1. Introduction
As the main power source, the diesel engine is widely used in ships, which is crucial to ensure the stability of navigation and operational efficiency. Due to the increasing energy consumption and the depletion of fossil fuels, countries around the world are actively promoting the development and application of renewable and clean energy [
1]. Many researchers have paid much attention to the development of cleaner alternative fuels, such as natural gas, bio-diesel, and alcohols, for reducing the PM emission and decreasing the dependence on fossil fuels [
2]. As a kind of clean, renewable energy, n-butanol is a high-quality diesel alternative fuel, which can be mixed with diesel in any proportion to avoid liquid phase separation and improve the stability of ethanol and diesel miscibility. It has a wide range of application prospects [
3,
4]. Ethanol and n-butanol can be made from crops such as corn, cassava, barley, sugar cane, and other agricultural products [
5]. When ethanol and n-butanol are used in marine diesel engines as alternative fuels, the stability of their operation needs to be paid more attention to. Long sailing time, bad sea conditions, and a high-intensity working environment expose ship equipment to various potential failure risks, including various failures of diesel engines [
6].
Ethanol has been widely studied in the research of alternative fuels. Chen [
7] studied combustion and emission characteristics under different ethanol ratios by injecting ethanol into the inlet and injecting diesel directly into the cylinder. The research results showed that with the increase in the ethanol ratio, the combustion duration of the engine was shortened, the ignition delay was prolonged, and the particle concentration in the engine was reduced. Wei [
8] studied the effects of ethanol substitution rate and EGR rate on diesel engine combustion and emission under high load by numerical simulation. The research results show that with the increase in the ethanol ratio, the content of soot and CO generated in the cylinder decreases, but the content of NO
x and HC generated increases. The maximum content of NO
x can be reduced by increasing the EGR rate. Pedrozo [
9] conducted experiments on a single-cylinder heavy-duty diesel engine with a constant speed of 1200 rpm, and studied the experimental study of dual-fuel combustion from low load to full load. The experimental results showed that when the indicated average effective pressure range was 0.6 MPa to 2.4 MPa, dual-fuel engines have a higher net indicated thermal efficiency than conventional diesel engines, while NO
x emissions are up to 90% lower than conventional diesel engines.
N-butanol is a four-carbon alcohol. Its carbon content is higher than ethanol, and it has good miscibility with diesel oil, with no need to add a cosolvent. Ning [
10] studied the effects of n-butanol addition on combustion and emission characteristics of diesel engines. The results showed that the addition of n-butanol made flame development slow and flame propagation fast, and the braking thermal efficiency of diesel engines decreased with the increase in the n-butanol mixing ratio. Lmani [
11] studied the combustion performance of n-butanol and diesel mixture at different injection times by means of experiment and numerical simulation. The research results showed that the addition of n-butanol increased the thermal efficiency and improved the combustion emission characteristics of the diesel engine compared with diesel. Plus, with the increase in the mixing ratio of n-butanol, the emission of NO
x, CO, and particulate matter decreased. Nadir [
12] studied the effect of adding n-butanol to diesel on the emission of polycyclic aromatic hydrocarbons (PAH) from diesel engines. The results show that the addition of n-butanol can significantly reduce the formation of PAHs.
The numerical simulation of a diesel engine is based on heat transfer, fluid dynamics, thermodynamics, and other disciplines to explain the fuel mixing, gas flow, and combustion processes in a diesel engine. Therefore, the numerical simulation can predict the combustion emission of diesel engines more accurately, and can also provide guidance for experimental research [
13,
14,
15,
16]. The CONVERGE software has obvious advantages in numerical simulation of a diesel engine. The multi-dimensional model of CONVERGE can describe the combustion process in the cylinder more accurately, which provides important support for experimental research [
17,
18,
19,
20]. In order to ensure the safety of navigation, it is necessary to maintain the diesel engine regularly, so the fault diagnosis technology of marine diesel engines comes into being [
21,
22].
In order to investigate the combustion and emission performance of ethanol and n-butanol as diesel alternative fuels in marine diesel engines, and to evaluate their potential as diesel alternative fuels, they were mixed with diesel in the way of partial substitution. In addition, the application of new alternative fuels may lead to the abnormal injection state of the injector, which will affect the reliability and performance of the equipment. Therefore, in order to improve the safety of the diesel engine, the abnormal state of the injector is diagnosed and recognized by the simulation data. By combining the combustion emission analysis of the fuel mixture with the status recognition of the fuel injector, it is expected that the combustion performance of the fuel mixture in the diesel engine can be fully understood, and the status diagnosis of the fuel injector can be realized in time, so as to improve its stability. Finally, it can expand the application of clean alternative fuels in diesel engines.
3. Results and Discussions
3.1. Combustion and Emissions with Different Fuel Blending Ratios
3.1.1. Cylinder Pressure and Heat Release Rate
The effects of the ethanol blending ratio on the combustion characteristics of the diesel engine at 100%, 75%, and 50% load are shown in
Figure 3. The peak cylinder pressures of D80E10B10, D70E20B10, and D60E30B10 blended fuels were 0.67%, 0.6%, and 0.48% higher than that of D100, respectively, while the peak cylinder pressure of D50E40B10 was 0.46% lower than that of D100. With the increase in the ethanol blending ratio, the peak cylinder pressure of D80E10B10, D70E20B10, D60E30B10, and D50E40B10 gradually decreased. Meanwhile, the ignition timing of the blended fuels gradually shifted back. This phenomenon is due to the obvious improvement in the atomization effect of the blended fuels at low ethanol blending ratios. At the same time, the blended fuels have higher oxygen content, which helps to promote complete combustion of the fuel in the cylinder, thereby increasing the peak combustion pressure in the cylinder, making the cylinder pressure peak of the blended fuels higher than that of diesel. However, as the ethanol blending ratio increased, on the one hand, the heat value of the blended fuels was lower than that of pure diesel, and on the other hand, due to the high evaporation enthalpy of ethanol and n-butanol, the ignition timing of the blended fuels was delayed, the delay in ignition period was increased, and the ignition timing was shifted to after the top dead center (the highest point of the piston stroke, when the crankshaft angle is 0 °CA), at which time the cylinder volume increased and cylinder pressure decreased, ultimately leading to a continuous decrease in the peak cylinder pressure.
Meanwhile, it can be seen from the figure that the peak instant heat release rate is significantly higher than that of pure diesel, and the corresponding crankshaft angle at each peak also gradually shifts later. In addition, the peak instant heat release rate of the same mixture of fuel also gradually decreases. The peak instant heat release rates of D80E10B10, D70E20B10, D60E30B10, and D50E40B10 mixture fuels are 1.35, 1.43, 1.44, and 1.24 times higher than that of D100, respectively. The corresponding crankshaft angle is delayed from 9.61 °CA to 9.12 °CA because of the low cetane number and high latent heat of the vaporization of ethanol, which can delay the ignition of the mixture fuel and prolong the diffusion time of the mixture fuel in the cylinder. Thus, the number of combustible mixtures is increased during the premixing stage, and heat release is more concentrated during combustion, which increases the peak instant heat release rate.
3.1.2. CA10, CA50, CA90, and IMEP
Figure 4 shows the effects of different blending ratios of the diesel/ethanol/n-butanol mixture on CA10, CA50, CA90, and IMEP. In this study, CA10, CA50, and CA90 represent the crankshaft angles corresponding to 10%, 50%, and 90% of the cumulative heat release in the cylinder, respectively, with CA10 representing the ignition start point, CA50 representing the combustion center, and CA90 representing the ignition end point. The delay period is defined as the crankshaft angle from the start of fuel injection to CA10, and the combustion duration is defined as the crankshaft angle between CA10 and CA90. It can be seen that, with the increases in the ethanol blending ratio, the CA10 of the diesel engine increases, while CA50, CA90, and IMEP decrease. The ignition start point undergoes a gradual shift from −0.6 °CA to 4.21 °CA. This is mainly because when the ethanol content increases, the cetane number of the mixture decreases, causing delayed combustion, prolonged delay period, and increased diffusion time of the mixture in the cylinder. As a result, the combustion duration decreases. In addition, since the ignition start point of the mixture gradually moves away from the top dead center, the cylinder volume increases, and the heat released by the fuel is less effectively converted into work, causing a decrease in IMEP.
3.1.3. NOx, Soot, CO, and CO2 Emissions
The effects of different ethanol blending ratios on emissions of diesel engines are shown in
Figure 5. The NO
x emissions decrease, and the ethanol blending ratio increases. The NO
x emissions of D80E10B10 fuel are slightly higher than those of pure diesel, and they gradually decrease and become lower than those of D100 because NO
x formation is affected by high temperature, oxygen enrichment, and longer combustion duration. The reduction in NO
x emissions is due to the high latent heat value of ethanol, which absorbs heat during combustion and lowers the cylinder temperature. On the other hand, the increase in ethanol reduces the viscosity of the blended fuel, thereby improving the quality of the in-cylinder mixture and increasing the combustion speed, which shortens the combustion duration and reduces NO
x emissions in a comprehensive manner.
When the ethanol blending ratio increases, the soot emissions gradually decrease. Compared with D100, the soot emissions of D80E10B10, D70E20B10, D60E30B10, and D50E40B10 blended fuels are reduced by 11.93%, 19.64%, 28.2%, and 29.18%, respectively. This is because ethanol has a lower octane number, which delays the ignition of the blended fuel, prolonging the diffusion time of the fuel and improving the premixing effect, thereby promoting combustion. Meanwhile, the addition of ethanol and n-butanol reduces the viscosity of the blended fuel, thereby improving its atomization and evaporation effects, further promoting the combustion process. In addition, the high oxygen content of ethanol and n-butanol also plays a positive role in oxidizing carbon smoke.
When the ethanol blending ratio increases, the CO2 emissions decrease, and the maximum in-cylinder CO generation decreases, while the final emissions increase. This is mainly due to the fact that during the peak generation stage of CO, the rapid heat release phase is in the cylinder; at this time, the mixed fuel is fully burned, and the maximum value of CO generation decreases. However, due to the higher latent heat value of ethanol than diesel, the mixed fuel will absorb a large amount of heat and generate a large amount of water vapor during the combustion stage. Subsequently, as the cylinder pressure and temperature decrease, CO cannot be fully oxidized to CO2, ultimately causing the final CO emissions to increase while the CO2 emissions decrease.
3.2. Combustion and Emissions with Different Injection Times
3.2.1. Cylinder Pressure and Heat Release Rate
The effect of different injection times on the in-cylinder pressure and heat release rate when a single injection strategy is adopted is illustrated in
Figure 6. It can be observed from the figures that as the injection time advances, both the peak values of cylinder pressure and the instantaneous heat release rate increase. Specifically, when the injection time is advanced to −17 °CA, there is a more uniform gas mixture in the cylinder, resulting in a rapid combustion-induced pressure rise with a peak value of 10.31 MPa at 5.51 °CA. Moreover, compared to the original model, an increase of 3729.94 J/deg can be seen in terms of peak instantaneous heat release rate while its corresponding crankshaft angle shifts from 1.7 °CA to −2.47 °CA. Due to extended fuel diffusion time caused by piston movement away from the top dead center, the volume within the cylinder is increased, which leads to lower pressure and temperature conditions inside it, along with enhanced premix effect facilitated by ethanol and n-butanol volatilization during the compression phase.
3.2.2. CA10, CA50, CA90 and IMEP
Figure 7 shows the effects of different injection times on CA10, CA50, CA90, and IMEP. CA10, CA50, and CA90 advance correspondingly with the advance of fuel injection time, and IMEP first increases and then decreases. The combustion delay period of the mixed fuel gradually increases, and the combustion duration gradually decreases. At −17 °CA, the longest fuel injection ignition delay period is 14.4 °CA, and the shortest combustion duration is 11.63 °CA. The IMEP of −17 °CA is increased by 0.01 MPa compared with that of −9 °CA. This is mainly due to the advance of the injection time. When the mixed fuel enters the cylinder, the pressure and temperature in the cylinder are relatively low; when the spray penetration distance is increased, the fuel diffusion time is extended, and the ignition delay period is increased. At the same time, as CA10 gradually approaches TDC, the volume in the cylinder decreases, the pressure increases, and the temperature rises, which increases the proportion of fuel combustion, thus speeding up the combustion rate and shortening the combustion duration. The reason why IMEP increases first and then decreases is that with the advance of fuel injection time, the center of gravity of combustion gradually approaches TDC from far away, and the work done by the heat released by combustion on the piston increases, resulting in the gradual increase in IMEP [
24]. But then the IMEP decreases as the starting point of combustion changes from near TDC to away from TDC.
3.2.3. NOx, Soot, CO, and CO2 Emissions
The effect of injection time on emissions from the diesel engine is shown in
Figure 8. It can be observed from the figures that NO
x emission gradually increases with the advance of oil injection time, while both the maximum production and total emission of soot continuously decrease. Compared to −9 °CA, NO
x emission at −17 °CA nearly doubles, whereas soot emission decreases by 23.35%. This phenomenon can be attributed to the improved mixing effect of mixed fuel due to the advance of fuel injection time and extension of the combustion delay period, resulting in a reduced proportion of local concentrated mixture. Additionally, ethanol and n-butanol, as oxygen-containing fuels, contribute oxygen atoms during fuel combustion, leading to more complete burning and higher cylinder temperature, which subsequently elevates NO
x emissions while reducing soot generation. With the advance of the injection time, the maximum production of CO in the cylinder decreases, while the emissions gradually increase, and the CO
2 emissions gradually decrease. The CO emission at −17 °CA increased by 81.5% compared to the −9 °CA injection. The reason for this phenomenon is that with the advance of the injection time, the premix effect of the mixture is good, and CO is fully oxidized to CO
2 in the main stage of combustion, and the maximum amount of CO production decreases. However, due to the advance of the injection time, the pressure and temperature of the fuel entering the cylinder are low, resulting in a prolonged ignition delay period. In this case, part of the gas mixture enters the piston gap and the cylinder boundary. Due to the cold shock effect, these gas mixtures are not sufficiently burned in the gap, ultimately leading to an increase in CO emissions and a decrease in CO
2 emissions.
3.3. Combustion and Emissions with Different Prespray Times
The impact of pre-injection timing on cylinder pressure and instantaneous heat release rate under two injection strategies is shown in
Figure 9. The peak values of cylinder pressure and instantaneous heat release rate during the pre-injection stage gradually decrease with earlier pre-injection times, while those during the main injection stage increase. This phenomenon is mainly attributed to a larger main pre-injection interval at earlier timings, resulting in a greater distance between the piston top dead center and injected fuel, leading to lower temperature and slower combustion of the formed premix due to a longer combustion delay period. Moreover, thinner premix further slows down combustion speed and reduces the peak value of the heat release rate during the pre-injection stage. Longer mixing time for the unburned part with air in this stage results in more mixtures conducive to fire during the primary injection stage when main injection fuel is introduced into the cylinder, causing a faster reaction rate and leading to higher peak heat release rate concentration. Additionally, as the piston descends during the main injection combustion phase with advancing pre-injection time, the volume inside the cylinder increases, which causes a reduction in cylinder pressure.
Figure 10 shows the effects of different pre-spray times on CA10, CA50, CA90, and IMEP. With the advance of the pre-spray time, CA10 and CA50 gradually increase. CA90 first increases and then decreases, but the changes for CA10, CA50, and CA90 are not obvious. This is mainly due to the advance of the pre-injection time. The pre-injection fuel in the cylinder mixing time is longer, and a relatively thin mixture is formed. The main injection fuel needs more time to diffuse to improve the equivalent ratio of the mixture, and the fuel will undergo compressed combustion. Since the combustion center of gravity is delayed after the top stop point, the heat released by the combustion of fuel in the cylinder does less work on the piston.
The influence of pre-injection time on pollutant emission of the diesel engine is shown in
Figure 11. The NO
x emission decreases first and then increases with the advance of pre-injection time, while the soot emission increases gradually. This is because the interval between the main injection and pre-injection is small at the initial stage. The diffusion time of pre-injection fuel is short, and most of the fuel is burned together with the main injection stage. The initial combustion temperature is low, resulting in a decrease in NO
x emissions. With the increase in the main injection and pre-injection interval, the pre-injection fuel is fully diffused, which helps to form a better mixture, resulting in an increase in local high temperature areas during the combustion process. The reason why soot emission increases gradually is that the piston is still far away from TDC, and the hot atmosphere in the cylinder is poor as the pre-injection time advances. At this time, part of the early combustion occurred at a lower temperature and pressure, which is not conducive to soot oxidation and combustion, thus increasing soot emission.
With the advance of pre-injection timing, there is a gradual increase in CO emission and a corresponding decrease in CO2 emission. Firstly, as the pre-injection time increases, the pressure and temperature within the cylinder decrease, leading to poor fuel atomization and inadequate fuel-air mixing. Consequently, wet wall formation becomes more likely, impeding the complete combustion of the pre-injected fuel mixture. Additionally, ethanol and n-butanol vaporization absorbs heat energy during combustion, resulting in lower overall combustion temperatures. As a consequence of these conditions, an increased amount of incompletely burned fuel enters the gap between the cylinder and the piston. Consequently, incomplete oxidation of generated CO into CO2 occurs, contributing to elevated levels of CO emissions while simultaneously reducing levels of CO2 emissions.
3.4. Fault Diagnosis of Fuel Injector
In this paper, two sets of fault simulation data are established for the fuel injection advance and delay fault phenomena. Firstly, the simulation data range for fuel injection advance failure is set from −13 °CA to −23 °CA at 1 °CA intervals, resulting in a total of 10 datasets. Secondly, the simulation data range for the injection lag fault extends from −7 °CA to 3 °CA at 1 °CA intervals, also comprising 10 datasets. Additionally, for the insufficient fuel injection fault phenomenon, the fuel injection range is reduced from 20.25 mg to 6.75 mg with a dataset created every 1.35 mg incrementally. The normal working state is defined as ranging from −8 °CA to −10 °C with an interval of 0.2 °C, resulting in a total of ten groups of data as well. Furthermore, during the process of fault diagnosis, six thermodynamic parameters were selected as characteristic indicators: average effective pressure (F1), explosion pressure (F2), crankshaft angle corresponding to explosion pressure (F3), maximum combustion temperature (F4), ignition delay period (F5), and combustion duration (F6).
The data of three fault conditions and one normal condition are extended using simulation and data interpolation technology. A total of 400 sets of data are obtained, with 100 sets for each condition. The data was divided into a training set containing 320 sets of data (80% of the total sample) and a test set containing 80 sets of data, 20 for each condition. After that, the data set is substituted into the PNN model for the classification task, and the smoothing factor parameter is set to 1. Then, it is compared with a radial basis function (RBF) neural network. The diagnostic accuracy of the PNN/RBF model is shown in
Figure 12. The PNN diagnostic model outperforms the RBF model in effectively identifying fuel injector faults; however, its average accuracy remains at 86%. Therefore, it is imperative to enhance the reliability and accuracy of the PNN diagnostic model for practical engineering applications.
The PSO-PNN and WOA-PNN models are employed for classification tasks, with data sets being utilized. In both optimization algorithms, the initial population is set to 50, the number of iterations is 100, and the variables have a lower bound of 0.001 and an upper bound of 100.
Figure 13 presents a comparison of the classification accuracy between these two models. The PSO-PNN model achieves an average accuracy of 90% in accurately identifying injector faults, while the WOA-PNN model demonstrates a higher average accuracy of 95%. In conclusion, the WOA-PNN model exhibits superior advantages in fault status identification and diagnosis for Marine diesel engines, enabling more precise detection of engine faults. Additionally, the exploration of the innovative hybrid FSO/RF communication system has illuminated a promising path towards addressing the challenges posed by atmospheric turbulence [
25].