Corrosion Behavior of Passivated Martensitic and Semi-Austenitic Precipitation Hardening Stainless Steel
Abstract
:1. Introduction
2. Experimental Methodology
2.1. Materials
2.2. Passivation Treatment
2.3. Microstructural Characterization
2.4. Corrosion Test
2.5. XPS Characterization
3. Results and Discussion
3.1. OM-SEM Microstructural
3.2. Corrosion Test
Potentiodynamic Polarization
3.3. XPS Analysis
4. Conclusions
- OM-SEM characterization indicated that the martensitic PHSS presented a microstructure with a martensitic (α’) phase and a semi-austenitic PHSS containing a microstructure of austenite (γ) and delta (δ) ferrite phases, respectively. Based on the values obtained from PREN, the semi-austenitic PHSS (25.37) presented a higher corrosion resistance than the martensitic PHSS (17.26).
- Potentiodynamic polarization results indicated that martensitic and semi-austenitic steels passivated in nitric acid showed lower corrosion resistance values (in the order of ×10−4 mm/yr).
- Nitric acid passivation made the surface susceptible to localized corrosion. The potentiodynamic polarization curves for PHSS immersed in 5 wt.% NaCl solution indicated that the passivation showed a trend since it is not fully defined.
- Despite having a well-defined passivation layer, passive samples studied in H2SO4 solution presented an increase in corrosion kinetics.
- Passivation current, ipass, was found to have higher values for samples exposed to sulfuric acid (from 0.506 up to 9.837 µA·cm−2).
- XPS analysis determined that the different chemical species on the surface film of martensitic and semi-austenitic PHSS in this work included Cr2O3 and Fe(OH)O. Passive films contained iron and chromium oxide and hydroxide.
- The samples passivated at 70 °C are the ones that presented the best results independently of the steel, passivating solution, and time.
- The citric acid passivation process on PHSS could be a green alternative to the currently employed nitric acid passivation process.
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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PHSS | Elements | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
Cr | Ni | Mo | Mn | Cu | Ti | Nb | N | Si | S | C | Fe | |
Martensitic | 14.0–16.0 | 5.0–7.0 | 0.50–1.0 | 1.00 | 1.25–1.75 | 0.90–1.40 | 0.5–0.75 | ≤0.1 | 1.00 | 0.030 | ≤0.05 | Balance |
Semi-austenitic | 16.0–17.0 | 4.0–5.0 | 2.50–3.25 | 0.50–1.25 | – | – | – | 0.07–0.13 | ≤0.50 | 0.030 | 0.07–0.11 | Balance |
PHSS | Passivation Baths | Time (min) | Temperature (°C) | Nomenclature Samples * |
---|---|---|---|---|
semi-austenitic | C6H8O7 | 50 | 49 | semi-austenitic-CA-75 min-49 °C |
HNO3 | 50 | 70 | semi-austenitic-NA–50 min-70 °C | |
HNO3 | 50 | 70 | semi-austenitic-NA–50 min-70 °C | |
C6H8O7 | 75 | 49 | semi-austenitic-CA–75 min-49 °C | |
martensitic | HNO3 | 75 | 70 | martensitic-NA–75 min–70 °C |
HNO3 | 50 | 49 | martensitic-NA–50 min–49 °C | |
C6H8O7 | 50 | 49 | martensitic-CA–50 min–49 °C | |
C6H8O7 | 75 | 49 | martensitic-CA-75 min-49 °C |
PHSS | Cr | Mo | N | PREN |
---|---|---|---|---|
Martensitic | 14.0–16.0 | 0.50–1.0 | ≤0.1 | 17.26 |
Semi-austenitic | 16.0–17.0 | 2.50–3.25 | 0.07–0.13 | 25.37 |
Sample | Ecorr (Volts) | Epitt (Volts) | icorr (µA·cm−2) | ipass (µA·cm−2) | Range Passive (Volts) | CR (mm/yr) |
---|---|---|---|---|---|---|
Semi-austenitic-CA–50 min–49 °C | −0.365 | 0.422 | 7.82 × 10−1 | 0.352 | 0.736 | 1.26 × 10−3 |
Semi-austenitic-NA–50 min–70 °C | −0.234 | 0.934 | 1.58 × 10−1 | 0.082 | 1.119 | 2.55 × 10−4 |
Martensitic-NA–75 min–70 °C | −0.234 | 0.565 | 1.37 × 10−1 | 0.119 | 0.740 | 2.25 × 10−4 |
Martensitic-CA–50 min–49 °C | −0.384 | 0.401 | 3.44 × 10−1 | 0.480 | 0.688 | 5.65 × 10−3 |
Sample | Ecorr (Volts) | Epitt (Volts) | icorr (µA·cm−2) | ipass (µA·cm−2) | Range passive (Volts) | CR (mm/yr) |
---|---|---|---|---|---|---|
Semi-austenitic-CA–75 min–49 °C | −0.314 | 0.875 | 0.7 × 10−1 | 9.837 | 1.055 | 1.13 × 10−2 |
Semi-austenitic-NA–50 min–70 °C | −0.226 | 0.766 | 2.24 × 10−1 | 0.506 | 0.692 | 3.62 × 10−4 |
Martensitic-NA–50 min–49 °C | −0.282 | 0.898 | 2.25 × 10−1 | 8.529 | 0.899 | 3.69 × 10−2 |
Martensitic-CA–75 min–49 °C | −0.349 | 0.857 | 5.37 × 10−1 | 8.193 | 0.880 | 8.82 × 10−2 |
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Almeraya-Calderón, F.; Samaniego-Gámez, O.; Maldonado-Bandala, E.; Nieves-Mendoza, D.; Olguín-Coca, J.; Jáquez-Muñoz, J.M.; Cabral-Miramontes, J.; Flores-De los Rios, J.P.; Bautista-Margulis, R.G.; Gaona-Tiburcio, C. Corrosion Behavior of Passivated Martensitic and Semi-Austenitic Precipitation Hardening Stainless Steel. Metals 2022, 12, 1033. https://doi.org/10.3390/met12061033
Almeraya-Calderón F, Samaniego-Gámez O, Maldonado-Bandala E, Nieves-Mendoza D, Olguín-Coca J, Jáquez-Muñoz JM, Cabral-Miramontes J, Flores-De los Rios JP, Bautista-Margulis RG, Gaona-Tiburcio C. Corrosion Behavior of Passivated Martensitic and Semi-Austenitic Precipitation Hardening Stainless Steel. Metals. 2022; 12(6):1033. https://doi.org/10.3390/met12061033
Chicago/Turabian StyleAlmeraya-Calderón, Facundo, Oliver Samaniego-Gámez, Erick Maldonado-Bandala, Demetrio Nieves-Mendoza, Javier Olguín-Coca, Jesús Manuel Jáquez-Muñoz, José Cabral-Miramontes, Juan Pablo Flores-De los Rios, Raul German Bautista-Margulis, and Citlalli Gaona-Tiburcio. 2022. "Corrosion Behavior of Passivated Martensitic and Semi-Austenitic Precipitation Hardening Stainless Steel" Metals 12, no. 6: 1033. https://doi.org/10.3390/met12061033