Enhancing Automotive Valve Guide Tribomechanical Performance Through Alloy Optimization in Powder Metallurgy
Abstract
1. Introduction
2. Materials and Methods
3. Results
3.1. Tribological Performance and Dominant Wear Mechanisms
3.2. Spectroscopy Analysis
3.3. Microstructure Analysis
3.4. Porosity Analysis
4. Conclusions
- The influence of alloy elements on wear resistance: Research has found that adding MoS2 and Cu can improve the wear resistance of materials. MoS2 provides stable performance in harsh working environments due to its high temperature strength, hardness, and low density; Cu can not only promote the sintering process but can also improve the strength and wear resistance of materials through the formation of solid solutions. Sample 3 did not add MoS2, but it did add a large amount of Cu to improve its wear resistance, while Sample 1 added a large amount of MoS2; however, its wear resistance was worse than that of Sample 2 with a small amount of MoS2 added. Therefore, a reasonable adjustment of the types and contents of alloy elements is the key to improving the wear resist.
- The influence of microstructure on wear resistance: The microstructure of the three samples is mainly pearlite, and pores and alloy phases of MoS2 and Cu are added to improve the wear resistance of the materials. Comparing the three samples, it was found that the morphology of pearlite has a significant impact on the wear resistance of the material. Sample 3 had finer pearlite layers with better wear resistance, while Samples 1 and 2 had poorer wear resistance due to the addition of MoS2 causing their pearlite layers to widen. The large amount of MoS2 alloy phase in Sample 1 reduces the tightness of the material, making it easy to detach and form abrasive wear during friction, further exacerbating the wear of the material. Although there is not much difference in porosity among the three samples, the presence of pores still has a certain impact on the wear resistance of the material. Pores can store oil and provide lubrication, thereby improving the wear resistance of materials. However, high porosity may reduce material strength and rigidity, which is not conducive to improving wear resistance. Therefore, the porosity should be reasonably controlled in the manufacturing process of powder metallurgy valve guides.
- Regarding the wear mechanisms of the alloys: Alloy 1 (high MoS2, low Cu) undergoes severe abrasive wear, as its coarse MoS2-rich phases and irregular pearlite easily detach during friction to form abrasive particles that scratch the surface, leading to the highest friction coefficient (0.5) and wear loss (2964 μm2). Alloy 2 (low MoS2, low Cu) experiences mild abrasive wear, where reduced MoS2 mitigates but does not eliminate phase coarsening, and low Cu provides limited lubrication, resulting in a moderate friction coefficient (0.3) and wear loss (1580 μm2). Alloy 3 (no Mo, high C-Cu) exhibits mild adhesive wear, with fine pearlite enhancing matrix hardness (145 HB) to resist scratching, Cu acting as a solid lubricant to reduce metal-to-metal contact, and pores (25.14% porosity) storing oil for further lubrication, thus achieving the lowest friction and wear.
- Based on the current research results, future work can focus on the following aspects: Further exploration of the influence of different alloy elements and their contents on the wear resistance of materials in order to find the best alloy element combination and content so as to maximize the wear resistance of materials. By adjusting the preparation process and heat treatment conditions, such as refining the pearlite layer and controlling the porosity and the distribution of alloy phase, the microstructure of the material can be optimized so as to improve the wear resistance and comprehensive properties of the material. The optimized material can then be applied to actual working conditions for long-term wear resistance testing and performance evaluation in order to verify its feasibility and reliability in practical applications.
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
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| Samples | C | Mo | Cu | S | Fe |
|---|---|---|---|---|---|
| #1 | 1.5 | 1.9 | 1.5 | 1.4 | 93.7 |
| #2 | 1.2 | 0.3 | 0.8 | 0.2 | 97.5 |
| #3 | 1.8 | 0 | 5 | 0.01 | 93.19 |
| Trademark | Sample 1 | Sample 2 | Sample 3 |
|---|---|---|---|
| Porosity/% | 23.74 | 22.99 | 25.14 |
| Sample | HIT (GPa)-MoS2 | HIT (MPa)-Black Porosity | HIT (GPa)-Matrix | HIT (GPa)-Cu | HIT (GPa)-Fe3C |
|---|---|---|---|---|---|
| #1 | 4.6 | 306 | 3.5 | ||
| #2 | 7.14 | 46.8 | 3.2 | ||
| #3 | 170.6 | 4.3 | 3.5 | 13.5 |
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Guo, F.; Yan, Z.; Lu, G.; Liu, W.; Zhang, P.; Shen, G. Enhancing Automotive Valve Guide Tribomechanical Performance Through Alloy Optimization in Powder Metallurgy. Metals 2025, 15, 1301. https://doi.org/10.3390/met15121301
Guo F, Yan Z, Lu G, Liu W, Zhang P, Shen G. Enhancing Automotive Valve Guide Tribomechanical Performance Through Alloy Optimization in Powder Metallurgy. Metals. 2025; 15(12):1301. https://doi.org/10.3390/met15121301
Chicago/Turabian StyleGuo, Fujian, Zhongyuan Yan, Guangyi Lu, Wenle Liu, Pan Zhang, and Gengzhe Shen. 2025. "Enhancing Automotive Valve Guide Tribomechanical Performance Through Alloy Optimization in Powder Metallurgy" Metals 15, no. 12: 1301. https://doi.org/10.3390/met15121301
APA StyleGuo, F., Yan, Z., Lu, G., Liu, W., Zhang, P., & Shen, G. (2025). Enhancing Automotive Valve Guide Tribomechanical Performance Through Alloy Optimization in Powder Metallurgy. Metals, 15(12), 1301. https://doi.org/10.3390/met15121301

