Reagents
2.2. Preparation of TiO2 NTs/PES Membranes
2.3. Measurements of Porosity and Pore Size
2.4. Pure Water Flux Measurement
2.5. Fouling Tests
2.6. Total Organic Carbon Estimation
2.7. Chemical Composition Test (FTIR)
2.8. X-ray Photoelectron Spectroscopy (XPS)
2.9. Surface Properties (Wettability and Surface Charge)
2.10. Membrane Morphology Study
2.11. Atomic Force Microscopy
3. Results
3.1. FTIR Measurement Results
3.2. XPS Results
3.3. Surface and Cross-Section Morphology
3.4. Atomic Force Microscopy (AFM)
3.5. Contact Angle Measurement Results
3.6. Membrane Surface Charge Results
3.7. Permeability of Membranes
3.8. Porosity and Mean Pore Radius of Membrane
3.9. Separation Performance of Membranes
3.10. Fouling Characteristics of Membranes
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Membranes | Surface Roughness (nm) | Contact Angle | Zeta Potential (mV) at pH 5 | Zeta Potential (mV) at pH 6 | Zeta Potential (mV) at pH 7 | Zeta Potential (mV) at pH 8 |
---|---|---|---|---|---|---|
Unmodified PES | 57.1 | 65.1 ± 2 ° | −24.2 ± 0.1 | −26.6 ± 0.7 | −27.5 ± 0.1 | −28.0 ± 0.9 |
Unmodified TiO2 NT membrane | – | 8.0 ± 2 ° | −8.3 ± 0.5 | −8.8 ± 0.4 | −9.2 ± 0.2 | −10.1 ± 0.8 |
PES with 0.25 wt% TiO2 NTs | 83.3 | 49.1 ± 1 ° | −25.2 ± 0.8 | −27.0 ± 0.6 | −27.8 ± 0.4 | −28.4 ± 0.5 |
PES with 0.5 wt% TiO2 NTs | 121 | 40.5 ± 2 ° | −26.4 ± 0.7 | −27.3 ± 0.4 | −28.6 ± 0.6 | −29.7 ± 0.8 |
PES with 1 wt% TiO2 NTs | 133 | 37.4 ± 1 ° | −28.2 ± 1 | −29.4 ± 0.4 | −31.5 ± 0.3 | −32.0 ± 0.6 |
Membrane | Mass of Dry Membrane (mg) | Mass of Wet Membrane (mg) |
---|---|---|
Unmodified PES | 14.6 ± 1 | 502.1 ± 2 |
PES with 0.25 wt% TiO2 NTs | 25.0 ± 2 | 557.5 ± 3 |
PES with 0.5 wt% TiO2 NTs | 27.2 ± 2 | 597.2 ± 1 |
PES with 1 wt% TiO2 NTs | 24.2 ± 2 | 639.2 ± 2 |
Permeate TOC (mg/L) | Permeate TC (mg/L) | Permeate IC (mg/L) | WLS Feed Water Rejection (%) | |
---|---|---|---|---|
Bare PES | 441.28 | 468.74 | 27.46 | 11.7 |
1 wt% TiO2/PES | 230.70 | 253.80 | 23.10 | 53.9 |
0.5 wt% TiO2/PES | 413.51 | 447.40 | 33.90 | 17.3 |
0.25 wt% TiO2/PES | 424.23 | 451.20 | 26.97 | 15.15 |
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Mahdi, N.; Kumar, P.; Goswami, A.; Perdicakis, B.; Shankar, K.; Sadrzadeh, M. Robust Polymer Nanocomposite Membranes Incorporating Discrete TiO2 Nanotubes for Water Treatment. Nanomaterials 2019, 9, 1186. https://doi.org/10.3390/nano9091186
Mahdi N, Kumar P, Goswami A, Perdicakis B, Shankar K, Sadrzadeh M. Robust Polymer Nanocomposite Membranes Incorporating Discrete TiO2 Nanotubes for Water Treatment. Nanomaterials. 2019; 9(9):1186. https://doi.org/10.3390/nano9091186
Chicago/Turabian StyleMahdi, Najia, Pawan Kumar, Ankur Goswami, Basil Perdicakis, Karthik Shankar, and Mohtada Sadrzadeh. 2019. "Robust Polymer Nanocomposite Membranes Incorporating Discrete TiO2 Nanotubes for Water Treatment" Nanomaterials 9, no. 9: 1186. https://doi.org/10.3390/nano9091186