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Open AccessReview

Recent Progress on Transition Metal Nitrides Nanoparticles as Heterogeneous Catalysts

Institute of Catalysis and Petrochemistry, CSIC, c/Marie Curie No. 2, Cantoblanco, 28049 Madrid, Spain
UA UNED-ICP (CSIC) Group Des. Appl. Heter. Catal, 28049 Madrid, Spain
Nanomaterials 2019, 9(8), 1111;
Received: 15 July 2019 / Revised: 22 July 2019 / Accepted: 23 July 2019 / Published: 2 August 2019
(This article belongs to the Special Issue Application of New Nanoparticle Structures as Catalysts)
PDF [4289 KB, uploaded 2 August 2019]


This short review aims at providing an overview of the most recent literature regarding transition metal nitrides (TMN) applied in heterogeneous catalysis. These materials have received renewed attention in the last decade due to its potential to substitute noble metals mainly in biomass and energy transformations, the decomposition of ammonia being one of the most studied reactions. The reactions considered in this review are limited to thermal catalysis. However the potential of these materials spreads to other key applications as photo- and electrocatalysis in hydrogen and oxygen evolution reactions. Mono, binary and exceptionally ternary metal nitrides have been synthetized and evaluated as catalysts and, in some cases, promoters are added to the structure in an attempt to improve their catalytic performance. The objective of the latest research is finding new synthesis methods that allow to obtain smaller metal nanoparticles and increase the surface area to improve their activity, selectivity and stability under reaction conditions. After a brief introduction and description of the most employed synthetic methods, the review has been divided in the application of transition metal nitrides in the following reactions: hydrotreatment, oxidation and ammonia synthesis and decomposition. View Full-Text
Keywords: heterogeneous catalysis; transition metal nitrides heterogeneous catalysis; transition metal nitrides

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Dongil, A. Recent Progress on Transition Metal Nitrides Nanoparticles as Heterogeneous Catalysts. Nanomaterials 2019, 9, 1111.

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