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Improved Catalytic Performance of Au/α-Fe2O3-Like-Worm Catalyst for Low Temperature CO Oxidation

Key Laboratory of Advanced Energy Material Chemistry (MOE), TKL of Metal and Molecule Based Material Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, China
Author to whom correspondence should be addressed.
Nanomaterials 2019, 9(8), 1118;
Received: 27 June 2019 / Revised: 17 July 2019 / Accepted: 26 July 2019 / Published: 3 August 2019
PDF [5318 KB, uploaded 3 August 2019]


The gold catalysts supported on various morphologies of α-Fe2O3 in carbon monoxide (CO) oxidation reaction have been studied for many researchers. However, how to improve the catalytic activity and thermal stability for CO oxidation is still important. In this work, an unusual morphology of α-Fe2O3 was prepared by hydrothermal method and gold nanoparticles were supported using a deposition-precipitation method. Au/α-Fe2O3 catalyst exhibited great activity for CO oxidation. The crystal structure and microstructure images of α-Fe2O3 were carried out by X-ray diffraction (XRD) and scanning electron microscopy (SEM) and the size of gold nanoparticles was determined by transmission electron microscopy (TEM). X-ray photoelectron spectra (XPS) and Fourier transform infrared spectra (FTIR) results confirmed that the state of gold was metallic. The 1.86% Au/α-Fe2O3 catalyst calcined at 300 °C had the best catalytic performance for CO oxidation reaction and the mechanism for CO oxidation reaction was also discussed. It is highly likely that the small size of gold nanoparticle, oxygen vacancies and active sites played the decisive roles in CO oxidation reaction. View Full-Text
Keywords: Au/α-Fe2O3; worm-like; CO oxidation Au/α-Fe2O3; worm-like; CO oxidation

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Han, Q.; Zhang, D.; Guo, J.; Zhu, B.; Huang, W.; Zhang, S. Improved Catalytic Performance of Au/α-Fe2O3-Like-Worm Catalyst for Low Temperature CO Oxidation. Nanomaterials 2019, 9, 1118.

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