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Open AccessArticle

H2S Sensing by Hybrids Based on Nanocrystalline SnO2 Functionalized with Cu(II) Organometallic Complexes: The Role of the Ligand Platform

1
Faculty of Chemistry, Moscow State University, 119991 Moscow, Russia
2
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 119991 Moscow, Russia
*
Author to whom correspondence should be addressed.
Nanomaterials 2017, 7(11), 384; https://doi.org/10.3390/nano7110384
Received: 1 October 2017 / Revised: 24 October 2017 / Accepted: 6 November 2017 / Published: 9 November 2017
(This article belongs to the Special Issue Nanomaterials for Sensing Applications)
This paper deals with the functionalization of nanocrystalline SnO2 with Cu(II) complexes with organic ligands, aimed at the improvement of sensor selectivity towards gas molecules. For the synthesis of metalorganic/SnO2 hybrid material complexes of Cu(II) with phthalocyanine, porphyrinines, bipyridine and azadithiacrown etherwere used. The analysis of gas sensor properties showed the possibility of increasing the sensitivity and selectivity of hybrid materials in H2S detection due to the electron transfer from SnO2 to an adsorbed organic molecule, which changes during the interaction between H2S and Cu(II) ions. View Full-Text
Keywords: organic–inorganic hybrid materials; tin dioxide; Cu(II) complex; H2S; semiconductor gas sensor organic–inorganic hybrid materials; tin dioxide; Cu(II) complex; H2S; semiconductor gas sensor
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MDPI and ACS Style

Rumyantseva, M.; Makeeva, E.; Gaskov, A.; Shepel, N.; Peregudova, S.; Khoroshutin, A.; Tokarev, S.; Fedorova, O. H2S Sensing by Hybrids Based on Nanocrystalline SnO2 Functionalized with Cu(II) Organometallic Complexes: The Role of the Ligand Platform. Nanomaterials 2017, 7, 384. https://doi.org/10.3390/nano7110384

AMA Style

Rumyantseva M, Makeeva E, Gaskov A, Shepel N, Peregudova S, Khoroshutin A, Tokarev S, Fedorova O. H2S Sensing by Hybrids Based on Nanocrystalline SnO2 Functionalized with Cu(II) Organometallic Complexes: The Role of the Ligand Platform. Nanomaterials. 2017; 7(11):384. https://doi.org/10.3390/nano7110384

Chicago/Turabian Style

Rumyantseva, Marina; Makeeva, Ekaterina; Gaskov, Alexander; Shepel, Nikolay; Peregudova, Svetlana; Khoroshutin, Andrey; Tokarev, Sergey; Fedorova, Olga. 2017. "H2S Sensing by Hybrids Based on Nanocrystalline SnO2 Functionalized with Cu(II) Organometallic Complexes: The Role of the Ligand Platform" Nanomaterials 7, no. 11: 384. https://doi.org/10.3390/nano7110384

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