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Quantification and Speciation of Trace Metals under Pollution Impact: Case Study of a Subarctic Lake

Vernadsky Institute of Geochemistry and Analytical Chemistry (GEOKhI), Russian Academy of Sciences, 119991 Moscow, Russia
Author to whom correspondence should be addressed.
Water 2020, 12(6), 1641;
Received: 22 May 2020 / Revised: 3 June 2020 / Accepted: 5 June 2020 / Published: 8 June 2020
(This article belongs to the Special Issue Environmental Chemistry of Water Quality Monitoring)
Monitoring the quantity and quality of metals in lake water is a major part of assessing water toxicity. A fundamental aspect of geochemical monitoring studies is the evaluation of the equilibrium distribution of metal speciation in water and the influence of environmental conditions on this process. It is important to understand the difference between the behavior of nanoparticles, dissolved particles, colloid particles, and suspended particles. This study involved environmental aquatic chemistry research and the assessment of the geochemical processes of metal speciation in an arctic lake in the metallurgical waste zone and other areas where natural processes prevail. Consecutive and parallel membrane filtration methods were used to compare the results of water analysis in Imandra Lake. The membrane pore sizes were 8, 1.2, 0.45, and 0.2 µm. The following filtrate characteristics were used: microfiltration-based mechanical suspension and oxidized contaminants (>8, 1.2, 0.45, 0.2, 0.1 μm), and ultrafiltration-based colloids, bacteria, viruses, etc. (less than 0.1 μm). Industrial effluents led to the formation of higher concentrations of elements (Ni, Cu, and Pb) in their labile forms. In the wastewater-mixing zone, the concentrations of most elements were evenly distributed in depth. In more distant areas, we found a significant increase in the concentration of elements in the near-bottom horizon in comparison with the surface water (Fe by more than three times). The obtained results showed that numerous elements had diverse distributions by speciation in the points located closer to the source of wastewater. This indicated the significant influence of the adsorption process on the system balance of elements such as Fe, Cu, and rare earth elements. The impact of the regional geochemical and anthropogenic speciation and the possible influence of climatic factors on the distribution of speciation were determined. View Full-Text
Keywords: metals; membrane filtration; Arctic lakes metals; membrane filtration; Arctic lakes
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MDPI and ACS Style

Dinu, M.I.; Shkinev, V.M.; Moiseenko, T.I.; Dzhenloda, R.K.; Danilova, T.V. Quantification and Speciation of Trace Metals under Pollution Impact: Case Study of a Subarctic Lake. Water 2020, 12, 1641.

AMA Style

Dinu MI, Shkinev VM, Moiseenko TI, Dzhenloda RK, Danilova TV. Quantification and Speciation of Trace Metals under Pollution Impact: Case Study of a Subarctic Lake. Water. 2020; 12(6):1641.

Chicago/Turabian Style

Dinu, Marina I., Valery M. Shkinev, Tatyana I. Moiseenko, Rustam K. Dzhenloda, and Tatyana V. Danilova 2020. "Quantification and Speciation of Trace Metals under Pollution Impact: Case Study of a Subarctic Lake" Water 12, no. 6: 1641.

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