Estimation of Wear Resistance for Multilayer Coatings Obtained by Nitrogenchroming
Abstract
:1. Introduction
2. Materials and Methods
2.1. Mathematical Model
- zmax < Δs—partial wear of the layer(s) with the total depth of z = zmax = zp;
- zmax = Δs—full wear of all the layers with the total depth of z = zmax = Δs;
- zmax > Δs—wear of the sample with the total depth of z = zmax > Δs.
2.2. A Particular Case Study
2.3. Experimental Equipment
- –
- X-ray diffraction analysis is conducted by diffractometer “DRON UM-1” (“MTPK-LOMO” Ltd., Saint Petersburg, Russia) in Cu Kα1 radiation using graphite monocrystal monochromator on diffracted beam;
- –
- Metallographic analysis is carried out by microscopes “MIM-8” (“MTPK-LOMO” Ltd., Saint Petersburg, Russia) and “Neophot-21” (Carl Zeiss Jena GmbH, Oberkochen, Germany);
- –
- X-ray spectral analysis is realized using scanning electron microscope “JSM-6490LV” (Tokyo Boeki Ltd., Tokyo, Japan).
3. Results
3.1. Microstructure of Coatings after Nitrogenchroming of Steels
3.1.1. Steel DINC80W1
3.1.2. Steel DIN 105WCr6
3.1.3. Comparative Analysis of Coatings
3.2. Wear Resistance of Steel DIN C80W1 after Chemical-Thermal Treatment
4. Discussion
5. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Layer Number | Density kg/m3 | Thickness, μm | Microhardness, GPa | Phase Composition |
---|---|---|---|---|
Multilayer Coating | ||||
1 | 7000 | 3 | 18.2 | Cr23C6 |
2 | 6970 | 4 | 16.2 | Cr7C3 |
n = 3 | 6800 | 3 | 8.8 | Cr2N |
Sample | ||||
n + 1 = 4 | 7840 | – | – | – |
Wearing Till Layer No. | The Total Mass Losses, mg | |
---|---|---|
min, ms(zj–1) | max, ms(zj) | |
1 | – | 4.0 |
2 | 4.0 | 14.2 |
3 | 14.2 | 24.1 |
4 | 24.1 | 24.1 |
Spectrum No. | Distance from the Surface μm | Content of Elements, % Mass | ||||
---|---|---|---|---|---|---|
C | Cr | Fe | Si | Mn | ||
1 | 3.0 | 5.4 | 84.6 | 10.0 | – | – |
2 | 7.0 | 9.0 | 79.8 | 11.2 | – | – |
3 | 10.0 | 9.1 | 78.6 | 12.1 | 0.2 | – |
4 | 50.0 | 0.7 | 1.5 | 95.9 | 1.5 | 0.4 |
Scheme | Distance from the Surface, μm | Content of Elements,% Mass | |||||||
---|---|---|---|---|---|---|---|---|---|
C | N | Cr | Fe | O | Si | Mn | W | ||
1 | 2.0 | 5.4 | – | 92.2 | 2.4 | – | – | – | – |
2 | 4.0 | 5.6 | – | 91.8 | 2.5 | – | – | – | 0.1 |
3 | 10.0 | 8.9 | 0.3 | 82.2 | 2.7 | 0.8 | – | – | 0.1 |
4 | 11.0 | 1.2 | 9.2 | 86.4 | 2.9 | 1.1 | 0.2 | – | – |
5 | 12.0 | 1.2 | 9.4 | 81.8 | 3.8 | 3.3 | 0.5 | – | – |
6 | 14.0 | 1.0 | – | 7.9 | 89.6 | – | 0.6 | 0.4 | 0.5 |
7 | 17.0 | 1.0 | – | 7.8 | 89.4 | – | 0.9 | 0.4 | 0.5 |
8 | 22.0 | 1.0 | – | 3.3 | 94.2 | – | – | 0.8 | 0.7 |
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Pavlenko, I.; Zajac, J.; Kharchenko, N.; Duplák, J.; Ivanov, V.; Kostyk, K. Estimation of Wear Resistance for Multilayer Coatings Obtained by Nitrogenchroming. Metals 2021, 11, 1153. https://doi.org/10.3390/met11081153
Pavlenko I, Zajac J, Kharchenko N, Duplák J, Ivanov V, Kostyk K. Estimation of Wear Resistance for Multilayer Coatings Obtained by Nitrogenchroming. Metals. 2021; 11(8):1153. https://doi.org/10.3390/met11081153
Chicago/Turabian StylePavlenko, Ivan, Jozef Zajac, Nadiia Kharchenko, Ján Duplák, Vitalii Ivanov, and Kateryna Kostyk. 2021. "Estimation of Wear Resistance for Multilayer Coatings Obtained by Nitrogenchroming" Metals 11, no. 8: 1153. https://doi.org/10.3390/met11081153