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Article

Assessment of Groundwater Vulnerability from Source to Tap Using TIN Approach

by
Tamara Marković
1,
Nikolina Novotni-Horčička
2,
Laszlo Palcsu
3 and
Igor Karlović
1,*
1
Croatian Geological Survey, 10000 Zagreb, Croatia
2
Varkom d.o.o., 42000 Varaždin, Croatia
3
HUN-REN Institute for Nuclear Research, Isotope and Climatological and Environmental Research Centre, 4001 Debrecen, Hungary
*
Author to whom correspondence should be addressed.
Water 2025, 17(23), 3341; https://doi.org/10.3390/w17233341
Submission received: 8 October 2025 / Revised: 18 November 2025 / Accepted: 19 November 2025 / Published: 21 November 2025
(This article belongs to the Section Hydrogeology)

Abstract

Groundwater and water supply systems are increasingly vulnerable to contamination, yet most assessments consider either hydrogeological or infrastructure risks. This study introduces the Total Integrated Network (TIN) approach, a framework designed to evaluate vulnerability comprehensively from source to tap. Field investigations were conducted in Varaždin County, Croatia, focusing on the Belski Dol spring, Briška reservoir, and PS Filipići. Hydrochemical analyses, stable isotope of water (δ18O, δ2H), tritium, noble gases, and radon concentrations were monitored and combined with system-level assessments. Results show that the Belski Dol spring exhibits high stability and low vulnerability, with a TIN index of approximately 25%, supported by long groundwater residence times and consistent water quality. PS Filipići displayed moderate vulnerability (35%), while the Briška reservoir showed the highest index (53%), linked to elevated radon and nitrate concentrations and infrastructure-related risks. These findings indicate that natural hydrogeological protection alone cannot ensure safe drinking water. The TIN approach highlights the importance of integrating aquifer conditions with distribution system performance to identify critical control points and prioritize interventions. This integrated methodology offers a more realistic basis for water safety management, supporting proactive measures to safeguard supply resilience and public health.
Keywords: isotopes; chemistry; vulnerability of groundwater and water supply system; TIN approach isotopes; chemistry; vulnerability of groundwater and water supply system; TIN approach

Share and Cite

MDPI and ACS Style

Marković, T.; Novotni-Horčička, N.; Palcsu, L.; Karlović, I. Assessment of Groundwater Vulnerability from Source to Tap Using TIN Approach. Water 2025, 17, 3341. https://doi.org/10.3390/w17233341

AMA Style

Marković T, Novotni-Horčička N, Palcsu L, Karlović I. Assessment of Groundwater Vulnerability from Source to Tap Using TIN Approach. Water. 2025; 17(23):3341. https://doi.org/10.3390/w17233341

Chicago/Turabian Style

Marković, Tamara, Nikolina Novotni-Horčička, Laszlo Palcsu, and Igor Karlović. 2025. "Assessment of Groundwater Vulnerability from Source to Tap Using TIN Approach" Water 17, no. 23: 3341. https://doi.org/10.3390/w17233341

APA Style

Marković, T., Novotni-Horčička, N., Palcsu, L., & Karlović, I. (2025). Assessment of Groundwater Vulnerability from Source to Tap Using TIN Approach. Water, 17(23), 3341. https://doi.org/10.3390/w17233341

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