3.1. Framework for Selecting the Most Suitable Energy Storage System
The selection of a suitable ESS for manufacturing facilities requires a structured approach, based on several criteria. In this section, a framework to facilitate such a selection is presented, including different technical, operational, economic, and environmental criteria. The proposed framework provides easy-to-follow steps for identifying, evaluating, and ranking ESS technologies. It can be used for different types of applications, each with specific goals, contributing to a systematization of the selection procedure. The process is based on the characteristics of the systems as well as the specifications of different applications that can be met in different industrial settings. For the selection of the most suitable ESS, the proposed framework consists of two stages and eight steps, for the selection of the most suitable ESS for different industrial applications. The first stage (Stage 1) of this process is the elimination of the ESS solutions that are clearly unsuitable. The remaining systems are further examined in the second stage (Stage 2), through simple simulations, maintaining the simplicity and industrial appeal of the proposed approach.
Figure 4 illustrates the proposed decision-making framework for selecting the most suitable ESS technology based on technical, operational, and economic criteria. The process follows a structured, yet simple approach composed of eight main steps, allowing systematic evaluation and comparison of potential ESS technologies.
As shown in
Figure 4, the proposed framework consists of two stages and eight steps.
The first stage (Stage 1) aims to identify and shortlist the technologies applicable to the examined case, producing a set of feasible candidates, while the second stage (Stage 2) focuses on the final selection through an in-depth analysis and comparison of the shortlisted technologies. To achieve this, the following steps, depicted in
Figure 4, are followed. The process begins with the definition of the problem (Step 1), followed by the selection of criteria to eliminate non-applicable technologies (Step 2). Subsequently, available technologies are identified (Step 3), and their compliance with the defined criteria is assessed (Step 4). This assessment is repeated for all available technologies (Step 5), leading to the shortlisting of the most suitable candidates (Step 6), which completes the first stage. In
Stage 2, simulations and detailed analyses are conducted for all shortlisted technologies (Step 7). The results are then compared, and the most suitable option is validated based on the objectives of the ESS implementation (Step 8). If the selected technology meets the defined requirements, it is adopted; otherwise, the requirements or the scope of the ESS implementation should be redefined.
In Stage 1, the identification and shortlisting of the most suitable technologies are performed by following Steps 1 to 6, as described in detail below. The first Step involves the identification of the problem, the desired outcome of the implementation of an ESS, and the main strategy to be followed.
In
Step 2, the functional purpose of the ESS within the power system, such as frequency regulation, peak shaving, renewable integration, or resilience enhancement, is defined. Defining the application context allows the specification of operational parameters, including required power capacity, energy rating, discharge duration, and response time. Once the target application is established, the operational requirements are specified, including parameters such as power capacity, discharge duration, response time, and desired reliability levels [
20,
22]. Depending on the defined requirements and constraints, the filtering may result in a varying number of candidate technologies, ranging from a single option to multiple feasible alternatives. The operational requirements of the ESS are defined, and the corresponding evaluation criteria are selected. The process begins by specifying the system’s technical and functional needs, such as rated power, required energy capacity, discharge duration, response time, and lifetime expectations. These requirements establish the performance boundaries that the ESS must satisfy within the target application. Based on these requirements, appropriate selection criteria are identified to ensure that the evaluation framework reflects the system’s actual operational needs, allowing only technologies capable of meeting these specifications to progress to subsequent analysis phases. The goal is to match the technical profile of each technology with the operational requirements of the target application. Studies highlight the importance of this alignment to ensure both functional adequacy and system reliability [
39].
In
Figure 5, a comprehensive outline of the criteria for selecting an ESS and the corresponding KPIs is provided, categorized into technical, economic, and environmental aspects.
Figure 5 serves as a foundational tool for evaluating and comparing different ESS technologies based on a comprehensive set of KPIs, created to capture the different dimensions of system performance, including cost, I5.0 alignment, impact on sustainability, resilience, and human-centricity. By systematically assessing each KPI, stakeholders can make informed decisions tailored to specific application needs and constraints [
15,
16,
17,
18]. It should be noted that the proposed framework is inherently modular and adaptable, allowing the inclusion of additional criteria depending on the specific characteristics of the application. These may include site-dependent factors such as transportation costs, land preparation requirements, proximity to grid connection points, availability of local technical support, and regulatory or policy-driven constraints.
The technical characteristics of an ESS are commonly expressed through several KPIs, which are critical for technology selection and system design. Storage Capacity refers to the total amount of energy that an ESS can store and subsequently deliver under specified operating conditions. It is a fundamental measure for determining whether the system can satisfy the required energy supply duration in a given application [
23]. Energy density quantifies the amount of energy stored per unit mass (Wh/kg) or volume (Wh/L). High energy density is essential for minimizing system footprint and enabling compact installations, particularly in space-constrained industrial environments. This KPI serves as a key differentiator among ESS technologies, with chemical-based batteries generally offering higher energy density than mechanical or thermal storage systems [
37].
Round-trip efficiency (
ηrt) defines the proportion of stored energy that can be recovered relative to the energy initially stored. It is expressed as:
High round-trip efficiency reduces energy losses during charge–discharge cycles and improves the overall delivered energy, thereby impacting operational costs and sustainability [
26]. Response time characterizes the speed at which an ESS can deliver its rated power. Fast response is particularly critical for applications such as peak shaving, frequency regulation, and grid stabilization, where supply must rapidly match transient demand or generation fluctuations [
25]. Self-discharge rate measures the proportion of stored energy lost over time when the system is idle. Systems with lower self-discharge rates maintain higher standby readiness and ensure better utilization of stored energy, which is especially important for backup and resilience-oriented applications [
37].
Capital Expenditure (CapEx) represents the initial investment required to acquire and install an energy storage system, typically expressed per unit of storage capacity (€/kWh or €/kW). CapEx is a critical KPI for evaluating the economic feasibility of ESS technologies and is often used in combination with operational costs and levelized cost metrics to guide investment decisions [
26]. Operation and maintenance (O&M) cost quantifies the recurring annual expenses associated with operating, maintaining, and servicing the ESS over its operational lifetime. It can be expressed per unit of power (€/kW/year) or per unit of energy capacity (€/kWh/year). O&M costs capture the long-term economic impact of ESS operation, including maintenance labor, parts replacement, system monitoring, and ancillary support services [
26].
Levelized cost of storage (LCOS) quantifies the total cost of delivering one unit of energy from an energy storage system over its entire operational lifetime. It accounts for both the CapEx and the ongoing O&M costs, discounted over time to reflect the time value of money. Mathematically, it is expressed as:
where
is the upfront capital cost,
is the operational cost in year
t,
is the energy delivered in year
t,
r is the discount rate, and
n is the system lifetime. The Levelized cost of storage (
) is a crucial KPI because it enables economic comparison between different ESS technologies, taking into account variations in efficiency, lifetime, and maintenance requirements. It is particularly valuable in strategic decision-making for industrial and grid-scale energy storage projects, guiding investment and technology selection [
40].
Lifetime/Cycle life refers to the duration over which an ESS can reliably store and deliver energy, either expressed as operational years or the number of full charge/discharge cycles until the system’s capacity falls below a predefined threshold. Longer lifetimes reduce replacement costs while improving economic viability, making this KPI crucial for both grid-scale and industrial applications [
26,
31].
Environmental KPIs address the ecological and sustainability aspects of ESS technologies. Environmental impact can describe the overall footprint throughout the system’s lifecycle, from cradle to grave, including raw material extraction, manufacturing, operation, and end-of-life management [
41]. Common LCA indicators include global warming potential, acidification, and resource depletion [
23,
25]. CO
2 Intensity quantifies the greenhouse gas emissions (kg CO
2 equivalent) per unit of delivered energy across the system’s lifecycle. It is particularly relevant in low-carbon industrial applications and when assessing compliance with carbon reduction targets [
42]. Recycling/End-of-Life Recoverability (
) measures the proportion of system materials that can be recovered and reused at end-of-life:
High recoverability supports circular economy objectives and reduces the environmental footprint, enhancing sustainability in industrial deployment [
12,
43]. Land Use describes the physical footprint required by the ESS, expressed per unit of energy or power (m
2/MWh or m
2/MW). This KPI can influence technology choice between compact battery systems and larger mechanical or thermal storage solutions [
33,
37].
In the context of the industrial transition and I5.0, ESS selection needs to extend beyond strict technical or economic characteristics to encompass additional criteria. The new criteria that should be taken into consideration must ensure human-centricity and resilience across all of the industry’s operations. I5.0-related dimensions are incorporated into the framework through measurable indicators where applicable, complemented by structured evaluation criteria for aspects that are inherently context-dependent. To formalize the decision-making process and improve methodological transparency, key performance indicators and Industry 5.0-related criteria are expressed through Equations (4)–(9), which enable consistent and quantifiable comparison between the different ESS technologies. Safety/Risk evaluates the likelihood and severity of hazardous events. Risk assessment models often combine probability and impact metrics to quantify system safety. In line with risk-based engineering approaches, risk can be expressed as [
44]:
where
represents the risk level,
the probability of occurrence of a hazardous event, and
the consequence or severity, such as economic loss, downtime, or safety impact. This formulation is widely used in process industries and energy systems to evaluate hazardous scenarios and guide technology selection. This KPI is particularly important for battery-based systems, where operational hazards can have severe consequences [
45].
Reliability refers to the ability of an ESS to perform without failures over time. Reliability can be measured by calculating the mean time between failures (MTBF), the mean time needed for repair, the system availability, or failure rates as described below. High reliability is essential in industrial processes requiring continuous and uninterrupted operation. Core reliability indicators can be derived from operational data [
46,
47]. More specifically, the Mean Time Between Failures (MTBF) is defined as [
47]:
where
represents the total operating time and
the number of failures observed. MTBF provides an estimate of the average time interval between consecutive failures. The Mean Time to Repair (MTTR) is defined as [
47]:
where
denotes the total downtime required for corrective maintenance and
the number of failures. MTTR is the mean time between failures and reflects the maintainability of the system and the efficiency of repair processes. For systems characterized by a constant failure rate, the reliability function is expressed as [
47]:
where
is the probability of failure-free operation up to time
and
is the failure rate. The relationship between failure rate and MTBF is given by
, assuming an exponential failure distribution. In addition, system availability is defined as [
46]:
where
denotes the steady state availability of the system, and
is the mean time needed for repair. These formulations collectively describe the reliability, maintainability, and availability characteristics of the ESS and are widely used in power system reliability analysis.
Workforce integration evaluates how well an ESS supports human-centric operations, aligning with the principles of Industry 5.0. This includes the human–machine interfaces, transparency of system operations, operator training requirements, and the overall ease of collaboration between operators and the ESS. High workforce integration ensures that operators can interact with the system safely and efficiently. In practice, workforce integration can be quantified using measurable performance indicators such as task completion time and training effort. Task completion time reflects how quickly operators can perform essential functions, both operational actions (e.g., system start/stop, mode changes) and maintenance tasks (e.g., routine inspections, component swaps). Shorter task times are indicative of intuitive interfaces and efficient procedures, reducing cognitive and physical workload, which is consistent with the objectives of human-centric design in industrial systems [
46,
48]. Similarly, training hours required for achieving and maintaining competence in ESS operation and maintenance can be used as a proxy for usability and workforce integration. Lower training time indicates clearer system logic, better documentation, and more accessible interaction paradigms, all of which support safe and efficient collaboration between operators and ESS technologies [
47,
49]. Assessment can be carried out using structured qualitative evaluations, such as operator surveys, expert assessments, and standardized human factors metrics, combined with semi-quantitative scoring of sub-elements like interface clarity, automation support, and training adequacy [
50,
51].
Outage recovery capacity evaluates how effectively an ESS contributes to the overall resilience of an industrial facility, specifically its ability to maintain or restore operations following unexpected disruptions. This KPI emphasizes the role of the storage system not just as a backup source of power, but as an enabler of operational continuity, ensuring that production lines, critical equipment, and control systems can resume normal functioning quickly after events such as power outages, grid disturbances, or equipment failures. Different ESS technologies offer varying levels of resilience. Evaluating this KPI, therefore, requires a holistic perspective that considers not only the inherent reliability and operational flexibility of the ESS itself, but also the degree to which it supports rapid recovery of the broader industrial process. Following Ma et al. (2025) [
52], resilience can be quantified by incorporating two key dimensions: robustness and adaptive capacity. System resilience (Re) is defined as the ratio of system strength to the applied load, expressed mathematically as [
52]:
where
represents the time when the event occurs,
denotes the time of failure, and
indicates the recovery time.
corresponds to the duration of the failure, while
represents the recovery duration. The factors
and
stand for robustness and redundancy, respectively. This formulation is particularly comprehensive for ESS evaluation because it integrates both system reliability and sustained recovery strategies. By introducing
and
, the metric captures the balance between robustness and redundancy as well as the adaptive capacity of the system relative to recovery speed. Assessment of outage recovery capacity can be performed using scenario-based simulations of disruptions and historical reliability data. By incorporating these considerations, this KPI ensures that ESS selection is aligned with the facility’s resilience objectives. This approach allows ESS technologies to be evaluated not only based on their inherent reliability but also on their ability to support operational continuity and resilience objectives across the broader industrial process [
49,
52,
53].
Adaptability/Compatibility (digital interoperability) measures the capacity of an ESS to integrate seamlessly with I5.0-enabling technologies, including digital twins, Internet of Things (IoT) platforms, collaborative robotics, and advanced control systems. This KPI ensures that the ESS can evolve alongside emerging digital infrastructure, support predictive analytics, and facilitate human–machine collaboration in a connected factory or microgrid environment. In practical industrial environments, interoperability is strongly linked to the ability of the ESS to communicate and exchange data with existing energy management systems, supervisory control and data acquisition systems, and factory automation platforms. Therefore, this KPI can be evaluated based on whether the system supports industrial communication protocols such as Modbus Transmission Control Protocol (TCP), enables secure and platform-independent data exchange through OPC UA, and provides application programming interfaces that facilitate integration with digital platforms and energy management systems. Furthermore, compatibility with supervisory control and energy management architectures ensures that the ESS can operate as an integrated component of the broader cyber-physical system, enabling real-time monitoring, control, and optimization of energy flows. These capabilities are essential for I5.0 environments, where energy systems must operate within interconnected, data-driven industrial ecosystems. Assessment typically involves evaluating technical documentation, integration tests, and expert assessments to determine the readiness of the system to operate in digitally connected industrial environments [
54].
In the present case study, I5.0-related dimensions influenced the shortlisting phase primarily through safety constraints associated with industrial processes and requirements linked to the facility’s energy management infrastructure.
Step 3 involves the identification of the available technologies. The technologies can be categorized by specifying whether they are commercially available, available at a pilot stage, or tailor-made solutions. Also, the parameters related to the place of the installation or the local markets can have a significant role, depending on the case examined.
At Steps 4 and 5, the framework includes an initial assessment based on the selected criteria and requirements of the previous step and an evaluation loop, allowing for the consideration of additional candidate ESS technologies, in order to narrow down the available technologies.
During
Step 6, the technologies that satisfy the defined criteria are shortlisted based on their previous results. Subsequently, for
Step 7, a techno-economic analysis is conducted to simulate system performance and assess the financial feasibility across the shortlisted technologies [
18,
22]. Following the simulation phase, the selected storage technologies are compared in terms of both technical and economic performance indicators. The results are then validated during
Step 8 and verified to ensure the suitability of the proposed ESS for the intended application.
Finally, the process concludes with the final selection of the optimal ESS technology, representing the most suitable solution considering efficiency, cost, scalability, and operational compatibility. This framework provides a comprehensive and adaptable methodology for the systematic evaluation and selection of energy storage technologies in both grid-connected and isolated applications.
3.2. Simulation Modeling
To formalize a simulation framework for the in-depth comparison of the shortlisted technologies, the core mathematical relationships and constraints underlying the energy system are defined. The system is simulated in discrete time steps, with a fixed temporal resolution, representing the evolution of supply, demand, and storage states over time. The simulation module utilized in this study has been developed by the authors within a commercial energy management platform (UPKIP [
55]) and is currently not available as a standalone published software tool. Therefore, the methodological description provided in this section focuses on the underlying modeling approach and simulation logic rather than on a specific software implementation.
The energy produced by a renewable energy system (
) of a given installed capacity is typically expressed as [
56]:
The parameters are defined as follows:
represents the total power consumed, measured in either kW or MW.
denotes the time period in hours, such as 8760 h for a full year.
stands for the capacity factor, expressed as a decimal between 0 and 1.
indicates technical availability, represented as a decimal reflecting the percentage uptime. The sizing of the energy storage system installations (
) is given by the following formula [
13]:
The parameters are defined as follows: represents the energy required per hour, measured in MWh. indicates the desired hours of autonomy, and denotes the total round-trip efficiency of the energy system. stands for the Depth of Discharge.
The energy system is simulated in discrete time steps, with a fixed temporal resolution representing the evolution of supply, demand, and storage states over time. At each time step (
), the fundamental energy balance equation ensures that the sum of all energy inputs equals the total demand [
57]:
Here,
is the grid power supplied,
is the photovoltaic generation,
is the power exchanged by the
-th storage unit,
is the total number of the different energy storage systems used, and
is the system load at time step
. This generalized energy balance forms the basis of time-series energy system modeling. For each energy storage unit, the state of charge (SoC) evolves according to the net charging and discharging flows, taking into account efficiency (round-trip or one-way, based on the borders of the system considered) [
58]:
The
is the state of charge of the
-th energy storage system used and is bound by minimum and maximum operational limits, and
is the time step duration in seconds. Charging/discharging powers are constrained by the rated capabilities of the storage technology:
where
ηi is the round-trip efficiency,
is the capacity of the storage unit, and
j is the time step. These storage dynamics and constraints are representative of common approaches to modeling storage in electrical energy systems. Together, these equations provide a structured mathematical foundation for the simulation framework, linking physical energy balances, storage behavior, system constraints, and optimization goals within a unified time-series modeling context.
In order to ensure the credibility of the simulation results, the consistency of the implemented model was validated utilizing using recorded telemetry data of the baseline system. The simulated energy flows, demand profiles, and system responses were verified to follow the same trends and operational constraints observed in the real system. As such, the model can be used to provide a reliable comparative assessment of alternative configurations under consistent and realistic operating conditions.