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Article

Self-Assembled Metal Nanohole Arrays with Tunable Plasmonic Properties for SERS Single-Molecule Detection

CNR-IMM, Institute for Microelectronic and Microsystems, Lecce, University Campus Ecotekne, Via per Monteroni, 73100 Lecce, Italy
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Authors to whom correspondence should be addressed.
Academic Editors: Kosei Ueno and Alessandro De Giacomo
Nanomaterials 2022, 12(3), 380; https://doi.org/10.3390/nano12030380
Received: 1 December 2021 / Revised: 11 January 2022 / Accepted: 21 January 2022 / Published: 24 January 2022
(This article belongs to the Special Issue Nanostructured Materials for Photonics and Plasmonics)
Arrays of metal nano-holes have proved to be among of the most promising structures for applications in the field of nano-photonics and optoelectronics. Supporting both localized and propagating surface plasmons resonances, they are characterized by very high versatility thanks to the tunability of these modes, by means of the change of their periodicity, the size of the holes and metal composition. The interaction between different optical features can be exploited to modulate electromagnetic field distribution leading various hot-spots excitations on the metal surfaces. In this work, long range ordered arrays of nano-holes in thin gold films, with different geometrical characteristics, were fabricated by a modified nano-sphere lithography protocol, which allows precise control on holes’ dimensions together with the preservation of the order and of the pristine periodicity of the array. An in-depth analysis of the correlation between surface plasmon modes interference and its effect on electromagnetic field distribution is proposed, both by numerical simulations and experimentally. Finally, metal nano-holes arrays are exploited for surface enhanced Raman experiments, evaluating and comparing their performances by the estimation of the enhancement factor. Values close to the single molecule detection are obtained for most of the samples, proving their potentialities in surface enhanced spectroscopy applications. View Full-Text
Keywords: metal nanoholes array; nanofabrication; nanosphere lithography; near field characterization; SERS metal nanoholes array; nanofabrication; nanosphere lithography; near field characterization; SERS
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MDPI and ACS Style

Lospinoso, D.; Colombelli, A.; Lomascolo, M.; Rella, R.; Manera, M.G. Self-Assembled Metal Nanohole Arrays with Tunable Plasmonic Properties for SERS Single-Molecule Detection. Nanomaterials 2022, 12, 380. https://doi.org/10.3390/nano12030380

AMA Style

Lospinoso D, Colombelli A, Lomascolo M, Rella R, Manera MG. Self-Assembled Metal Nanohole Arrays with Tunable Plasmonic Properties for SERS Single-Molecule Detection. Nanomaterials. 2022; 12(3):380. https://doi.org/10.3390/nano12030380

Chicago/Turabian Style

Lospinoso, Daniela, Adriano Colombelli, Mauro Lomascolo, Roberto Rella, and Maria Grazia Manera. 2022. "Self-Assembled Metal Nanohole Arrays with Tunable Plasmonic Properties for SERS Single-Molecule Detection" Nanomaterials 12, no. 3: 380. https://doi.org/10.3390/nano12030380

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