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Article
Peer-Review Record

Nyrdvomenshor Nephrite Deposit, Polar Urals, Russia

Minerals 2023, 13(6), 767; https://doi.org/10.3390/min13060767
by Evgeniy V. Kislov 1,*, Mikhail P. Popov 2,3, Firat M. Nurmukhametov 3, Viktor F. Posokhov 1 and Vladislav V. Vanteev 1
Reviewer 1:
Reviewer 2: Anonymous
Reviewer 3: Anonymous
Minerals 2023, 13(6), 767; https://doi.org/10.3390/min13060767
Submission received: 16 April 2023 / Revised: 23 May 2023 / Accepted: 31 May 2023 / Published: 2 June 2023
(This article belongs to the Special Issue Formation of Gemstones and Geology of Gem Deposits)

Round 1

Reviewer 1 Report

Please add some products (jewelry) photos, if possible. It is difficult to assign the quality of the gemstones. Please add  comparison between this deposit and related similarly deposits found in Russia

Author Response

Please add some products (jewelry) photos, if possible. It is difficult to assign the quality of the gemstones.

- corrected. High-quality nephrite was mined at the deposit in 1980-1981. Since then, there has been no mining and no products have been manufactured. But in the article figure 6 with photographs of nephrite plates is replaced - the option with illumination is selected and the size is increased for clarity.

Please add  comparison between this deposit and related similarly deposits found in Russia

- corrected. Comparison was added.

Author Response File: Author Response.docx

Reviewer 2 Report

Review: Minerals 2376191

 

Nyrdvomenshor gem stones deposit, Polar Urals, Russia

Evgeniy V. Kislov, Mikhail P. Popov, Firat M. Nurmukhametov, Viktor F. Posokhov, Vladislav V. Vanteev

 

The study is important both from a theoretical and gemmological point of view. This is the first in detail mineralogical and geochemical investigation on this nephrite deposit from a remote region in the Northern Urals of the Russian Federation. The authors must change the introduction and final text which copy their text from an extended abstract on the same deposit (to be included in references): Kislov, E. V., M. P. Popov, F. M. Nurmukhametov, V. F. Posokhov. 2022b. Nephrite from the Nyrdvomenshor deposit (Polar Urals): features of composition and formation settings. – In: Ultramafic-mafic Complexes: Geology, Composition, Ore Potential. Materials of Conference. Apatity, 54-57 (in Russian).

 

Comments and notes:

Title: Nyrdvomenshor is well known as a nephrite deposit (Kazak et al., 1976; Efros, Prokofiev, 1979; Suturin, Zamaletdinov, 1984; Suturin et al., 2015), and as the authors do not describe the mineralogy of jadeite and jasperq or other gemstones from the local placers, thus a better title can be: Mineralogy of the Nyrdvomenshor nephrite deposit, Polar Urals, Russia

 

Abstract: We have Studied are quality characteristics, the chemical, mineral and isotope composition of nephrite, diopsidite and rodingite samples from the Nyrdvomenshor nephrite deposit in the Polar Urals. We  Applied are visual petrographic……

22: Keywords: nephrite, diopsidite, rodingite, Nyrdvomenshor, Polar Urals uvarovite, chromite, metamorphism, metasomatism

26: Nephrite consist mainly of fibrous tremolite or actinolite. The general formula for the tremolite-actinolite-ferroactinolite isomorphic series is: □Ca2(Mg,Fe)5Si8O22(OH)2

27-28: …China and New Zealand. [Central America is famous for jadeite artifacts, and not for nephrite artifacts].

28-30: The most expensive samples are white translucent, black and bright green with a minimum amount of ore minerals, or with the “cat's eye” effect nephrites, as well as alluvial pebbles with edges of coloring.

33-35 Move the sentence after the S-type deposits to 39: The Dahua deposit in the Guangxi Zhuang Autonomous Region [3] and Luodian deposit in Guizhou Province [4] in southern China, formed on the contact of diabases and limestones, are close to the D type.

49: The Fengtien deposit is known in Taiwan [12-14] – it is a S-type deposit.

50: … Co Phuong deposit in Shon La Province in Vietnam – reference: Long et al., 2004.

53: … in the USA and Canada from Guatemala to Alaska , and mining is carried out…..

54: … Nephrite deposits are known but poorly studied in Wyoming [24] and several other states in the USA.

57: A few nephrite occurrences are known in Switzerland, Italy and Austria.

74: A number of small deposits…

76: … in the Southern Urals

79: There are three nephrite occurrences in the Bashkir Republic…

85-86: See above and move to 49-50: On the southern extension of the Urals, is the Dzhetygara nephrite occurrence in Kazakhstan [38]. A better reference is: Kovalenko, I.V., I.P. Khadzhi, V.S. Kovalenko, A.F. Sviridenko. 1985. Features of the microstructure and composition of ultramafic related nephrite. Zap. All-Union. Mineral. Soc., 114, 6, 707-712 (in Russian)

93: … nephrite linked to (related to) serpentinite …

126: …scattered , rare-earth and trace elements…

128: РЗЭ (REE)

141: … δ18O values

154: …town

168: Four companies…

177: Rai-Iz

185: Beside the geological data of Vakhrusheva et al., 2017, the deposit is well described in the earlier monograph Nephrites by N.A. Suturin, and P.S. Zamaletdinov, 1984 (second revised edition Suturin et al., 2015).

189: … albite-jadeitites,…

191: Numbers 1 to 16 for right part of Figure 1; or delete text on 194-201.

246: …minerals in diopsidite

262: Do the 3 nephrite samples in Table 3 correspond to number of samples from Figure 6?

287: In Table 4: Are you sure, that with max FeO 4.80%, the mineral is tremolite, and not actinolite. Are you sure, that with min FeO 0.61%, the pyroxene is omphacite?

287 In Table 4 and 404: The official name for shuiskite is (do you have proper analytical data for the formula): shuiskite-(Cr) Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O or shuiskite-(Mg) Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH).

341: Uvarovite is detected also in nephrite from China (Sichuan) and New Zealand: Jin, X., Z. Qiu, S. Dai, J. Yi, L. Li, Y. Zhang. 2014. Gemmological and mineralogical characteristics of nephrite from Ya’an, Sichuang Province. Journal of Gems & Gemmology, 16, 5, 1-8 (in Chinese with English abstract). Cooper, A. F. 2022. Origin and evolution of nephrites, diopsidites and giant diopside crystals from the contact zones of the pounamu ultramafics, Westland, New Zealand. New Zealand Journal of Geology and Geophysics, 10.1080/00288306.2022.2050771. A single uvarovite analysis is also reported from the near-by Puserka jadeite deposit (Popov et al., 2015).

363: 1020 ppm of Cr Ni…

364-371: Everywhere after the data for the three elements – ppm

391: Ulankhoda…

402 and 410: The official IMA formula of tremolite is: □Ca2(Mg5.0-4.5 Fe2+0.0-0.5)Si8O22(OH)2

408: There are no proper component data to declare the mineral is omphacite (see 287, Table 4). In the next sentence there is a “transfer” from omphacite to jadeite – also a high-pressure mineral, but not in paragenesis with tremolite, which in metamorphic conditions unusually is a formed at lower-temperatures and pressures. Bolders of both nephrite and jadeite (but not formed together –

there are no reported data or photos) in the region are described by Dergunov et al., 1975 (for jadeite in the three ultramafic complexes in the Polar Urals with possible similar genesis see: Meng et al. 2011. Zircon U-Pb dating of jadeitite from the Syum-Keu ultramafic complex, Polar Urals, Russia: Constraints for subduction initiation. Journal of Asian Earth Sciences, 42, 596-606).

415-433: This text must be placed at 441 as discussion after the new data of the authors.

450-451: Text to be deleted.

454: Of importance for the Conclusions are:

  • Green nephrite from this deposit is tremolite, linked to S-type (serpentinite linked) genesis.
  • It was formed by both multistage metasomatic and superimposed metamorphic processes.
  • Mineral composition……
  • Geochemical and isotope characteristics…..

References:

483: Kievlenko, E.Ya. Geology of Gems. Ocean Pictures: Littleton CO, USA. 2003, 468 p.

485: https://doi.org/10.2747/0020-6814.47.2.113

486: http://dx.doi.org/10.5741/GemS.55.2.198

507: https://doi.org/10.1016/0016-7037(88)90321-3

535: https://doi.org/10.1016/j.oregeorev.2020.103335

537: https://doi.org/10.1016/j.lithos.2007.01.001

546 and 548: The study is not a review on all nephrite occurrences in Russia and worldwide – old communications of 1915-1918 can be omitted or replaced by contemporary review papers.

570: https://doi.org/10.1016/0016-7037(90)90160-M

576: doi.10.1016/j.ijms.2011.10.003

577: https://doi.org/10.1080/00288306.2010.514929

579: doi.10.1016/j.jseaes.2011.05.012

582: https://doi.org/10.1002/gea.21417

588: https://doi.org/10.2113/gsecongeo.97.3.593

589: This paper (see same author at N45 in references) can be replaced by another one and cited in the text: Kislov, E.V., M.P. Popov, F.M. Nurmuhametov. 2021. Perspective of the Nyrdvomenshor nephrite deposit, Polar Urals. In: Dynamics and Interaction of the Earths Geospheres. Еd. Tomsk CSTI, Tomsk, 1, 312-314 (in Russian).

 

Comments for author File: Comments.pdf

The English text can be a bit better. 

Author Response

We are sincerely grateful to the reviewer for the great work not only in reviewing, but also in editing, correcting, and supplementing our manuscript. As a result of this, as well as corrections for two more reviews, it has become much better. We apologize for any misprints, inaccuracies, omissions and errors.

The study is important both from a theoretical and gemmological point of view. This is the first in detail mineralogical and geochemical investigation on this nephrite deposit from a remote region in the Northern Urals of the Russian Federation. The authors must change the introduction and final text which copy their text from an extended abstract on the same deposit (to be included in references): Kislov, E. V., M. P. Popov, F. M. Nurmukhametov, V. F. Posokhov. 2022b. Nephrite from the Nyrdvomenshor deposit (Polar Urals): features of composition and formation settings. – In: Ultramafic-mafic Complexes: Geology, Composition, Ore Potential. Materials of Conference. Apatity, 54-57 (in Russian).

- corrected

Comments and notes:

Title: Nyrdvomenshor is well known as a nephrite deposit (Kazak et al., 1976; Efros, Prokofiev, 1979; Suturin, Zamaletdinov, 1984; Suturin et al., 2015), and as the authors do not describe the mineralogy of jadeite and jasperq or other gemstones from the local placers, thus a better title can be: Mineralogy of the Nyrdvomenshor nephrite deposit, Polar Urals, Russia

 - corrected

Abstract: We have Studied are quality characteristics, the chemical, mineral and isotope composition of nephrite, diopsidite and rodingite samples from the Nyrdvomenshor nephrite deposit in the Polar Urals. We  Applied are visual petrographic……

 - corrected

22: Keywords: nephrite, diopsidite, rodingite, Nyrdvomenshor, Polar Urals uvarovite, chromite, metamorphism, metasomatism

 - corrected

26: Nephrite consist mainly of fibrous tremolite or actinolite. The general formula for the tremolite-actinolite-ferroactinolite isomorphic series is: □Ca2(Mg,Fe)5Si8O22(OH)2

- corrected

27-28: …China and New Zealand. [Central America is famous for jadeite artifacts, and not for nephrite artifacts].

- corrected

28-30: The most expensive samples are white translucent, black and bright green with a minimum amount of ore minerals, or with the “cat's eye” effect nephrites, as well as alluvial pebbles with edges of coloring.

- corrected

33-35 Move the sentence after the S-type deposits to 39: The Dahua deposit in the Guangxi Zhuang Autonomous Region [3] and Luodian deposit in Guizhou Province [4] in southern China, formed on the contact of diabases and limestones, are close to the D type.

- corrected

49: The Fengtien deposit is known in Taiwan [12-14] – it is a S-type deposit.

- corrected

50: … Co Phuong deposit in Shon La Province in Vietnam – reference: Long et al., 2004.

- corrected

53: … in the USA and Canada from Guatemala to Alaska , and mining is carried out…..

- corrected

54: … Nephrite deposits are known but poorly studied in Wyoming [24] and several other states in the USA.

- corrected

57: A few nephrite occurrences are known in Switzerland, Italy and Austria.

- corrected

74: A number of small deposits…

- corrected

76: … in the Southern Urals

- corrected

79: There are three nephrite occurrences in the Bashkir Republic…

- corrected

85-86: See above and move to 49-50: On the southern extension of the Urals, is the Dzhetygara nephrite occurrence in Kazakhstan [38]. A better reference is: Kovalenko, I.V., I.P. Khadzhi, V.S. Kovalenko, A.F. Sviridenko. 1985. Features of the microstructure and composition of ultramafic related nephrite. Zap. All-Union. Mineral. Soc., 114, 6, 707-712 (in Russian)

- corrected

93: … nephrite linked to (related to) serpentinite …

- corrected

126: …scattered , rare-earth and trace elements…

- corrected

128: РЗЭ (REE)

- corrected

141: … δ18O values

- corrected

154: …town

- corrected

168: Four companies…

- corrected

177: Rai-Iz

- corrected

185: Beside the geological data of Vakhrusheva et al., 2017, the deposit is well described in the earlier monograph Nephrites by N.A. Suturin, and P.S. Zamaletdinov, 1984 (second revised edition Suturin et al., 2015).

- corrected

189: … albite-jadeitites,…

- corrected

191: Numbers 1 to 16 for right part of Figure 1; or delete text on 194-201.

- corrected

246: …minerals in diopsidite

- corrected

262: Do the 3 nephrite samples in Table 3 correspond to number of samples from Figure 6?

No, they are different samples

287: In Table 4: Are you sure, that with max FeO 4.80%, the mineral is tremolite, and not actinolite.

- corrected, and at the text too

Are you sure, that with min FeO 0.61%, the pyroxene is omphacite?

Omphacite is a mineral of variable composition, a solid solution of diopside and jadeite, less often it is indicated that diopside, jadeite and aegirine. When writing its formula, either the predominance of magnesium over iron is noted, or iron is not indicated at all.

287 In Table 4 and 404: The official name for shuiskite is (do you have proper analytical data for the formula): shuiskite-(Cr) Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O or shuiskite-(Mg) Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH).

- corrected. We have identified an unnamed mineral of the shuiskite group with a significant predominance of iron. The necessary clarifications in the table, text, and captions to the illustration have been made.

341: Uvarovite is detected also in nephrite from China (Sichuan) and New Zealand: Jin, X., Z. Qiu, S. Dai, J. Yi, L. Li, Y. Zhang. 2014. Gemmological and mineralogical characteristics of nephrite from Ya’an, Sichuang Province. Journal of Gems & Gemmology, 16, 5, 1-8 (in Chinese with English abstract). Cooper, A. F. 2022. Origin and evolution of nephrites, diopsidites and giant diopside crystals from the contact zones of the pounamu ultramafics, Westland, New Zealand. New Zealand Journal of Geology and Geophysics, 10.1080/00288306.2022.2050771. A single uvarovite analysis is also reported from the near-by Puserka jadeite deposit (Popov et al., 2015).

- corrected. About the deposit in Sichuan there is an indication of the presence of uvarovite and a photograph. But analyzes of the chemical composition of the mineral are not given. Nephrite from New Zealand contains grossular with a high content of the uvarovite component. The mention of the find in Pusierka is given, although it is not associated with nephrite.

363: 1020 ppm of Cr Ni…

- corrected

364-371: Everywhere after the data for the three elements – ppm

- corrected

391: Ulankhoda…

- corrected

402 and 410: The official IMA formula of tremolite is: □Ca2(Mg5.0-4.5 Fe2+0.0-0.5)Si8O22(OH)2

- corrected, clarification is given in the text of the article

408: There are no proper component data to declare the mineral is omphacite (see 287, Table 4). In the next sentence there is a “transfer” from omphacite to jadeite – also a high-pressure mineral, but not in paragenesis with tremolite, which in metamorphic conditions unusually is a formed at lower-temperatures and pressures. Bolders of both nephrite and jadeite (but not formed together – there are no reported data or photos) in the region are described by Dergunov et al., 1975 (for jadeite in the three ultramafic complexes in the Polar Urals with possible similar genesis see: Meng et al. 2011. Zircon U-Pb dating of jadeitite from the Syum-Keu ultramafic complex, Polar Urals, Russia: Constraints for subduction initiation. Journal of Asian Earth Sciences, 42, 596-606).

- corrected, clarification is given in the text of the article

415-433: This text must be placed at 441 as discussion after the new data of the authors.

- corrected

450-451: Text to be deleted.

- corrected

454: Of importance for the Conclusions are:

  • Green nephrite from this deposit is tremolite, linked to S-type (serpentinite linked) genesis.
  • It was formed by both multistage metasomatic and superimposed metamorphic processes.
  • Mineral composition……
  • Geochemical and isotope characteristics…..
  • - corrected

References:

483: Kievlenko, E.Ya. Geology of Gems. Ocean Pictures: Littleton CO, USA. 2003, 468 p.

- corrected

485: https://doi.org/10.2747/0020-6814.47.2.113

- corrected

486: http://dx.doi.org/10.5741/GemS.55.2.198

- corrected

507: https://doi.org/10.1016/0016-7037(88)90321-3

- corrected

535: https://doi.org/10.1016/j.oregeorev.2020.103335

- corrected

537: https://doi.org/10.1016/j.lithos.2007.01.001

- corrected

546 and 548: The study is not a review on all nephrite occurrences in Russia and worldwide – old communications of 1915-1918 can be omitted or replaced by contemporary review papers.

- corrected

570: https://doi.org/10.1016/0016-7037(90)90160-M

- corrected

576: doi.10.1016/j.ijms.2011.10.003

- corrected

577: https://doi.org/10.1080/00288306.2010.514929

- corrected

579: doi.10.1016/j.jseaes.2011.05.012

- corrected

582: https://doi.org/10.1002/gea.21417

- corrected

588: https://doi.org/10.2113/gsecongeo.97.3.593

- corrected

589: This paper (see same author at N45 in references) can be replaced by another one and cited in the text: Kislov, E.V., M.P. Popov, F.M. Nurmuhametov. 2021. Perspective of the Nyrdvomenshor nephrite deposit, Polar Urals. In: Dynamics and Interaction of the Earth’s Geospheres. Еd. Tomsk CSTI, Tomsk, 1, 312-314 (in Russian).

- corrected. Unclear. The link to the abstract of thesis cannot be replaced by a link to the article, since its differ in conclusions about the number of deformation stages. It is not clear why our abstract are here - it was not considered in them.

Author Response File: Author Response.docx

Reviewer 3 Report

The authors present the results of a study of jade alluvial material from the Nyrdvomenshor deposit. The overall impression of the submitted manuscript is ambiguous. The poor quality of the analytical data and dubious identification of minerals raise doubts that the authors dealt with nephrite, and not tremolitite.

I believe that this manuscript should not be published in Minerals. However, below I have listed the main comments which need clarification if the authors would like to submit this manuscript somewhere else:

- The presentation of analytical data is careless. Normally, all analyses should be calculated on the crystal-chemical formula.

- Very strange presentation of mineral analyses. I understand if the authors gave a mean analysis and then showed the range of changes in the components from minimum to maximum in the selected population of analyses.

- The totals in all Tables are not match the data in Tables.

- I have doubts about the correct identification of minerals.

- In Table 2 grossular (ideal formula Ca3Al2Si3O12) contains !MgO ~ 36-38 wt.%.

- Images of nephrite are low quality. If a petrographic study has been performed, the authors can provide some optical images of nephrite.

 

- Why did isotope analyses were carried out, there is no interpretation of these data in the manuscript. 

Author Response

The authors present the results of a study of jade alluvial material from the Nyrdvomenshor deposit. The overall impression of the submitted manuscript is ambiguous. The poor quality of the analytical data and dubious identification of minerals raise doubts that the authors dealt with nephrite, and not tremolitite.

- corrected. Applied instruments and methods correspond to the world level. The description of the technique met with no objections from the reviewer. With regard to bringing tabular data, they are supplemented by average values. The studied rock really belongs to nephrite, and not to tremolitite, as evidenced by the photographs. The text is supplemented by a description of the microfabric and morphology of grains and aggregates of tremolite, confirming that it is nephrite.

I believe that this manuscript should not be published in Minerals. However, below I have listed the main comments which need clarification if the authors would like to submit this manuscript somewhere else:

- The presentation of analytical data is careless. Normally, all analyses should be calculated on the crystal-chemical formula.

- The more traditional style is the presentation of full representative analyses, but this requires considerable space. Therefore, the editors object to presenting a significant number of analyzes in the text. Recalculation of all analyzes into crystal chemical formulas will double the volume. If necessary, such information can be provided by the authors to everyone upon request.

- Very strange presentation of mineral analyses. I understand if the authors gave a mean analysis and then showed the range of changes in the components from minimum to maximum in the selected population of analyses.

- corrected. Tables are supplemented with average values.

- The totals in all Tables are not match the data in Tables.

- corrected. The sum in the tables was not the sum of the maximum and minimum values of partial analyzes, but the maximum and minimum sum of partial analyzes. These values have been removed.

- I have doubts about the correct identification of minerals.

- corrected. Tables are supplemented with average values. The table of composition of grossular in rodingite has been corrected.

- In Table 2 grossular (ideal formula Ca3Al2Si3O12) contains !MgO ~ 36-38 wt.%.

- corrected. Sorry for mistake.

- Images of nephrite are low quality. If a petrographic study has been performed, the authors can provide some optical images of nephrite.

 - corrected. Photos of the plates are replaced by photos with illumination of a larger size.

- Why did isotope analyses were carried out, there is no interpretation of these data in the manuscript. 

Interpretation of isotopic data is contained in the Discussion section and is reflected in the conclusions

Author Response File: Author Response.docx

Round 2

Reviewer 3 Report

Please see the attachment.

Comments for author File: Comments.pdf

Author Response

Thank you very much for your comments and suggestions. According to the sample you proposed, the tables were redone, crystal chemical formulas are given

Author Response File: Author Response.pdf

Round 3

Reviewer 3 Report

The manuscript can be accepted for publication.

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