Next Article in Journal
The Water Governance Reform Framework: Overview and Applications to Australia, Mexico, Tanzania, U.S.A and Vietnam
Next Article in Special Issue
Diversity and Biotechnological Potential of Xylan-Degrading Microorganisms from Orange Juice Processing Waste
Previous Article in Journal
Field Water Balance Closure with Actively Heated Fiber-Optics and Point-Based Soil Water Sensors
Previous Article in Special Issue
Agroindustrial Wastewater Treatment with Simultaneous Biodiesel Production in Attached Growth Systems Using a Mixed Microbial Culture
Open AccessArticle

Zeolite as a Potential Medium for Ammonium Recovery and Second Cheese Whey Treatment

1
Department of Chemical Engineering, University of Patras, 26504 Patras, Greece
2
Department of Environmental and Natural Resources Management, University of Patras, 2 G. Seferi Str., 30100 Agrinio, Greece
3
Department of Civil Engineering, Democritus University of Thrace, 67100 Xanthi, Greece
4
Institute of Chemical Engineering Sciences (FORTH/ ICE-HT), Stadiou Str., Platani, P.O.Box 1414, 26504 Patras, Greece
*
Author to whom correspondence should be addressed.
Water 2019, 11(1), 136; https://doi.org/10.3390/w11010136
Received: 7 December 2018 / Revised: 3 January 2019 / Accepted: 8 January 2019 / Published: 14 January 2019
  |  
PDF [2347 KB, uploaded 14 January 2019]
  |  

Abstract

The efficiency of natural zeolite to remove ammonium from artificial wastewater (ammonium aqueous solutions) and to treat second cheese whey was examined, aiming to recover nitrogen nutrients that can be used for further applications, such as slow-release fertilizers. Sorption experiments were performed using artificial wastewater and zeolite of different granulometries (i.e., 0.71–1.0, 1.8–2.0, 2.0–2.8, 2.8–4.0, and 4.0–5.0 mm). The granulometry of the zeolite had no significant effect on its ability to absorb ammonium. Nevertheless, smaller particles (0.71–1.0 mm) exhibited quicker NH4+-N adsorption rates of up to 93.0% in the first 10 min. Maximum ammonium removal efficiency by the zeolite was achieved at ammonium concentrations ranging from 10 to 80 mg/L. Kinetic experiments revealed that chemisorption is the mechanism behind the adsorption process of ammonium on zeolite, while the Freundlich isotherm model fitted the experimental data well. Column sorption experiments under batch operating mode were performed using artificial wastewater and second cheese whey. Column experiments with artificial wastewater showed high NH4+-N removal rates (over 96% in the first 120 min) for all granulometries and initial NH4+-N concentrations tested (200 and 5000 mg/L). Column experiments with second cheese whey revealed that natural zeolite can remove significant organic loads (up to 40%, 14.53 mg COD/g of zeolite) and NH4+-N (about 99%). For PO43−-P, the zeolite appeared to saturate after day 1 of the experiments at a removal capacity of 0.15 mg P/g of zeolite. Desorption experiments with water resulted in low NH4+-N and PO43−-P desorption rates indicating that the zeolite could be used as a substrate for slow nitrogen release in soils. View Full-Text
Keywords: zeolite; secondary cheese-whey; ammonium removal; adsorption experiments; column experiments zeolite; secondary cheese-whey; ammonium removal; adsorption experiments; column experiments
Figures

Figure 1

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
SciFeed

Share & Cite This Article

MDPI and ACS Style

Kotoulas, A.; Agathou, D.; Triantaphyllidou, I.E.; Tatoulis, T.I.; Akratos, C.S.; Tekerlekopoulou, A.G.; Vayenas, D.V. Zeolite as a Potential Medium for Ammonium Recovery and Second Cheese Whey Treatment. Water 2019, 11, 136.

Show more citation formats Show less citations formats

Note that from the first issue of 2016, MDPI journals use article numbers instead of page numbers. See further details here.

Related Articles

Article Metrics

Article Access Statistics

1

Comments

[Return to top]
Water EISSN 2073-4441 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert
Back to Top