Next Article in Journal
Evaluation Model of Rice Seedling Production Line Seeding Quality Based on Deep Learning
Next Article in Special Issue
Histological Bone-Healing Evaluation of Critical-Size Defects Filled with β-Tricalcium Phosphate in Rat Tibiae
Previous Article in Journal
Effects of the Agrivoltaic System on Crop Production: The Case of Tomato (Solanum lycopersicum L.)
Previous Article in Special Issue
The Effects of Systemic Vitamin D Level on the Healing of Different Graft Materials: An Experimental Histological Study
 
 
Search for Articles:
Title / Keyword
Author / Affiliation / Email
Journal
Article Type
 
 
Advanced Search
 
Section
Special Issue
Volume
Issue
Number
Page
 
Journals
Applied Sciences
Volume 14
Issue 7
10.3390/app14073096
applsci-logo
Submit to this Journal Review for this Journal Propose a Special Issue
► Article Menu

Article Menu

share Share announcement Help format_quote Cite question_answer Discuss in SciProfiles
first_page
settings
Order Article Reprints
Font Type:
Arial Georgia Verdana
Font Size:
Aa Aa Aa
Line Spacing:
Column Width:
Background:
Article

Surface Roughness of Polyetheretherketone Printed by Fused Deposition Modeling: A Pilot Study Investigating the Impact of Print Layer Thickness and Polishing Method

by
Tânia Soares
1,
Carlos Fernandes
2,3,*,
Cláudia Barbosa
4,5,
Mário A. P. Vaz
2,3,
Tiago Reis
4,5 and
Maria Helena Figueiral
1,2
1
Faculty of Dental Medicine, University of Porto, 4200-393 Porto, Portugal
2
Institute of Science and Innovation in Mechanical Engineering and Industrial Engineering (INEGI), 4200-465 Porto, Portugal
3
Faculty of Engineering, University of Porto, 4200-465 Porto, Portugal
4
Faculty of Health Sciences, University Fernando Pessoa, 4249-004 Porto, Portugal
5
FP-I3ID, Faculty of Health Sciences, University Fernando Pessoa, 4249-004 Porto, Portugal
*
Author to whom correspondence should be addressed.
Appl. Sci. 2024, 14(7), 3096; https://doi.org/10.3390/app14073096
Submission received: 7 March 2024 / Revised: 28 March 2024 / Accepted: 3 April 2024 / Published: 7 April 2024
(This article belongs to the Special Issue Advances in Oral Rehabilitation: Materials, Techniques and Clinical Applications)
Browse Figures
Review Reports Versions Notes

Abstract

Polyetheretherketone is a high-performance thermoplastic polymer that can be used in 3D printing by fused deposition modeling, and is a promising material for dental applications. Some printing parameters are sensitive and can influence the properties of the printed object. Thus, this work aims to evaluate the influence of the print layer thickness on the surface roughness of polyetheretherketone before and after polishing and to verify the effectiveness of the polishing method used, as well as to compare it with the results obtained using polymethyl methacrylate as the control group. Specimens with different impression layer thicknesses were printed with polyetheretherketone (Group A—0.1 mm and Group B—0.3 mm). Additionally, a control group with polymethyl methacrylate specimens was milled. Roughness evaluation was conducted using a contact profilometer after the specimens had been printed (before polishing). Then, silicon carbide sandpaper was used to polish the surface, and the roughness was reassessed. Differences were observed between specimens regarding the print layer thickness and the roughness, with the 0.3 mm layer thickness showing the lowest roughness values. The results of this pilot study suggest that the surface roughness of fused deposition modeling printed polyetheretherketone is influenced by print layer thickness, with the lowest roughness seen at a thickness of 0.3 mm.

1. Introduction

Polyetheretherketone (PEEK) is a semi-crystalline high-performance thermoplastic polymer developed by Imperial Chemical Industries in 1977. Due to its interesting mechanical and thermal properties, like modulus of elasticity, mechanical resistance, rigidity, and lightness, it has been considered an alternative to metals such as titanium and zirconium. Because this material has a modulus of elasticity and ultimate tensile stress similar to human bone, enamel, and dentin, it is suitable for use in dentistry, particularly in oral rehabilitation, for dental implants, removable prostheses, crowns, and fixed bridges [1,2,3,4,5,6,7]. Its glass transition point is approximately 143 °C, and its melting point is 343 °C [1,6,8,9,10]. Moreover, it allows good polishing, which promotes less bacterial plaque adhesion, and presents good wear resistance [2,11,12,13,14].
Initially, PEEK was processed using traditional casting methods, which were time-consuming and unsuitable for manufacturing small items. Later, through computer-aided design/computer-aided manufacturing (CAD/CAM) technology, PEEK disks were used to mill crowns, fixed partial dentures, removable prostheses, partial denture frameworks, obturating prostheses, and dental implants. However, low production rates, the excessive waste of grinding material, and an inability to produce more complicated and controlled architectures are the disadvantages of subtractive technology [15,16].
Fused deposition modeling (FDM) is a method in which layers of molten material are deposited from a filamentous nozzle and then solidified within 0.1 s [17]. This printing technique has become increasingly important, as it allows the construction of parts with complex geometries and is a more economical and simpler method due to using filament instead of powder [18]. Some authors refer to FDM as an alternative method to manufacture complex PEEK structures due to it being a low-cost, easy, and minimal-waste 3D printing technology. This technique overcomes some CAD/CAM milling problems and generates items more resistant to aging since PEEK filaments absorb less moisture than PEEK milling blocks [16]. Moreover, 3D printing in PEEK is an innovation in dentistry that allows for greater effectiveness and efficiency and is a quick and inexpensive process [9,19].
Several parameters can modify the outcome of FDM printing, influencing the mechanical behavior and properties of the devices, such as print layer thickness, print wire width, printing speed, extruder temperature and diameter, filament feed rate, viscosity, filament quality, and the printing routine itself. Therefore, initial tests are necessary to understand the ideal parameters for each filament [16,20,21,22]. The influence of FDM printing parameters on the printed PEEK parts’ dimensional stability and mechanical properties is attracting increasing interest in research. Moby et al. [16] concluded that the surface roughness of 3D FDM-printed PEEK seems suitable for dental restorations. However, information about the surface characteristics of FDM PEEK remains unclear [16,20,21,22].
Given the direct correlation between surface roughness and biofilm formation, polishing materials designed for use in the oral cavity becomes crucial. This step is essential for aesthetic reasons and also plays a significant role in minimizing bacterial plaque accumulation and enhancing resistance to the fluids present in the oral environment. A rough surface tends to suffer discoloration or pigmentation, increases bacterial accumulation, and may promote abrasion wear of opposing dental elements. Therefore, it is extremely important to evaluate the surface topography, roughness, hardness, and abrasion of materials that may be used in the oral cavity [23,24]. Kurahashi et al. [23] stated that humans can detect roughness values of at least 0.5 µm.
According to different authors, the print layer thickness is decisive for the printed parts’ surface roughness and dimensional accuracy [10,11,21,25]. Due to the layer-by-layer deposition printing process, the surfaces of objects made by 3D printing have inevitable irregularities.
Optimizing printing parameters to enhance the surface roughness of printed objects may lead to an extended printing time. Thus, the alternative is often to finish the surface after printing using techniques such as mechanical polishing [8,25,26]. This is a common surface processing method in dentistry to obtain a smooth surface. Heimer et al. [24] tested different polishing techniques on PEEK and polymethyl methacrylate (PMMA) samples and concluded that different material specimens were similarly polishable. It is worth mentioning that PMMA is a material widely used in the oral cavity and the gold standard in the manufacture of dentures and occlusal splints due to its mechanical proprieties, easy processing, repair techniques, and good polishing ability [5,27,28]. Its use as pre-formed blocks for milling is associated with lower porosity [29]. However, there is no consensus among authors on the best technique for polishing FDM PEEK or milled PMMA [21,30,31,32].
This study established two objectives. First, we aim to evaluate how the print layer thickness affects the surface roughness of FDM-printed PEEK before and after mechanical polishing. Additionally, we seek to assess the effectiveness of polishing PEEK with SiC sandpaper and compare it to PMMA polished with the same technique.

2. Materials and Methods

This research used a PEEK filament (Peek Ketaspire KT-820 NT Filament, Medphen, Madrid, Spain) for Class I Medical Devices (ISO 10993-1) [33]. Following the manufacturer’s instructions, the filament was dried in an oven at 150 °C (Vismec DW25, Moretec, Hoorn, The Netherlands) for 4 h before the printing process and after printing to prevent water absorption. An adhesive (Nano Polymer Adhesive, Vision Miner, Irvine, CA, USA) was applied on the surface of the print table to promote the adhesion of the specimens to the table and prevent the printed pieces from warping. Printing was performed on the FDM 3D printer AON-M2 (AON3D, Montreal, QC, Canada), on which initial tests were carried out to assess the technical parameters (printing path, printing speed, print layer thickness, extruder temperature), as recommended by the manufacturer. The final specimens and the stabilization gutter prototype were printed with the printer-adjusted parameters summarized in Table 1. The selected printing path is shown in Figure 1.
The specimens (10 mm × 10 mm × 1.5 mm) were designed using the software Solidworks (Version 2021) (Dassault Systèmes Solidworks Corporation, Waltham, MA, USA). Four specimens were printed—two specimens (A1 and A2) with 0.1 mm and two specimens (B1 and B2) with 0.3 mm of print layer thickness—to evaluate whether changing this parameter modifies the specimen’s surface roughness. The surface roughness of all specimens was assessed after the printing process without any surface finishing. Subsequently, these specimens were polished with a series of silicon carbide (SiC) sandpapers of increasing grain (P80, P180, P320, P800, P1200, and P4000, Struers, Ballerup, Denmark) [18,34,35,36]. For this procedure, the specimens were first placed in a support material (Polyvinyl Siloxane, Aquasil Ultra, Dentsply Sirona, Charlotte, NC, USA) (Figure 2) to allow safe and uniform polishing. The polishers (Rotopol-21, Struers, Denmark) were used with tap water lubrication at 300 rotations per minute (rpm) for 60 s (Figure 3). After this procedure, the specimens’ roughness was measured again.
The control group for comparison consisted of 3 specimens produced in PMMA (Aidite Temp, Aidite Technology Co, Qinhuangdao, China). Another STL file was created using computer software (Exocad DentalCAD, Exocad GmbH, Darmstadt, Germany) for specimens with the same dimensions as the PEEK specimens (10 × 10 × 1.5 mm). These PMMA specimens were then milled (DWX-52D, Roland DGA Corporation, Irvine, CA, USA). After milling, different surface treatments were carried out on these specimens: one specimen was left unfinished (P1), another was polished with the SiC sandpaper used for the PEEK specimens (P2), and another was subjected to a conventional finish with polishing drills and diamond paste (P3). Then, their roughness was evaluated.
A Hommelwerke T8000 controller with an LV-50 linear unit (Hommelwerke GmbH, Villingen-Schwenningen, Germany) was employed to obtain the specimens’ surface topography (see Figure 4a). A TKL 300 pickup was used as the stylus probe, with a vertical measurement range of ±300 µm, a tip radius of 5 µm, and a cone angle of 90 degrees. A support structure was created in polylactic acid (PLA) using the FDM 3D printer to fix the specimens in place securely, ensuring accurate and repeatable readings from the stylus profilometer (see Figure 4b). A 7.5 mm × 3 mm evaluation area was defined on each specimen with a resolution of 1 µm × 10 µm. The 7.5 mm dimension was perpendicular to the printing direction, where higher roughness is expected. The topographies were subjected to a form removal (plane tilt) and a cut-off filter of 0.8 mm. The specimens’ areal surface roughness parameters were determined per ISO 25178-2 to calculate the arithmetic mean of the surface height (Sa). Also, a profile was extracted perpendicularly to the printing direction, and the arithmetic mean roughness (Ra) was calculated according to ISO 4287, as well as the maximum height from the highest peak and the deepest valley (St). Data analysis was performed using Microsoft Excel (Version 2402) software (Microsoft, Microsoft Corporation, Redmond, WA, USA).

3. Results

The surface topography of the two specimens (A1 and A2) with 0.1 mm and the two specimens (B1 and B2) with 0.3 mm of print layer thickness was assessed (1) after printing without any surface finishing (before polishing assessment) and (2) after polishing with SiC sandpaper (Figure 5).
In the first analysis, specimen B1’s roughness was higher than the profilometer tip’s measurement range (approximately 300 µm), making it impossible to measure. A considerable difference was observed in the surface roughness of the specimens in the two evaluation moments, and, as expected, all specimens showed higher surface roughness in the first measurement (Table 2). After the polishing procedures, Ra, Sa, and St decreased significantly in each specimen.
Regarding the comparison between specimens with the same print layer thickness, it was not possible to compare B1 and B2 before polishing. However, all other comparisons (A1 with A2, before and after polishing, and B1 with B2 after polishing) showed very close values in the evaluated parameters, both before and after final polishing (Table 2).
Because the specimens differed in their printing characteristics—specifically, the print layer thickness—they were grouped according to this characteristic to calculate average roughness parameters (Table 3). Comparing the average values of Ra, Sa, and St of the two groups at each of the moments of roughness evaluation showed that the groups tended to differ. Group A always had a rougher surface than Group B (0.98 µm and 0.33 µm, respectively, before polishing), although this difference tended to be smaller after polishing (0.11 µm and 0.04 µm, respectively) (see Figure 6 and Table 3).
Regarding the PMMA specimens (P1, P2, and P3), surface topography was carried out on all specimens (Figure 7), and the parameters Sa, Ra, and St were assessed. A considerable difference was observed in the surface roughness between the unpolished and polished specimens. However, the specimens’ surface roughness was similar in the different polishing steps applied, as shown in Table 4.
When comparing the PEEK specimens with the PMMA specimens, although the PEEK specimens had higher roughness before polishing, after polishing with SiC sandpaper, the PEEK specimens had equal or lower roughness than the PMMA specimen under the same conditions (Table 5).

4. Discussion

The aims of this study were (1) to determine how print layer thickness affected the surface roughness of FDM PEEK before and after mechanical polishing; and (2) to assess the effectiveness of polishing PEEK with SiC sandpaper and compare it to polishing PMMA with the same technique. This study demonstrated that printing PEEK specimens with a 0.3 mm print layer thickness produced inferior surface roughness both before and after SiC sandpaper polishing. When compared to the gold standard (PMMA), after polishing, the PEEK specimens had the same roughness in Group A (0.1 mm impression layer thickness) and lower roughness in Group B (0.3 mm impression layer thickness).
The advantages of 3D FDM printing include minimal time to produce items, a limited amount of material, and low cost. However, it has two disadvantages: (1) the need for postprocessing treatment to remove the support structures and polish the surface, and (2) a variable behavior because the printing conditions, such as nozzle temperature, chamber temperature, printing speed, and print layer thickness, directly affect the characteristics of printed objects [19,37]. Limaye et al. [22] reported that PEEK printing is technically complex compared to other thermoplastic materials melted at low temperatures. These authors performed a scanning electron microscope analysis of FDM-engineered PEEK samples and found irregularities created by material dragging by the nozzle during print. Optimizing printing parameters is crucial for controlling the mechanical properties of printed PEEK parts [22].
According to Wu et al. [14] and Li et al. [16], the print layer thickness is the parameter with the greatest influence on some mechanical properties of the printed structure. They claim that increasing the print layer thickness reduces the printed part’s geometry precision and contour perfection and showed optimal mechanical properties in PEEK in samples produced with a layer thickness of 0.3 mm [14]. Some authors recommend a print layer thickness of 0.1 mm to reduce internal defects and improve the surface finish [21]. The print layer thickness seems to be a printing parameter that significantly affects the structure roughness. According to various authors, these two properties are directly related, because a decrease in print layer thickness generally causes a decrease in surface roughness [8,21,25,38]. The authors attribute these surface roughness results to the interlayer gaps caused by the FDM printing [38]. The results of the present study contradict those of the authors mentioned above [8,21,25,38] since the specimens with the highest roughness had the lowest print layer thickness (0.1 mm). Nonetheless, as mentioned previously, other printing conditions, such as nozzle temperature, chamber temperature, and printing speed, directly affect the characteristics of printed objects and may explain the difference between the present study and previous ones. Another hypothesis that could be raised is the utilization of multiple brands of PEEK across these studies and on different printers. This variation in materials and printing methods may have influenced the behavior observed, potentially contributing to the disparity in the results. The printing conditions should be described and protocolized to enable a comparison with future studies’ results.
Defining an optimal polishing technique for PEEK is important because, regardless of the print layer thickness, mechanical finishing decreases surface roughness and can promote smooth and soft surfaces.
The maximum roughness of hard surfaces within the oral cavity after polishing, as indicated by several authors [23,24,39,40,41,42], should not exceed 2 µm, which represents the threshold for bacterial plaque accumulation. Nevertheless, alternative studies suggest that a clinically acceptable limit could be set at 10 µm [40,43].
Some authors state that assessing roughness using a contact-type roughness measuring device, such as the one used in this work, is not ideal due to the risk of damaging the sample surface [21]. However, Elawadly et al. [44] chose to evaluate roughness (Ra) using this method because the color of the PEEK samples causes inadequate light reflection, making the use of optical interferometry difficult. These authors considered this method effective due to promoting direct contact between the measuring tip and the sample surface. In the present study, the contact-type roughness measuring device was also used because the same difficulty was encountered when reading PEEK using optical interferometry. Other authors employ different approaches because there is no universal method for treating PEEK’s surface.
Several investigations report different values when polishing milled PEEK with SiC sandpaper, namely, Keul et al. [45] (P500 to P2400) found Ra = 0.04 µm, Çulhaoglu et al. [45] (P1200) Ra = 0.53 µm, and Caglar et al. [45] (P600 and P800) Ra = 1.11 µm. A direct comparison cannot be made since no publication was found describing the same sequence of SiC sandpapers used in this work (P80, P180, P320, P800, P1200, and P4000) for FDM PEEK. Even so, given that lower roughness values were obtained with the method used (Ra between 0.04 µm and 0.11 µm), it is suggested that polishing FDM PEEK with SiC sandpaper of different grain sizes could be an effective technique.
Han et al. [18] conducted a study where the surface morphology of printed PEEK samples was determined. The authors evaluated both samples with three different surface treatments: (1) no polishing, (2) mechanical polishing (SiC sandpaper), and (3) sandblasting (120 µm alumina). As expected, the untreated specimens had the roughest surfaces (Sa = 17.67 µm), and the polished specimens had the smoothest surfaces (Sa = 0.42 µm). The same trend was observed in the present study, as the samples with and without polishing differed in surface roughness. However, although the initial roughness values of Group A agree with the results of Han et al. [18] (Sa before polishing in Group A = 17.65 µm), the initial roughness of the Group B samples was much lower (Sa before polishing in Group B = 6.51 µm). After polishing, both groups had lower roughness than that reported by those authors (final Sa of Group A = 0.17 µm and final Sa of Group B = 0.09 µm). Thus, the polishing technique used in the present work seems to be more effective, since the specimens from Group A, which had an initial roughness close to that described by Han et al. [18], showed a lower roughness after polishing than that reported by those authors.
The same was verified in the work of Gao et al. [21], which also analyzed the surface roughness of FDM PEEK specimens. They obtained Ra values of 0.61 to 0.66µm before polishing and Ra values of 0.10 to 0.15 µm after polishing the specimens. The present study obtained lower roughness results after polishing (Ra = 0.04 and 0.11 µm), probably due to using a different polishing technique, although this cannot be confirmed as Gao et al. [21] did not mention the polishing protocol used. Thus, it can be assumed that the polishing method employed, involving P80, P180, P320, P800, P1200, and P4000 SiC sandpapers, seems to be suitable for rendering FDM PEEK clinically usable.
Kurahashi et al. [23] state that humans can detect roughness values of at least 0.5 µm. In fact, in this work, the specimens’ roughness was within that limit (Ra = 0.04 µm and 0.12 µm). In addition, as already mentioned, the roughness limit for plaque accumulation in restorations inserted in the oral cavity should not be greater than 2 µm [23,24,31,40,42,45,46,47], so since the results obtained were lower than this value, there was no need to add another polishing method to the specimens’ surface.
The roughness analysis of the PMMA specimens was aimed at comparison with the PEEK specimens, as PMMA is a gold-standard material in prosthodontics. PMMA had lower roughness values than PEEK for unpolished specimens (PMMA Ra = 0.26 µm; PEEK Ra = 0.33 µm and 0.98 µm), but the same Ra as PEEK specimens with a 0.1 mm print layer thickness after polishing with SiC sandpaper (PMMA Ra = 0.11 µm; PEEK Ra = 0.11 µm). The lowest roughness was found in PEEK specimens with a 0.3 mm impression layer after polishing with sandpaper (Ra = 0.04 µm). Therefore, although PEEK after FDM printing has a rough surface, finishing it with SiC sandpaper reduces roughness to values close to, or even lower than, the roughness values of the gold-standard material and at a clinically acceptable level for use in the oral cavity (Ra < 0.2 µm). However, the studies that report techniques for polishing milled PMMA [31,32] with SiC sandpaper (until P1200) present an Ra between 0.19 µm–0.35 µm, corroborating the idea that the polishing method used in this study is also clinically suitable for milled PMMA.
Since the present study is a pilot study, the sample size and the flat geometry of the printed parts are its main limitations. Future studies with larger sample sizes are needed to corroborate the present findings. Also, different geometries, such as removable prostheses, fixed provisional prostheses, and occlusal splints, should be tested to simulate clinical situations and demonstrate whether the polishing method is effective in these geometries.

5. Conclusions

The results suggest a relationship between the print layer thickness and the surface roughness of the FDM PEEK specimens, with the 0.3 mm layer thickness showing the lowest roughness. They also revealed that mechanical finishing with a series of SiC sandpapers of increasing grit (P80, P180, P320, P800, P1200, and P4000) effectively reduced the specimens’ surface roughness.
Future research, with larger samples, should investigate how to optimize the printing process to minimize the roughness of the printed specimens and, consequently, decrease the need for mechanical surface finishing after printing.

Author Contributions

Conceptualization, T.S., C.F. and C.B. methodology, C.F. and C.B.; software, C.F.; validation, C.B. and M.H.F.; formal analysis, M.H.F., C.B. and T.R.; investigation, T.S.; resources, C.F. and M.A.P.V.; data curation, T.S., C.F., C.B. and T.R.; writing—T.S. and T.R.; writing—review and editing, T.S., M.H.F., C.B. and M.A.P.V.; visualization, M.H.F., C.B. and M.A.P.V.; supervision, M.A.P.V.; project administration, T.R.; funding acquisition, C.F. and M.A.P.V. All authors have read and agreed to the published version of the manuscript.

Funding

This research received no external funding.

Data Availability Statement

Data are contained within the article.

Acknowledgments

The authors thank those who voluntarily helped in the 3D printing and polishing of the specimens, namely, Bruna Oliveira of INEGI’s Product Development Engineer Department and Emília Soares of the FEUP’s materiolography laboratory. Carlos Fernandes is grateful for the funding through LAETA, Portugal, in the framework of project UID/50022/2020.

Conflicts of Interest

The authors declare no conflicts of interest.

References

  1. Czyzewski, W.; Jachimczyk, J.; Hoffman, Z.; Szymoniuk, M.; Litak, J.; Maciejewski, M.; Kura, K.; Rola, R.; Torres, K. Low-Cost Cranioplasty-A Systematic Review of 3D Printing in Medicine. Materials 2022, 15, 4731. [Google Scholar] [CrossRef] [PubMed]
  2. Papathanasiou, I.; Kamposiora, P.; Papavasiliou, G.; Ferrari, M. The use of PEEK in digital prosthodontics: A narrative review. BMC Oral Health 2020, 20, 217. [Google Scholar] [CrossRef] [PubMed]
  3. Elfahl, B.N.; Mostafa, T.M.N. Polyetheretherketone custom CAD-CAM splint for treatment of periodontally affected mobile anterior teeth. J. Prosthet. Dent. 2020, 127, 210–212. [Google Scholar] [CrossRef] [PubMed]
  4. Skirbutis, G.; Dzingute, A.; Masiliunaite, V.; Sulcaite, G.; Zilinskas, J. A review of PEEK polymer’s properties and its use in prosthodontics. Stomatol. Balt. Dent. Maxillofac. J. 2017, 19, 19–23. [Google Scholar]
  5. Shrivastava, S.P.; Dable, R.; Nirmal Raj, A.P.; Mutneja, P.; Srivastava, S.B.; Haque, M. Comparison of Mechanical Properties of PEEK and PMMA: An In Vitro Study. J. Contemp. Dent. Pract. 2021, 22, 179–183. [Google Scholar] [CrossRef] [PubMed]
  6. Luo, C.; Liu, Y.; Peng, B.; Chen, M.; Liu, Z.; Li, Z.; Kuang, H.; Gong, B.; Li, Z.; Sun, H. PEEK for Oral Applications: Recent Advances in Mechanical and Adhesive Properties. Polymers 2023, 15, 386. [Google Scholar] [CrossRef]
  7. Najeeb, S.; Zafar, M.S.; Khurshid, Z.; Siddiqui, F. Applications of polyetheretherketone (PEEK) in oral implantology and prosthodontics. J. Prosthodont. Res. 2016, 60, 12–19. [Google Scholar] [CrossRef] [PubMed]
  8. Schonhoff, L.M.; Mayinger, F.; Eichberger, M.; Reznikova, E.; Stawarczyk, B. 3D printing of dental restorations: Mechanical properties of thermoplastic polymer materials. J. Mech. Behav. Biomed. Mater. 2021, 119, 104544. [Google Scholar] [CrossRef]
  9. Haleem, A.; Javaid, M. Polyether ether ketone (PEEK) and its manufacturing of customised 3D printed dentistry parts using additive manufacturing. Clin. Epidemiol. Glob. Health 2019, 7, 654–660. [Google Scholar] [CrossRef]
  10. Li, H.; Xiao, X.; Liao, W.; Liu, T.; Li, G. Numerical Simulation and Experimental Study Regarding the Cross-Sectional Morphology of PEEK Monofilament Deposition During FDM-Based 3D Printing. Langmuir 2023, 39, 13287–13295. [Google Scholar] [CrossRef]
  11. Wang, Y.; Muller, W.D.; Rumjahn, A.; Schwitalla, A. Parameters Influencing the Outcome of Additive Manufacturing of Tiny Medical Devices Based on PEEK. Materials 2020, 13, 466. [Google Scholar] [CrossRef] [PubMed]
  12. Wang, S.; Li, Z.; Ye, H.; Zhao, W.; Liu, Y.; Zhou, Y. Preliminary clinical evaluation of traditional and a new digital PEEK occlusal splints for the management of sleep bruxism. J. Oral. Rehabil. 2020, 47, 1530–1537. [Google Scholar] [CrossRef]
  13. Bathala, L.; Majeti, V.; Rachuri, N.; Singh, N.; Gedela, S. The Role of Polyether Ether Ketone (Peek) in Dentistry—A Review. J. Med. Life 2019, 12, 5–9. [Google Scholar] [CrossRef] [PubMed]
  14. Wu, W.; Geng, P.; Li, G.; Zhao, D.; Zhang, H.; Zhao, J. Influence of Layer Thickness and Raster Angle on the Mechanical Properties of 3D-Printed PEEK and a Comparative Mechanical Study between PEEK and ABS. Materials 2015, 8, 5834–5846. [Google Scholar] [CrossRef] [PubMed]
  15. Chen, X.; Wang, F.; Sun, F.; Zhang, L.; Wu, G. Digital fabrication of an adult speech aid prosthesis by using a 3-dimensionally printed polyetheretherketone framework. J. Prosthet. Dent. 2022, 127, 358–361. [Google Scholar] [CrossRef] [PubMed]
  16. Moby, V.; Dupagne, L.; Fouquet, V.; Attal, J.P.; Francois, P.; Dursun, E. Mechanical Properties of Fused Deposition Modeling of Polyetheretherketone (PEEK) and Interest for Dental Restorations: A Systematic Review. Materials 2022, 15, 6801. [Google Scholar] [CrossRef] [PubMed]
  17. Kessler, A.; Hickel, R.; Reymus, M. 3D Printing in Dentistry-State of the Art. Oper. Dent. 2020, 45, 30–40. [Google Scholar] [CrossRef]
  18. Han, X.; Yang, D.; Yang, C.; Spintzyk, S.; Scheideler, L.; Li, P.; Li, D.; Geis-Gerstorfer, J.; Rupp, F. Carbon Fiber Reinforced PEEK Composites Based on 3D-Printing Technology for Orthopedic and Dental Applications. J. Clin. Med. 2019, 8, 240. [Google Scholar] [CrossRef]
  19. Baek, I.; Kwon, O.; Lim, C.M.; Park, K.Y.; Bae, C.J. 3D PEEK Objects Fabricated by Fused Filament Fabrication (FFF). Materials 2022, 15, 898. [Google Scholar] [CrossRef]
  20. Rodzeń, K.; Harkin-Jones, E.; Wegrzyn, M.; Sharma, P.K.; Zhigunov, A. Improvement of the layer-layer adhesion in FFF 3D printed PEEK/carbon fibre composites. Compos. Part A Appl. Sci. Manuf. 2021, 149, 106532. [Google Scholar] [CrossRef]
  21. Gao, S.; Liu, R.; Xin, H.; Liang, H.; Wang, Y.; Jia, J. The Surface Characteristics, Microstructure and Mechanical Properties of PEEK Printed by Fused Deposition Modeling with Different Raster Angles. Polymers 2021, 14, 77. [Google Scholar] [CrossRef] [PubMed]
  22. Limaye, N.; Veschini, L.; Coward, T. Assessing biocompatibility & mechanical testing of 3D-printed PEEK versus milled PEEK. Heliyon 2022, 8, e12314. [Google Scholar] [CrossRef]
  23. Kurahashi, K.; Matsuda, T.; Ishida, Y.; Ichikawa, T. Effect of polishing protocols on the surface roughness of polyetheretherketone. J. Oral Sci. 2020, 62, 40–42. [Google Scholar] [CrossRef] [PubMed]
  24. Heimer, S.; Schmidlin, P.R.; Roos, M.; Stawarczyk, B. Surface properties of polyetheretherketone after different laboratory and chairside polishing protocols. J. Prosthet. Dent. 2017, 117, 419–425. [Google Scholar] [CrossRef] [PubMed]
  25. Guo, C.; Liu, X.; Liu, G. Surface Finishing of FDM-Fabricated Amorphous Polyetheretherketone and Its Carbon-Fiber-Reinforced Composite by Dry Milling. Polymers 2021, 13, 2175. [Google Scholar] [CrossRef] [PubMed]
  26. Turner, B.N.; Gold, S.A. A review of melt extrusion additive manufacturing processes: II. Materials, dimensional accuracy, and surface roughness. Rapid Prototyp. J. 2015, 21, 250–261. [Google Scholar] [CrossRef]
  27. Grymak, A.; Waddell, J.N.; Aarts, J.M.; Ma, S.; Choi, J.J.E. Evaluation of wear behaviour of various occlusal splint materials and manufacturing processes. J. Mech. Behav. Biomed. Mater. 2022, 126, 105053. [Google Scholar] [CrossRef]
  28. Perea-Lowery, L.; Vallittu, P.K. Resin adjustment of three-dimensional printed thermoset occlusal splints: Bonding properties—Short communication. J. Mech. Behav. Biomed. Mater. 2019, 95, 215–219. [Google Scholar] [CrossRef] [PubMed]
  29. Gibreel, M.; Perea-Lowery, L.; Vallittu, P.K.; Lassila, L. Characterization of occlusal splint materials: CAD-CAM versus conventional resins. J. Mech. Behav. Biomed. Mater. 2021, 124, 104813. [Google Scholar] [CrossRef]
  30. Quezada, M.M.; Salgado, H.; Correia, A.; Fernandes, C.; Fonseca, P. Investigation of the Effect of the Same Polishing Protocol on the Surface Roughness of Denture Base Acrylic Resins. Biomedicines 2022, 10, 1971. [Google Scholar] [CrossRef]
  31. Tasin, S.; Ismatullaev, A.; Usumez, A. Comparison of surface roughness and color stainability of 3-dimensionally printed interim prosthodontic material with conventionally fabricated and CAD-CAM milled materials. J. Prosthet. Dent. 2022, 128, 1094–1101. [Google Scholar] [CrossRef] [PubMed]
  32. Myagmar, G.; Lee, J.H.; Ahn, J.S.; Yeo, I.L.; Yoon, H.I.; Han, J.S. Wear of 3D printed and CAD/CAM milled interim resin materials after chewing simulation. J. Adv. Prosthodont. 2021, 13, 144–151. [Google Scholar] [CrossRef] [PubMed]
  33. FILAMENT2PRINT. Available online: https://filament2print.com/pt/avancados/1794-peek-ketaspire.html (accessed on 7 February 2024).
  34. Ozdogan, A.; Tosun, B. Effects of Different Polishing Procedures on the Surface Roughness and Hardness of Polyether Ether Ketone (PEEK). Odovtos—Int. J. Dent. Sci. 2020, 23, 219–227. [Google Scholar] [CrossRef]
  35. Stawarczyk, B.; Beuer, F.; Wimmer, T.; Jahn, D.; Sener, B.; Roos, M.; Schmidlin, P.R. Polyetheretherketone-a suitable material for fixed dental prostheses? J. Biomed. Mater. Res. B Appl. Biomater. 2013, 101, 1209–1216. [Google Scholar] [CrossRef]
  36. Culhaoglu, A.K.; Ozkir, S.E.; Sahin, V.; Yilmaz, B.; Kilicarslan, M.A. Effect of Various Treatment Modalities on Surface Characteristics and Shear Bond Strengths of Polyetheretherketone-Based Core Materials. J. Prosthodont. 2020, 29, 136–141. [Google Scholar] [CrossRef] [PubMed]
  37. Prechtel, A.; Stawarczyk, B.; Hickel, R.; Edelhoff, D.; Reymus, M. Fracture load of 3D printed PEEK inlays compared with milled ones, direct resin composite fillings, and sound teeth. Clin. Oral Investig. 2020, 24, 3457–3466. [Google Scholar] [CrossRef] [PubMed]
  38. Wang, P.; Zou, B.; Xiao, H.; Ding, S.; Huang, C. Effects of printing parameters of fused deposition modeling on mechanical properties, surface quality, and microstructure of PEEK. J. Mater. Process. Technol. 2019, 271, 62–74. [Google Scholar] [CrossRef]
  39. Erdağ, Ü.H.; Şahin, O.; Köroğlu, A.; Özdemir, T.; Dede, D.Ö. Performance of polyether ether ketone (peek) for dental applications: Surface roughness and color stability. Polym. Bull. 2022, 80, 6819–6834. [Google Scholar] [CrossRef]
  40. Koroglu, A.; Sahin, O.; Dede, D.O.; Yilmaz, B. Effect of different surface treatment methods on the surface roughness and color stability of interim prosthodontic materials. J. Prosthet. Dent. 2016, 115, 447–455. [Google Scholar] [CrossRef]
  41. Bollen, C.M.; Papaioanno, W.; Van Eldere, J.; Schepers, E.; Quirynen, M.; van Steenberghe, D. The influence of abutment surface roughness on plaque accumulation and peri-implant mucositis. Clin. Oral Implant. Res. 1996, 7, 201–211. [Google Scholar] [CrossRef]
  42. Alp, G.; Johnston, W.M.; Yilmaz, B. Optical properties and surface roughness of prepolymerized poly(methyl methacrylate) denture base materials. J. Prosthet. Dent. 2019, 121, 347–352. [Google Scholar] [CrossRef] [PubMed]
  43. Kaplan, B.; Goldstein, G.; Vijayaraghavan, T.; Nelson, I. The effect of three polishing systems on the surface roughness of four hybrid composites: A profilometric and scanning electron microscopy study. J. Prosthet. Dent. 1996, 76, 34–38. [Google Scholar] [CrossRef] [PubMed]
  44. Elawadly, T.; Radi, I.A.W.; El Khadem, A.; Osman, R.B. Can PEEK Be an Implant Material? Evaluation of Surface Topography and Wettability of Filled Versus Unfilled PEEK With Different Surface Roughness. J. Oral Implantol. 2017, 43, 456–461. [Google Scholar] [CrossRef] [PubMed]
  45. Batak, B.; Cakmak, G.; Johnston, W.M.; Yilmaz, B. Surface roughness of high-performance polymers used for fixed implant-supported prostheses. J. Prosthet. Dent. 2021, 126, 254.e1. [Google Scholar] [CrossRef] [PubMed]
  46. Kuhar, M.; Funduk, N. Effects of polishing techniques on the surface roughness of acrylic denture base resins. J. Prosthet. Dent. 2005, 93, 76–85. [Google Scholar] [CrossRef]
  47. Cakmak, G.; Donmez, M.B.; Atalay, S.; de Paula, M.S.; Fonseca, M.; Schimmel, M.; Yilmaz, B. Surface roughness and stainability of CAD-CAM denture base materials after simulated brushing and coffee thermocycling. J. Prosthet. Dent. 2022. online ahead of print. [Google Scholar] [CrossRef]
Applsci 14 03096 g001
Figure 1. Printing path.
Figure 1. Printing path.
Applsci 14 03096 g001
Applsci 14 03096 g002
Figure 2. Packing the specimens in the support to perform their polishing.
Figure 2. Packing the specimens in the support to perform their polishing.
Applsci 14 03096 g002
Applsci 14 03096 g003
Figure 3. (a) Polishers (Rotopol-21, Struers, Denmark). (b) Polishing of a specimen.
Figure 3. (a) Polishers (Rotopol-21, Struers, Denmark). (b) Polishing of a specimen.
Applsci 14 03096 g003
Applsci 14 03096 g004
Figure 4. (a) Stylus probe profilometer (Hommelwerke GmbH, Germany). (b) Support for fixing the specimens for the surface topography reading.
Figure 4. (a) Stylus probe profilometer (Hommelwerke GmbH, Germany). (b) Support for fixing the specimens for the surface topography reading.
Applsci 14 03096 g004
Applsci 14 03096 g005
Figure 5. Surface topography of the specimens without any surface finishing (a–c) and after polishing with SiC sandpaper (d–g).
Figure 5. Surface topography of the specimens without any surface finishing (a–c) and after polishing with SiC sandpaper (d–g).
Applsci 14 03096 g005
Applsci 14 03096 g006
Figure 6. Difference between average Ra (a) and average Sa (b) of Groups A and B.
Figure 6. Difference between average Ra (a) and average Sa (b) of Groups A and B.
Applsci 14 03096 g006
Applsci 14 03096 g007
Figure 7. Three-dimensional image of the surface roughness of PMMA specimens P1, P2, and P3.
Figure 7. Three-dimensional image of the surface roughness of PMMA specimens P1, P2, and P3.
Applsci 14 03096 g007
Table 1. Printing parameters used.
Table 1. Printing parameters used.
ParametersTechnical Specifications
Extruder diameter0.6 mm
Printing layer thickness0.1 mm or 0.3 mm
Print speed10 mm/s
Printing table temperature160 °C
Chamber temperature100 °C
Extruder temperature380 °C
Table 2. Roughness parameters before and after polishing for each specimen.
Table 2. Roughness parameters before and after polishing for each specimen.
SpecimensRoughness ParametersBefore Polishing (μm)After Polishing (μm)
A1Sa17.30.19
Ra0.910.12
St1247.64
A2Sa180.15
Ra1.050.09
St12310.2
B1Sa 0.09
Ra 0.05
St 26
B2Sa6.510.1
Ra0.330.05
St11827.5
Table 3. Averages (Ra and Sa) before and after polishing for Groups A and B.
Table 3. Averages (Ra and Sa) before and after polishing for Groups A and B.
GroupGroup Average Ra (μm)Group Average Sa (μm)
Before polishingAfter polishingBefore polishingAfter polishing
A (A1 and A2)0.980.1117.650.17
B (B1 and B2)0.330.056.510.09
Table 4. Roughness test results for each PMMA specimen—Ra, Sa, and St.
Table 4. Roughness test results for each PMMA specimen—Ra, Sa, and St.
SpecimensP1
(Unfinished Specimen)		P2
Polished with SiC Sandpaper)		P3
(Conventional Finish)
Roughness ParametersSa0.740.40.49
Ra0.260.110.11
St9.757.686.62
Table 5. Arithmetic mean roughness (Ra) before and after polishing PEEK and PMMA specimens.
Table 5. Arithmetic mean roughness (Ra) before and after polishing PEEK and PMMA specimens.
SpecimensArithmetic Mean Roughness (Ra) before Polishing ± SD (μm)Arithmetic Mean Roughness (Ra) after Polishing ± SD (μm)
PEEK—Group A0.98 ± 0.070.11 ± 0.02
PEEK—Group B0.33 ± *0.04 ± 0
PMMA0.26 ± *0.11 ± *
SD—standard deviation; * Not possible to calculate standard deviation because there is only one specimen.
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.

Share and Cite

MDPI and ACS Style

Soares, T.; Fernandes, C.; Barbosa, C.; Vaz, M.A.P.; Reis, T.; Figueiral, M.H. Surface Roughness of Polyetheretherketone Printed by Fused Deposition Modeling: A Pilot Study Investigating the Impact of Print Layer Thickness and Polishing Method. Appl. Sci. 2024, 14, 3096. https://doi.org/10.3390/app14073096

AMA Style

Soares T, Fernandes C, Barbosa C, Vaz MAP, Reis T, Figueiral MH. Surface Roughness of Polyetheretherketone Printed by Fused Deposition Modeling: A Pilot Study Investigating the Impact of Print Layer Thickness and Polishing Method. Applied Sciences. 2024; 14(7):3096. https://doi.org/10.3390/app14073096

Chicago/Turabian Style

Soares, Tânia, Carlos Fernandes, Cláudia Barbosa, Mário A. P. Vaz, Tiago Reis, and Maria Helena Figueiral. 2024. "Surface Roughness of Polyetheretherketone Printed by Fused Deposition Modeling: A Pilot Study Investigating the Impact of Print Layer Thickness and Polishing Method" Applied Sciences 14, no. 7: 3096. https://doi.org/10.3390/app14073096

APA Style

Soares, T., Fernandes, C., Barbosa, C., Vaz, M. A. P., Reis, T., & Figueiral, M. H. (2024). Surface Roughness of Polyetheretherketone Printed by Fused Deposition Modeling: A Pilot Study Investigating the Impact of Print Layer Thickness and Polishing Method. Applied Sciences, 14(7), 3096. https://doi.org/10.3390/app14073096

Note that from the first issue of 2016, this journal uses article numbers instead of page numbers. See further details here.

Article Metrics

Back to TopTop