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Polymers 2017, 9(10), 547;

Deformation-Induced Phase Transitions in iPP Polymorphs

Department of Mechanical Engineering, Materials Technology Institute, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
Faculty of Engineering Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands
Current address: Sabic T&I, STC Geleen, P.O. Box 319, 6160 AH Geleen, The Netherlands.
Author to whom correspondence should be addressed.
Academic Editor: Roberto Pantani
Received: 21 August 2017 / Revised: 28 September 2017 / Accepted: 18 October 2017 / Published: 24 October 2017
(This article belongs to the Special Issue Processing-Structure-Properties Relationships in Polymers)


This detailed study reveals the relation between structural evolution and the mechanical response of α -, β - and γ -iPP. Uni-axial compression experiments, combined with in situ WAXD measurements, allowed for the identification of the evolution phenomena in terms of phase composition. Tensile experiments in combination with SAXS revealed orientation and voiding phenomena, as well as structural evolution in the thickness of the lamellae and amorphous layers. On the level of the crystallographic unit cell, the WAXD experiments provided insight into the early stages of deformation. Moreover, transitions in the crystal phases taking place in the larger deformation range and the orientation of crystal planes were monitored. At all stretching temperatures, the crystallinity decreases upon deformation, and depending on the temperature, different new structures are formed. Stretching at low temperatures leads to crystal destruction and the formation of the oriented mesophase, independent of the initial polymorph. At high temperatures, above T α c , all polymorphs transform into oriented α -iPP. Small quantities of the initial structures remain present in the material. The compression experiments, where localization phenomena are excluded, show that these transformations take place at similar strains for all polymorphs. For the post yield response, the strain hardening modulus is decisive for the mechanical behavior, as well as for the orientation of lamellae and the evolution of void fraction and dimensions. β -iPP shows by far the most intense voiding in the entire experimental temperature range. The macroscopic localization behavior and strain at which the transition from disk-like void shapes, oriented with the normal in tensile direction, into fibrillar structures takes place is directly correlated with the strain hardening modulus. View Full-Text
Keywords: polymorphism; isotactic polypropylene; deformation; phase transitions; uniaxial compression; uniaxial tensile deformation; temperature; in situ X-ray; cavitation polymorphism; isotactic polypropylene; deformation; phase transitions; uniaxial compression; uniaxial tensile deformation; temperature; in situ X-ray; cavitation

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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. (CC BY 4.0).

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Caelers, H.J.M.; Troisi, E.M.; Govaert, L.E.; Peters, G.W.M. Deformation-Induced Phase Transitions in iPP Polymorphs. Polymers 2017, 9, 547.

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