Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery
Abstract
:Highlights:
- Electrolyte of highly complex chemical composition resulting from specially designed pyro-electrometallurgical e-waste process, aiming to reflect future obstacles considering sole e-waste recycling
- A one-factor solvent extraction methodology for the comparison of three commercial extractants in terms of efficiency, distribution coefficients, selectivity, and influence of impurities on Cu extraction from experimentally obtained electrolyte
- Feed pH, extractant, and stripping agent concentration affect solvent extraction most significantly through reaction equilibrium shifts and active centers availability
- Optimized process conditions enable selective Cu extraction among highly abundant Fe, Zn, Pb, Ni, and Sn and trace elements (i.e., Al, Co, Cr, Mg, Na, Sb, Ga, Ge)
- Transfer monitoring, distribution, and methodology for additional valorization of metals
1. Introduction
2. Experimental
2.1. Material
2.2. Sole E-Waste Preparation Process
2.3. Reagents and Procedure
2.4. Analytical Methods
3. Results and Discussion
3.1. Feed Composition
3.2. Solvent Extraction (SX) Optimization
3.2.1. Effect of Extractant Concentrations and O/A Ratio
3.2.2. Effect of Phase Contact Time
3.2.3. Effect of Feed pH
3.2.4. McCabe-Thiele Extraction Diagram
3.3. Stripping Optimization
3.3.1. Effect of the Acid Concentration
3.3.2. Effect of O/A Stripping Ratio
3.3.3. Effect of Stripping Contact Time
3.3.4. Effect of Extractant Concentration in the Loaded Organic Phase
3.3.5. McCabe-Thiele Stripping Diagram
3.4. Solvent Extraction with LIX® 984N and OPT 5510
3.5. Copper and Metal Impurities Distribution
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Acknowledgments
Conflicts of Interest
References
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Element | Metallic Granulate | Anodes | Electrolyte | ||
---|---|---|---|---|---|
% | % | ppm | mg/L | g/L | |
Cu | 69.12 | 83.40 | - | - | 41.37 |
Fe | 5.90 | 3.90 | - | - | 20.67 |
Zn | 12.71 | 5.40 | - | - | 26.55 |
Ni | 1.68 | 2.32 | - | - | 9.89 |
Sn | 5.89 | 7.27 | - | 453.1 | - |
Pb | 3.30 | 3.52 | - | 3.1 | - |
Bi | n.a. | 0.04 | - | 112.9 | - |
Ca | n.a. | 0.10 | - | 346.3 | - |
Co | 0.01 | 0.05 | - | 163.4 | - |
Cr | 0.12 | 0.03 | - | 95.8 | - |
Mg | n.a. | 0.03 | - | 61.1 | - |
Ag | 0.64 | 0.64 | - | <DL | - |
Au | 30 ppm | 0.11 | - | <DL | - |
Al | 0.12 | - | 63 | 19.3 | - |
Cd | 0.04 | - | 62 | 21.7 | - |
Mn | 0.10 | - | 84 | 29.7 | - |
B | n.a. | - | 32 | 8.7 | - |
Na | n.a. | - | 120 | 41.8 | - |
Sb | n.a. | - | 23 | 5.8 | - |
Ga | n.a. | - | 47 | 12.5 | - |
Ge | n.a. | - | 4 | 1.2 | - |
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Djokić, J.; Radovanović, D.; Nikolovski, Z.; Andjić, Z.; Kamberović, Ž. Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery. Metals 2021, 11, 1383. https://doi.org/10.3390/met11091383
Djokić J, Radovanović D, Nikolovski Z, Andjić Z, Kamberović Ž. Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery. Metals. 2021; 11(9):1383. https://doi.org/10.3390/met11091383
Chicago/Turabian StyleDjokić, Jovana, Dragana Radovanović, Zlatko Nikolovski, Zoran Andjić, and Željko Kamberović. 2021. "Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery" Metals 11, no. 9: 1383. https://doi.org/10.3390/met11091383