Green Preparation and Dry Sliding Wear Properties of a Macro-ZTA/Fe Composite Produced by a Two-Step Method
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Preparation of Composite by Two-Step Process
- (1)
- In the first step, the mold was closed and locked at the pressure of 115 MPa, then a filling pressure (P1) of 125 MPa was exerted to push molten iron and particles into the filling channel continuously at a high speed (150 mm/s). Then the particles were in contact with the molten iron and were wrapped by the rapidly flowing molten metal, thus achieving a uniform dispersion during the filling process. Subsequently, the metal-particle mixture was pushed into the workpiece cavities.
- (2)
- In the second step, the metal-particle mixture in the cavities was subjected to a boost pressure (P2) of 130 MPa to realize feeding and solidification and the pressure was maintain a certain time to achieve a tight bonding between the meal and particles.
- (3)
- After the solidification was completed, the boost pressure was removed and the mold was opened to obtain the ZTA/HCCI composite.
2.3. Instruments and Characterizations
3. Results and Discussion
3.1. Distribution and Interface
3.2. Microstructure
3.3. Mechanical Properties
3.4. Wear Property
3.4.1. Wear Resistance of the Composite
3.4.2. Worn Surface of the Composite
3.4.3. Worn Sub-Surface of the Composite
3.4.4. Worn Surface of the Counterpart Ring
4. Conclusions
- (1)
- In the prepared composite, the ZTA particles were distributed homogeneously inside the HCCI matrix, and the interface combined by mechanical bonding was tight, clear and smooth, where no debonding or other defects were observed. The XRD results showed that the composite mainly consists of Al2O3, t–ZrO2, m–ZrO2, M7C3, austenite, and martensite.
- (2)
- The impact toughness of the composite (6.67 J·cm−2) is significantly lower than that of the HCCI alloy (9.27 J·cm−2). The fracture surface morphology of the composite showed that the fracture appears inside the particles, indicating a relatively strong bonding between the matrix and particles. Moreover, the fracture mode of the matrix is dominated by a ductile fracture.
- (3)
- Under dry sliding wear conditions, the wear resistance of the composite is obviously higher than that of the unreinforced HCCI material, and the relative wear resistance of the composite to HCCI increased from 1.8 to 2.9 times when the applied load varied from 300 to 900 N, which indicated the wear resistance of the composite is much better at higher load.
- (4)
- The wear mechanism of the composite is mainly slight abrasive wear under lower applied load (300 N), which is manifested as relatively shallow and narrow grooves and scratches, while the wear characteristics of fragmentation of particles, transfer layer and interface cracking dominate the wear process when the applied load is higher (900 N).
Author Contributions
Funding
Conflicts of Interest
References
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Composition (vol.%) | Particle Size (mm) | Density (g·cm−3) | Melting Point (°C) | Hardness (HV) | Fracture Toughness (MPa·m1/2) |
---|---|---|---|---|---|
Al2O3–60% ZrO2–40% | 2–3 | 4.0 | 1900 | 1700–1900 | 7.0 |
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Qiu, B.; Xing, S.; Dong, Q. Green Preparation and Dry Sliding Wear Properties of a Macro-ZTA/Fe Composite Produced by a Two-Step Method. Metals 2019, 9, 986. https://doi.org/10.3390/met9090986
Qiu B, Xing S, Dong Q. Green Preparation and Dry Sliding Wear Properties of a Macro-ZTA/Fe Composite Produced by a Two-Step Method. Metals. 2019; 9(9):986. https://doi.org/10.3390/met9090986
Chicago/Turabian StyleQiu, Bo, Shuming Xing, and Qi Dong. 2019. "Green Preparation and Dry Sliding Wear Properties of a Macro-ZTA/Fe Composite Produced by a Two-Step Method" Metals 9, no. 9: 986. https://doi.org/10.3390/met9090986