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Atmosphere 2018, 9(8), 320;

Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures

Atmospheric Chemistry Research Laboratory, University of Bayreuth, 95447 Bayreuth, Germany
Authors to whom correspondence should be addressed.
Current address: Department of Multiphase Chemistry, Max Planck Institute for Chemistry, 55128 Mainz, Germany.
Received: 18 July 2018 / Revised: 11 August 2018 / Accepted: 14 August 2018 / Published: 18 August 2018
(This article belongs to the Section Aerosols)
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The photochemical reaction of OH radicals with the 17 hydrocarbons n-butane, n-pentane, n-hexane, n-heptane, n-octane, n-nonane, cyclooctane, 2,2-dimethylbutane, 2,2-dimethylpentane, 2,2-dimethylhexane, 2,2,4-trimethylpentane, 2,2,3,3-tetramethylbutane, benzene, toluene, ethylbenzene, p-xylene, and o-xylene was investigated at 288 and 248 K in a temperature controlled smog chamber. The rate constants were determined from relative rate calculations with toluene and n-pentane as reference compounds, respectively. The results from this work at 288 K show good agreement with previous literature data for the straight-chain hydrocarbons, as well as for cyclooctane, 2,2-dimethylbutane, 2,2,4-trimethylpentane, 2,2,3,3-tetramethylbutane, benzene, and toluene, indicating a convenient method to study the reaction of OH radicals with many hydrocarbons simultaneously. The data at 248 K (k in units of 10−12 cm3 s−1) for 2,2-dimethylpentane (2.97 ± 0.08), 2,2-dimethylhexane (4.30 ± 0.12), 2,2,4-trimethylpentane (3.20 ± 0.11), and ethylbenzene (7.51 ± 0.53) extend the available data range of experiments. Results from this work are useful to evaluate the atmospheric lifetime of the hydrocarbons and are essential for modeling the photochemical reactions of hydrocarbons in the real troposphere. View Full-Text
Keywords: OH radicals; smog chamber; rate constant; hydrocarbons; low temperatures OH radicals; smog chamber; rate constant; hydrocarbons; low temperatures

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Han, L.; Siekmann, F.; Zetzsch, C. Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures. Atmosphere 2018, 9, 320.

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