Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Synthesis of Sol–Gel Silica Materials
2.3. Characterization of the Sol–Gel Silica Materials and of Thin Films
2.3.1. Photopolymerization
2.3.2. Fourier-Transform Infrared Spectroscopy (FTIR)
2.3.3. Thermogravimetric Analysis (TGA)
2.3.4. Transmission Electron Microscopy (TEM)
2.3.5. UV/Vis Spectroscopy
2.3.6. Atomic Force Microscopy (AFM)
2.3.7. Spectroscopic Ellipsometry (SE) Measurements
2.3.8. Contact-Angle (CA) Measurements
3. Results and Discussion
3.1. FTIR Spectroscopy
3.2. Thermogravimetric Analysis (TGA)
3.3. TEM Analysis
3.4. UV/Vis Spectroscopy
3.5. AFM Analysis and Spectroscopic Ellipsometry (SE) Measurements
3.6. Contact-Angle Measurements
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Conflicts of Interest
References
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Alkoxysilane | Structure | Molecular Formula | Mw (g·mol−1) |
---|---|---|---|
TEOS | | C8H20O4Si | 208.33 |
DMVES | | C6H14OSi | 130.26 |
OTES | | C14H32O3Si | 276.48 |
HDTMES | | C19H42O3Si | 346.63 |
Sample | TEOS (mL) | DMVES (mL) | OTES (mL) | HDTMES (mL) |
---|---|---|---|---|
A | 4.2 | 1.52 | 2.9 | - |
B | 4.2 | 1.52 | - | 0.7 |
Sample | 30–105 °C | 105–350 °C | 350–700 °C | Residue at 700 °C | ||
---|---|---|---|---|---|---|
wt. loss % | wt. loss % | Tmax 1 °C | wt. loss % | Tmax °C | N2% | |
A | 1.50 | 5.58 | 272.8 | 29.75 | 488.4 | 63.17 |
B | 2.42 | 7.37 | 239.5 | 22.18 | 485.4 | 68.04 |
Sample | Film Thickness (nm) | Roughness (nm) | MSE |
---|---|---|---|
A | 426.96 | 2.90 | 0.89 |
B | 513.91 | 6.63 | 0.70 |
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Purcar, V.; Rădițoiu, V.; Rădițoiu, A.; Raduly, F.M.; Ispas, G.C.; Căprărescu, S.; Frone, A.N.; Trică, B.; Nicolae, C.-A.; Anastasescu, M.; et al. Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings. Appl. Sci. 2021, 11, 11044. https://doi.org/10.3390/app112211044
Purcar V, Rădițoiu V, Rădițoiu A, Raduly FM, Ispas GC, Căprărescu S, Frone AN, Trică B, Nicolae C-A, Anastasescu M, et al. Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings. Applied Sciences. 2021; 11(22):11044. https://doi.org/10.3390/app112211044
Chicago/Turabian StylePurcar, Violeta, Valentin Rădițoiu, Alina Rădițoiu, Florentina Monica Raduly, Georgiana Cornelia Ispas, Simona Căprărescu, Adriana Nicoleta Frone, Bogdan Trică, Cristian-Andi Nicolae, Mihai Anastasescu, and et al. 2021. "Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings" Applied Sciences 11, no. 22: 11044. https://doi.org/10.3390/app112211044
APA StylePurcar, V., Rădițoiu, V., Rădițoiu, A., Raduly, F. M., Ispas, G. C., Căprărescu, S., Frone, A. N., Trică, B., Nicolae, C.-A., Anastasescu, M., & Stroescu, H. (2021). Effect of Modified Silica Materials on Polyvinyl Chloride (PVC) Substrates to Obtain Transparent and Hydrophobic Hybrid Coatings. Applied Sciences, 11(22), 11044. https://doi.org/10.3390/app112211044