Effect of Nano-SnS and Nano-MoS2 on the Corrosion Protection Performance of the Polyvinylbutyral and Zinc-Rich Polyvinylbutyral Coatings
Abstract
:1. Introduction
2. Experimental
2.1. Material and Sample Preparation
2.2. Weight Loss Measurements
2.3. Electrochemical Experiments
2.4. Scanning Electron Microscope (SEM) Observations
2.5. Theoretical Study
3. Results and Discussion
3.1. Weight Loss Measurements
3.2. Polarization Curve
3.3. Electrochemical Impedance Spectroscopy (EIS)
3.4. SEM Analyses
3.5. Corrosion Mechanism Analysis
3.6. Molecular Dynamics Simulation
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Material | Manufacturer | Label |
---|---|---|
Polyvinylbutyral | MACKLIN | P815775 |
Tin sulfide | 6Carbon Tech. Shenzhen | SC-CRYSTAL-SNS |
Molybdenum disulfide | HANLANE | MoS2-50 |
Zinc | HANLANE | Zn-50 |
Coating | ω (mg m−2 h−1) | ηw (%) |
---|---|---|
Blank | 59.52 | - |
PVB | 41.67 | 30 |
nano-SnS | 23.81 | 60 |
nano-SnS-Zn/PVB | 15.48 | 74 |
nano-MoS2/PVB | 20.24 | 66 |
nano-MoS2-Zn/PVB | 14.29 | 76 |
Coating | Ecorr (mV per SCE) | icorr (μA cm−2) | βc (mV dec−1) | βa (mV dec−1) | Crate (mpy) | |
---|---|---|---|---|---|---|
Blank | −245 | 2.185 | 60 | 55 | 1.00 | - |
PVB | −147 | 1.839 | 179 | 75 | 0.85 | 15.8 |
nano-SnS/PVB | −97 | 0.921 | 105 | 280 | 0.42 | 57.9 |
nano-SnS-Zn/PVB | −107 | 0.757 | 99 | 317 | 0.35 | 65.4 |
nano-MoS2/PVB | −98 | 0.710 | 102 | 297 | 0.33 | 67.5 |
nano-MoS2-Zn/PVB | −62 | 0.591 | 84 | 190 | 0.27 | 72.9 |
Coating | Rs (Ω cm2) | Rc (kΩ cm2) | Rct (kΩ cm2) | Cc (μF cm−2) | Cdl (μF cm−2) | W | |
---|---|---|---|---|---|---|---|
Blank | 7.94 | 0.04 | 0.32 | 13.08 | 128.30 | 0.002902 | - |
PVB | 19.50 | 0.07 | 3.50 | 1.84 | 18.17 | 0.000620 | 90.86 |
nano-SnS/PVB | 18.14 | 0.11 | 50.84 | 2.69 | 54.21 | - | 99.37 |
nano-SnS-Zn/PVB | 22.54 | 0.30 | 74.36 | 2.49 | 69.49 | - | 99.57 |
nano-MoS2/PVB | 20.07 | 0.26 | 97.84 | 3.07 | 60.39 | - | 99.67 |
nano-MoS2-Zn/PVB | 25.09 | 0.30 | 126.20 | 1.92 | 43.34 | - | 99.75 |
Classification | Samples | |
---|---|---|
Silicon carbide composite | POA–SiC/EP | 87.54 |
Metal Organic Framework | ATT/ZIF-8 | 97.3 |
Organic inhibitor | polyaspartic acid | 86.8 |
System | Interaction Energy (kcal mol−1) |
---|---|
Cu+PVB | −852.33 |
Cu+MoS2/PVB | −1838.253 |
Cu+SnS/PVB | −1074.433 |
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Qu, Z.; Wang, L.; Tang, H.; Ye, H.; Li, M. Effect of Nano-SnS and Nano-MoS2 on the Corrosion Protection Performance of the Polyvinylbutyral and Zinc-Rich Polyvinylbutyral Coatings. Nanomaterials 2019, 9, 956. https://doi.org/10.3390/nano9070956
Qu Z, Wang L, Tang H, Ye H, Li M. Effect of Nano-SnS and Nano-MoS2 on the Corrosion Protection Performance of the Polyvinylbutyral and Zinc-Rich Polyvinylbutyral Coatings. Nanomaterials. 2019; 9(7):956. https://doi.org/10.3390/nano9070956
Chicago/Turabian StyleQu, Zuopeng, Lei Wang, Hongyu Tang, Huaiyu Ye, and Meicheng Li. 2019. "Effect of Nano-SnS and Nano-MoS2 on the Corrosion Protection Performance of the Polyvinylbutyral and Zinc-Rich Polyvinylbutyral Coatings" Nanomaterials 9, no. 7: 956. https://doi.org/10.3390/nano9070956