Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions
Abstract
:1. Introduction
2. Materials and Methods
2.1. Synthesis of Sb2S3 Nanorods
2.2. Synthesis of Sb2S3@PPy Coaxial Nanorods
2.3. Materials Characterization
2.4. Electrochemical Performance
3. Results and Discussion
3.1. Materials Synthesis and Characterization
3.2. Lithium Storage Performances
3.3. Sodium Storage Performance
3.4. Potassium Storage Performance
3.5. Alkali Metal Ions Storage Mechanism
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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SIBs | KIBs | Ref. | |||||
---|---|---|---|---|---|---|---|
Electrode Material | Reversible Capacity (mAh g−1) | Cycle Life (mAh g−1) | Rate Performance (mAh g−1) | Reversible Capacity (mAh g−1) | Cycle Life (mAh g−1) | Rate Performance (mAh g−1) | |
Our work | 940 @ 0.1 A g−1 | 881 @ 0.1 A g−1 after 50 cycles | 940@ 0.1 A g−1 490 @ 1 A g−1 | 700 @ 0.1 A g−1 | 487 @ 0.1 A g−1 after 18 cycles | 690 @ 0.1 A g−1 280 @ 1 A g−1 | |
CNT@Sb2S3@PPy | 596 @ 0.1 A g−1 | 500 @ 0.1 A g−1 after 80 cycles | 596 @ 0.1 A g−1 400 @ 1 A g−1 | - | - | - | [30] |
Sb2S3@PPy | 600 @ 0.1 A g−1 | 427 @ 0.1 A g−1 after 50 cycles | 600 @ 0.1 A g−1 500 @ 1 A g−1 | - | - | - | [31] |
Sb2S3@C | 700 @ 0.2 A g−1 | 650 @ 0.2 A g−1 after 50 cycles | 700 @ 0.2 A g−1 450 @ 0.8 A g−1 | - | - | - | [32] |
3D SbNPs@C | - | - | - | 488 @ 0.2 A g−1 | 461 @ 0.2 A g−1 after 15 cycles | 478 @ 0.2 A g−1 288 @ 1 A g−1 | [33] |
Sb2S3-SNG | - | - | - | 530 @ 0.1 A g−1 | 500 @ 0.1 A g−1 after 100cycles | - | [34] |
Alkali Metal Ions | Diffusion Coefficient (cm2 s−1) |
---|---|
Li+ | 3.16 × 10−10 |
Na+ | 7 × 10−11 |
K+ | 1.78 × 10−10 |
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Shi, Y.; Li, F.; Zhang, Y.; He, L.; Ai, Q.; Luo, W. Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions. Nanomaterials 2019, 9, 560. https://doi.org/10.3390/nano9040560
Shi Y, Li F, Zhang Y, He L, Ai Q, Luo W. Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions. Nanomaterials. 2019; 9(4):560. https://doi.org/10.3390/nano9040560
Chicago/Turabian StyleShi, Yang, Feng Li, Yi Zhang, Liang He, Qing Ai, and Wen Luo. 2019. "Sb2S3@PPy Coaxial Nanorods: A Versatile and Robust Host Material for Reversible Storage of Alkali Metal Ions" Nanomaterials 9, no. 4: 560. https://doi.org/10.3390/nano9040560