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Open AccessArticle

Geochemical and Isotopic Evidence of Groundwater Salinization Processes in El Dabaa Area, Northwestern Coast, Egypt

1
Hydrogeochemistry Department, Water Resources and Desert Soil Division, Desert Research Center, Cairo 11753, Egypt
2
Chemistry Department, Faculty of Science, Ain Shams University, Abbasia, Cairo P.O. Box 11566, Egypt
3
Institute of Environmental Science and Research, Ain Shams University, Abbasia, Cairo P.O. Box 11566, Egypt
*
Author to whom correspondence should be addressed.
Geosciences 2018, 8(11), 392; https://doi.org/10.3390/geosciences8110392
Received: 25 August 2018 / Revised: 12 October 2018 / Accepted: 26 October 2018 / Published: 29 October 2018
(This article belongs to the Special Issue Geochemical Equilibrium and Processes in Seawater)
El Dabaa city is located along the northwestern coast ridge zone of Egypt, where the groundwater is the major water source for drinking, domestic, and agricultural purposes. The groundwater salinity increased over the last decades, therefore, geochemical techniques and environmental isotopes have been utilized to identify the main groundwater recharge and salinization sources. The study area comprises two main groundwater aquifers: the porous oolitic Pleistocene and the fractured limestone Miocene aquifers. The groundwater salinity of the Pleistocene aquifer ranges from 751 to 27,870 mg/L, with an average value of 6006 mg/L. The salinity of the Miocene aquifer ranges from 3645 to 41,357 mg/L, with an average value of 11,897 mg/L. Fresh and brackish groundwater have been recorded in the shallow hand-dug wells, while saline groundwater has been found in deeper wells close to the shoreline. Groundwater samples have been categorized into two distinct groups according to the salinity ranges, hydrochemical ion ratios, and stable isotopic content. Group I is composed of groundwater with salinity less than 10,000 mg/L, and depleted stable isotopic content (−5.64 < δ18O < −2.45; −23.5 < δ2H < −0.02), while Group II contains groundwater with salinity values above 10,000 mg/L and relatively enriched stable isotopic content (−1.86 < δ18O < −0.48; −10.3 < δ2H < −2.0). The weight mass balance mixing model shows that Group I falls close to the rain and/or water extract samples, indicating meteoric water origin that has evolved due to leaching and dissolution processes. Group II is mostly located between the rainwater and the seawater samples, revealing mixing with water of marine origin due to groundwater overexploitation. The estimated seawater mixing index (SMI) of groundwater samples of Group II is greater than one, which confirms mixing with seawater. The water-rock reaction NETPATH (geochemical groundwater reaction and mixing code) model scenarios representing Group I suggests that gypsum, dolomite, and halite are dissolved, while calcite is formed with a slight influence from evaporation processes. Six mixing models representing Group II are used to investigate seawater mixing scenarios. The models suggest that illite and dolomite are dissolved, while calcite and gypsum are precipitated with a seawater mixing ratios ranging from 28% to 98%. In conclusion, due to the scarcity of annual groundwater recharge in the El Dabaa area, groundwater withdrawal should be well managed to avoid groundwater salinization and further seawater intrusion. View Full-Text
Keywords: geochemistry; groundwater; seawater intrusion; stable isotopes; El Dabaa area geochemistry; groundwater; seawater intrusion; stable isotopes; El Dabaa area
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Eissa, M.A.; Shawky, H.; Samy, A.; Khalil, M.M.H.; El Malky, M. Geochemical and Isotopic Evidence of Groundwater Salinization Processes in El Dabaa Area, Northwestern Coast, Egypt. Geosciences 2018, 8, 392.

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