Groundwater Quality Near Riverbanks and Its Suitability for Agricultural Use in Semi-Arid Regions
Abstract
1. Introduction
2. Materials and Methods
2.1. Study Area
2.2. Sampling Design
2.3. Laboratory Analyses
- pHc = the pH at which water with a given calcium content and alkalinity is in equilibrium with calcium carbonate.
- K2 = the second dissociation constant for carbonic acid.
- Kc = the solubility product constant for calcium carbonate.
2.4. Data Analysis and Classification
3. Results and Discussion
3.1. Soil Characterization
3.2. Groundwater Characterization
3.3. Groundwater Levels in the Wells of the Study Sites
3.4. Groundwater Quality
3.5. Limitations and Future Investigations
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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| Crop Division | Electric Conductivity (EC) | ||
|---|---|---|---|
| Low Salt Tolerance Crops | Medium Salt Tolerance Crops | High Salt Tolerance | |
| Fruit Crops | (0–3000) (μS cm−1): Limon, Peach, Pear Apricot, Orange, Apple | (3000–4000) (μS cm−1): Cantaloupe, Olive, Figs, Pomegranate | (4000–10,000) (μS cm−1): Date palm |
| Vegetable Crops | (3000–4000) (μS cm−1): Green beans, Celery, Radish | (4000–10,000) (μS cm−1): Cucumber, Peas, Onion, Carrot, Potatoes, Lettuce, Cauliflower, Tomato | (10,000–120,000) (μS cm−1): Spinach, beets |
| Field Crops | (4000–6000) (μS cm−1): Field beans | (6000–10,000) (μS cm−1): Sunflower, Corn, Rice, Flax, Sorghum | (10,000–16,000) (μS cm−1): Cotton, Sugar beet, Barley (grains) |
| Location | pH | EC | Ca | Mg | Na | K | Cl | SO4 | HCO3 | CO3 | SAR | ESP | Sand | Silt | Clay | Texture |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| ds m−1 | meq L−1 | (mmol L−1)½ | % | gm kg−1 | ||||||||||||
| S1 | 8.32 | 2.22 | 9.32 | 6.21 | 7.15 | 1.23 | 13.21 | 7.51 | 1.60 | Nil | 2.57 | 3.99 | 552 | 316 | 132 | SL |
| S2 | 7.12 | 9.41 | 26.97 | 40.25 | 27.52 | 1.34 | 55.46 | 43.92 | 6.20 | Nil | 4.75 | 6.43 | 440 | 317 | 243 | L |
| S3 | 7.71 | 3.92 | 14.18 | 12.40 | 12.76 | 1.42 | 25.43 | 13.73 | 1.20 | Nil | 3.50 | 5.04 | 443 | 368 | 189 | L |
| S4 | 7.20 | 8.70 | 38.31 | 13.53 | 37.20 | 1.91 | 49.22 | 23.26 | 7.52 | Nil | 7.31 | 9.30 | 602 | 277 | 121 | SL |
| S5 | 7.44 | 3.00 | 6.11 | 10.23 | 11.89 | 1.25 | 20.73 | 8.61 | 2.25 | Nil | 4.16 | 5.77 | 436 | 319 | 245 | L |
| S6 | 8.25 | 2.12 | 4.99 | 8.31 | 6.82 | 1.60 | 10.22 | 9.01 | 1.97 | Nil | 2.64 | 4.07 | 520 | 271 | 209 | SCL |
| S7 | 7.05 | 10.01 | 33.21 | 29.32 | 42.21 | 2.10 | 59.21 | 40.15 | 3.20 | Nil | 7.55 | 9.57 | 524 | 267 | 209 | SCL |
| S8 | 7.55 | 4.84 | 16.93 | 14.92 | 15.29 | 1.40 | 22.37 | 25.20 | 1.24 | Nil | 3.83 | 5.40 | 459 | 367 | 174 | L |
| S9 | 7.00 | 11.13 | 34.96 | 41.83 | 32.17 | 1.69 | 70.21 | 41.01 | 1.40 | Nil | 5.19 | 6.93 | 638 | 213 | 149 | SL |
| S10 | 7.95 | 2.35 | 9.34 | 6.56 | 6.80 | 0.76 | 6.21 | 13.21 | 1.21 | Nil | 2.41 | 3.82 | 541 | 383 | 76 | SL |
| S11 | 7.62 | 3.11 | 12.13 | 8.15 | 10.06 | 1.02 | 19.54 | 10.63 | 1.76 | Nil | 3.16 | 4.66 | 509 | 337 | 154 | L |
| S12 | 7.31 | 5.18 | 20.8 | 12.96 | 17.62 | 1.32 | 32.5 | 17.60 | 2.11 | Nil | 4.29 | 5.92 | 521 | 339 | 140 | L |
| Max | 8.32 | 11.13 | 38.31 | 41.83 | 42.21 | 2.1 | 70.21 | 43.92 | 7.52 | Nil | 7.55 | 9.57 | 638 | 383 | 245 | - |
| Min | 7.00 | 2.12 | 4.99 | 6.21 | 6.80 | 0.76 | 6.21 | 7.51 | 1.20 | Nil | 2.41 | 3.82 | 436 | 213 | 76 | - |
| Mean | 7.54 | 5.50 | 18.94 | 17.06 | 18.96 | 1.43 | 32.03 | 21.15 | 2.64 | Nil | 4.28 | 5.91 | 515 | 315 | 170 | - |
| SD | 0.45 | 3.37 | 11.76 | 12.75 | 12.57 | 0.55 | 21.23 | 13.57 | 2.07 | Nil | 1.71 | 1.91 | 64.03 | 49.82 | 51.04 | |
| Location | pH | EC | Ca | Mg | Na | K | Cl | SO4 | HCO3 | CO3 | SAR | |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| ds m−1 | meq L−1 | (mmol L−1)½ | ||||||||||
| Season 1 | W1 | 7.31 | 2.88 | 9.10 | 6.30 | 12.10 | 0.90 | 17.5 | 10.49 | 2.11 | Nil | 4.36 |
| W2 | 7.56 | 3.28 | 8.42 | 5.36 | 16.41 | 0.87 | 20.32 | 8.97 | 2.74 | Nil | 6.25 | |
| W3 | 7.78 | 1.38 | 4.21 | 3.12 | 4.82 | 0.64 | 6.44 | 5.31 | 2.23 | Nil | 2.52 | |
| W4 | 7.18 | 4.28 | 11.42 | 10.97 | 15.73 | 1.04 | 22.31 | 14.36 | 3.64 | Nil | 4.70 | |
| Season 2 | W1 | 7.84 | 3.72 | 8.84 | 8.28 | 9.21 | 0.64 | 12.93 | 11.52 | 3.31 | Nil | 3.15 |
| W2 | 7.31 | 4.13 | 13.02 | 8.18 | 18.65 | 0.98 | 29.51 | 10.09 | 3.12 | Nil | 5.73 | |
| W3 | 8.09 | 1.50 | 4.97 | 3.83 | 4.92 | 0.80 | 6.35 | 5.96 | 2.91 | Nil | 2.35 | |
| W4 | 7.15 | 4.02 | 11.31 | 10.21 | 17.21 | 1.00 | 22.73 | 14.68 | 3.79 | Nil | 5.25 | |
| Season 3 | W1 | 7.16 | 4.94 | 10.21 | 9.02 | 28.60 | 0.75 | 32.12 | 15.18 | 4.44 | Nil | 9.22 |
| W2 | 7.10 | 5.49 | 15.24 | 10.52 | 29.66 | 0.20 | 26.84 | 25.54 | 2.98 | Nil | 8.26 | |
| W3 | 8.18 | 2.19 | 7.43 | 6.35 | 7.79 | 0.35 | 10.11 | 9.26 | 2.91 | Nil | 2.97 | |
| W4 | 7.09 | 5.14 | 14.37 | 8.32 | 28.2 | 0.19 | 26.18 | 23.69 | 2.93 | Nil | 8.37 | |
| Season 4 | W1 | 7.21 | 5.02 | 19.89 | 15.32 | 14.23 | 0.13 | 32.21 | 15.64 | 3.41 | Nil | 3.39 |
| W2 | 7.08 | 5.18 | 19.16 | 17.41 | 14.81 | 0.14 | 27.27 | 22.83 | 2.31 | Nil | 3.46 | |
| W3 | 7.83 | 2.23 | 8.21 | 7.13 | 7.03 | 0.24 | 11.32 | 9.05 | 2.02 | Nil | 2.54 | |
| W4 | 7.15 | 4.99 | 17.82 | 12.27 | 18.47 | 0.14 | 23.56 | 24.19 | 3.29 | Nil | 4.76 | |
| Season 5 | W1 | 7.11 | 4.91 | 20.23 | 18.64 | 10.79 | 0.14 | 19.63 | 27.63 | 4.12 | Nil | 2.45 |
| W2 | 7.21 | 5.21 | 22.52 | 16.83 | 12.58 | 0.17 | 18.38 | 28.24 | 4.71 | Nil | 2.84 | |
| W3 | 7.82 | 1.53 | 5.19 | 4.12 | 5.83 | 0.31 | 5.96 | 6.26 | 2.63 | Nil | 2.70 | |
| W4 | 7.01 | 4.96 | 18.76 | 17.41 | 13.15 | 0.16 | 28.16 | 20.62 | 1.53 | Nil | 3.09 | |
| Season 6 | W1 | 7.18 | 4.79 | 17.24 | 14.93 | 15.70 | 0.25 | 24.36 | 20.14 | 2.51 | Nil | 3.91 |
| W2 | 7.00 | 5.35 | 15.27 | 12.85 | 24.44 | 0.19 | 31.14 | 21.11 | 1.21 | Nil | 6.52 | |
| W3 | 7.88 | 1.93 | 7.85 | 6.23 | 5.31 | 0.23 | 8.31 | 12.03 | 1.10 | Nil | 2.00 | |
| W4 | 7.03 | 4.93 | 15.36 | 13.96 | 19.83 | 0.18 | 29.13 | 20.14 | 2.12 | Nil | 5.18 | |
| Max | 8.18 | 5.49 | 22.52 | 18.64 | 29.66 | 1.04 | 32.21 | 28.24 | 4.71 | Nil | 9.22 | |
| Min | 7.00 | 1.38 | 4.12 | 3.12 | 4.82 | 0.13 | 5.96 | 5.31 | 1.10 | Nil | 2.00 | |
| Mean | 7.39 | 3.92 | 12.75 | 10.32 | 14.81 | 0.42 | 20.53 | 15.96 | 2.84 | Nil | 4.42 | |
| SD | 1.55 | 1.41 | 5.39 | 4.72 | 7.48 | 0.33 | 8.78 | 7.19 | 0.93 | Nil | 2.07 | |
| Location | PHc | TDS | SI | RSC | SARadj | Na% | SR | JR | PS | MR | |
|---|---|---|---|---|---|---|---|---|---|---|---|
| mg L−1 | - | meq L−1 | (mmol L−1)½ | % | - | - | meq L−1 | % | |||
| Season 1 | W1 | 6.1 | 1843.20 | 1.21 | −13.29 | 14.39 | 47.27 | 8.29 | 0.69 | 22.75 | 40.91 |
| W2 | 6.0 | 2099.20 | 1.56 | −11.04 | 21.25 | 55.63 | 7.42 | 0.81 | 24.81 | 38.90 | |
| W3 | 6.4 | 883.20 | 1.38 | −5.10 | 7.56 | 42.69 | 2.89 | 0.75 | 9.10 | 42.56 | |
| W4 | 5.8 | 2739.20 | 1.38 | −18.75 | 16.92 | 42.82 | 6.13 | 0.71 | 29.49 | 49.00 | |
| Season 2 | W1 | 5.9 | 2380.80 | 1.94 | −13.81 | 11.03 | 36.52 | 3.91 | 0.71 | 18.69 | 48.36 |
| W2 | 5.9 | 2643.20 | 1.41 | −18.08 | 20.06 | 48.08 | 9.46 | 0.63 | 34.56 | 38.58 | |
| W3 | 6.2 | 960.00 | 1.89 | −5.89 | 7.52 | 39.39 | 2.18 | 0.77 | 9.33 | 43.52 | |
| W4 | 5.8 | 2572.80 | 1.35 | −17.73 | 18.90 | 45.83 | 6.00 | 0.76 | 30.07 | 47.44 | |
| Season 3 | W1 | 5.8 | 3161.60 | 1.36 | −14.79 | 33.19 | 60.42 | 7.23 | 0.89 | 39.71 | 46.91 |
| W2 | 5.7 | 3513.60 | 1.40 | −22.78 | 30.56 | 53.69 | 9.01 | 1.11 | 39.61 | 40.84 | |
| W3 | 5.9 | 1401.60 | 2.28 | −10.87 | 10.40 | 37.14 | 3.47 | 0.77 | 14.74 | 46.08 | |
| W4 | 5.9 | 3289.60 | 1.19 | −19.76 | 29.30 | 55.58 | 8.94 | 1.08 | 38.03 | 36.67 | |
| Season 4 | W1 | 5.7 | 3212.80 | 1.51 | −31.80 | 12.54 | 28.97 | 9.45 | 0.44 | 40.03 | 43.51 |
| W2 | 5.8 | 3315.20 | 1.28 | −34.26 | 12.46 | 29.02 | 11.81 | 0.54 | 38.69 | 47.61 | |
| W3 | 6.1 | 1427.20 | 1.73 | −13.32 | 8.38 | 32.15 | 5.60 | 0.62 | 15.85 | 46.48 | |
| W4 | 5.7 | 3193.60 | 1.45 | −26.80 | 17.61 | 38.21 | 7.16 | 0.78 | 35.66 | 40.78 | |
| Season 5 | W1 | 5.5 | 3142.40 | 1.61 | −34.75 | 9.56 | 21.95 | 4.76 | 0.55 | 33.45 | 47.95 |
| W2 | 5.4 | 3334.40 | 1.81 | −34.64 | 11.36 | 24.47 | 3.90 | 0.68 | 32.50 | 42.77 | |
| W3 | 6.2 | 979.20 | 1.62 | −6.68 | 8.64 | 39.74 | 2.27 | 0.98 | 9.09 | 44.25 | |
| W4 | 6.0 | 3174.40 | 1.01 | −34.64 | 10.51 | 26.90 | 18.41 | 0.47 | 38.47 | 48.13 | |
| Season 6 | W1 | 5.8 | 3065.60 | 1.38 | −29.66 | 14.08 | 33.15 | 9.71 | 0.64 | 34.43 | 46.41 |
| W2 | 6.1 | 3424.00 | 0.90 | −26.91 | 21.52 | 46.69 | 25.74 | 0.78 | 41.70 | 45.70 | |
| W3 | 6.4 | 1235.20 | 1.48 | −12.98 | 6.00 | 28.24 | 7.55 | 0.64 | 14.33 | 44.25 | |
| W4 | 5.9 | 3155.20 | 1.13 | −27.20 | 18.13 | 40.56 | 13.74 | 0.68 | 39.20 | 47.61 | |
| Min | 5.4 | 883.20 | 0.90 | −34.75 | 6.00 | 21.95 | 2.18 | 0.44 | 9.09 | 36.67 | |
| Max | 6.4 | 3513.6 | 2.28 | −5.10 | 33.19 | 60.42 | 25.74 | 1.11 | 41.70 | 49.00 | |
| Mean | 5.9 | 2506.13 | 1.48 | −20.23 | 15.49 | 39.90 | 8.13 | 0.73 | 28.51 | 44.38 | |
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Share and Cite
Al-Shihmani, L.S.S.; Al-Sarraji, A.J.; Al-Shammary, A.A.G.; Fernández-Gálvez, J.; Caballero-Calvo, A. Groundwater Quality Near Riverbanks and Its Suitability for Agricultural Use in Semi-Arid Regions. Appl. Sci. 2025, 15, 12338. https://doi.org/10.3390/app152212338
Al-Shihmani LSS, Al-Sarraji AJ, Al-Shammary AAG, Fernández-Gálvez J, Caballero-Calvo A. Groundwater Quality Near Riverbanks and Its Suitability for Agricultural Use in Semi-Arid Regions. Applied Sciences. 2025; 15(22):12338. https://doi.org/10.3390/app152212338
Chicago/Turabian StyleAl-Shihmani, Layth Saleem Salman, Ali Jawad Al-Sarraji, Ahmed Abed Gatea Al-Shammary, Jesús Fernández-Gálvez, and Andrés Caballero-Calvo. 2025. "Groundwater Quality Near Riverbanks and Its Suitability for Agricultural Use in Semi-Arid Regions" Applied Sciences 15, no. 22: 12338. https://doi.org/10.3390/app152212338
APA StyleAl-Shihmani, L. S. S., Al-Sarraji, A. J., Al-Shammary, A. A. G., Fernández-Gálvez, J., & Caballero-Calvo, A. (2025). Groundwater Quality Near Riverbanks and Its Suitability for Agricultural Use in Semi-Arid Regions. Applied Sciences, 15(22), 12338. https://doi.org/10.3390/app152212338

